Is Chlorogenic Acid Bitter?

Chlorogenic acid at 5° published threshold concentration (100 mg/ L) in aqueous 0.2% potassium acid tartrate was not significantly more bitter than aqueous 0.2% potassium tartrate alone when evaluated by taste panel.     

Chemistry of Uranium in Glass-Forming Melts: Redox Interactions of Uranium with Chromium and Iron in Aluminosilicates

The mutual interactions by internal redox reactions of uranium and chromium and uranium and iron in two aluminosilicate glass-forming melts were studied by optical spectrophotometry. Cr(VI) was found to oxidize completely all available U(V) and U(IV) to U(VI), whereas Fe(III) was not a strong enough oxidizing agent to affect the uranium redox states. Cr(II) totally reduced all the U(V) and U(VI) in the system to U(IV); Fe(II) did not reduce any of the uranium redox species. Cr(III) coexisted with U(VI), U(V), and U(IV) in the melts. The degree of mutual interaction was governed not only by the difference in redox potentials between the respective redox couples, but also by the stability of molecular associations between the redox ions within the melt microstructure.     

Fracture Induced in Al2O3 Bicrystals by Anisotropic Thermal Expansion

Bicrystals of Al₂O₃ were fabricated to study the effects of thermal expansion anisotropy on fracture in a model system containing one grain boundary. Fractures occurred perpendicular to the directions of maximum tensile stress in bicrystals with thermal expansion coefficient differences as low as 0.31×10⁻⁶⁰C⁻¹ and originated at the boundary, probably in areas of high residual stress associated with pores. Numerical stress analysis of two-dimensional model bicrystal configurations showed that stresses induced by thermal expansion anisotropy are maximal in a region localized along the bicrystal boundary.     

Suggested Chemistry of Zinc Oxychloride Cements

Solutions of ZnCl₂ were prepared from ZnCl₂· n H₂O and by reaction of zinc metal with HCl. Specific gravities and pH values were determined as a function of composition. A ternary phase, 4ZnO·ZnCl₂·5H₂O, was precipitated when the ZnCl₂ solutions were diluted to a pH of 5.48 ± 0.05. Mixtures of ZnO with ZnCl, and HCI solutions were equilibrated in sealed containers and analyzed by X-ray diffraction. The resulting phase diagram shows 2 ternary phases, 4ZnO·ZnCl₂·5H₂O (4·1·5) and ZnO·ZnCl₂·2H₂O (1.1.2), both of which are soluble to the extent of < 1 wt% in ZnCl₂ solutions. Thermogravimetric data indicate that the 1.1.2 phase loses half the constituent H₂O at ∼230°C and the remainder, with ZnCl₂, at higher temperatures. The 4.1.5 phase dissociates to ZnO and 1.1.2 at ∼160°C. The system ZnCl₂-H₂O is not binary, but is a section through the ternary system ZnO-HCl-H₂O, with the solubility curve of the 4.1.5 phase intersecting the ZnCl₂-H₂O section in dilute solutions.     

A GENERAL APPROACH TO THE STUDY OF SPATIAL SYSTEMS II. Two Examples of Application

The emphasis in this work is on the practical application of ideas set forth in Part I. Two studies involving spatial distribution are discussed: the distribution of human population in the Indianapolis, Indiana Region, and the world distribution of mammals. In the first, populations over the period 1890–1980 of Ihe 393 townships making up the study area are used to produce classifications involving various numbers of classes of township types. A test of the theoretical structure posed in Part I is then detailed. On the theory that the underlying relations involved cannot sustain a real world structure involving more than five functional classes, it is hypothesized that classifications involving more than five classes will be associated with township distribution patterns that conflict with Central Place Theory. This is shown to be clearly so. In the second study, the derivation of a five region partitioning of world mammalian distribution patterns is described. Discussion includes the introduction of a wholly new rationale for taxonomic revision based on biogeographic criteria (and ultimately the principles described in Part I). The study closes with a short argument regarding why the model described in Part I should not be labelled as either social physics or anti-humanistic.     

