A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

Molecular dynamics study on nanotube-resonators with mass migration applicable to both frequency-tuner and data-storage-media

We investigated the cantilevered carbon-nanotube-resonator including electromigratively movable nanoparticle via classical molecular dynamics simulations and continuum model. The change of the effective mass value, which was closely correlated with the position change of the encapsulated nanoparticle, could be regressed by a power function, the resonance frequency of the carbon-nanotube-resonator could be tuned by controlling the nanoparticle’s position, and the possible frequency-shift-ranges then reached 18–85%. The suggested device could be served as a data-storage-media for electromechanical nonvolatile-memory as well as a frequency-tuner.     

Fabrication of Al matrix composite reinforced with submicrometer-sized Al<Subscript>2</Subscript>O<Subscript>3</Subscript> particles formed by combustion reaction between HEMM Al and V<Subscript>2</Subscript>O<Subscript>5</Subscript> composite particles during sintering

To fabricate an Al-V matrix composite