Singular perturbation analysis of high-frequency filter design

The control design of systems with lightly damped high frequency oscillatory modes is treated. Systems exhibiting these lightly damped modes include turbine generators and large flexible structures. Frequently the dynamics of these high-frequency modes are not known very accurately. As a result, the design objective is to improve the slow dynamics without destabilizing the high-frequency modes. From a classical frequency domain design viewpoint, this is in part a filtering problem requiring some kind of high-frequency filter. The singular perturbation method is used to systematically develop a two-time-scale method to design these high-frequency filters and provides guidelines on the kind of high-frequency filter to be used. In addition, the method provides an asymptotic error analysis. The design is illustrated with an example representative of a power system model with a two-mass turbine-generator model.     

ASN_EZE: An Analgesic for Writers of ASN.1 Applications

Many programmers find that the logical structure of data defined in ASA.1 is simple enough, but the physical representation requires painfully careful attention to lots of detail. ASN.1 'compilers' which we had used required a programmer ot know the intricacies of both ASN.1 and the generated code. Furthermore those which generated 'C' code were prone to 'memory leaks' and produced bulky code. Two features of object orientiation led us to develop a code generator that procues 'C++'. First Class inheritance permits a small number of functions to operate on objects of any derived class. Second, the destructors of such objects can be designed to prevent memory leaks automatically. Our own use of the system shows that within a few days programmers withh no pair exposure to ASN.1 can start writing applications using only the ASN.1 specification for reference. The generated code is compact and well protected anainst memory leaks. This paper describes the capabilies of the code generator, the library of functions for handling all ASN.1 objects so generated, and the interior structure of these objects which allows the library functions to navigate any hierarchy. The las section discusses our experience in using the system.     

Effect of Joint Thickness and Residual Stresses on the Properties of Ceramic Adhesive Joints: I, Finite Element Analysis of Stresses in Joints

The finite element method was used to determine the stress distributions in adhesive joints prepared using alumina adher-ends and silicate glass adhesives with varying thicknesses and thermal expansion coefficients. These analyses, together with the results of literature analyses for joints subjected to externally applied loads, aided in interpreting the experimental observations which are described in Part II of the paper.     

Thermal Expansion of Pb3O4

Thermal expansion of Pb₃O₄ was investigated by high-temperature X-ray diffraction. The coefficient in the a ₀ direction is 14.6×10⁻⁶/°C. Expansion in the c₀ direction is 32% greater, with a coefficient of 19.3×10⁻⁶/°C. Coefficients of expansion are linear from 25° to 490°C and are comparable with those of tetragonal and orthorhombic PbO.     

A PORE NETWORK MODEL FOR THE CALCULATION OF NON-DARCY FLOW COEFFICIENTS IN FLUID FLOW THROUGH POROUS MEDIA

A computational method was developed to determine the correlation between permeability and the Forchheimer (non-Darcy) coefficient and to investigate numerically the factors that affect this correlation. The method is based on the construction of a 2-D random pore network. The porous medium is represented as a network of cylindrical pipes with randomly generated size, orientation, and connectivity. Probability density functions are used to characterize the orientation, length, diameter, and connectivity properties of the pipes that form the pore space. In this article the development and validation of the computational method are discussed. The computational procedure provides an expected value for the medium properties and a variation around this expected value, which is a measure of the uncertainty associated with the calculation of porous media properties. It was found that the porous medium structure has a strong effect on the flow properties. Specifically, the splitting of the pores is mostly responsible for non-Darcy flow behavior. Examination of the behavior of the medium properties under compaction shows that there is a unifying correlation for the behavior of the permeability. However, each type of porous medium exhibits different non-Darcy flow behavior under compaction. Finally, a statistical model, which correlates the structure characteristics of the porous medium to the measured properties, is presented.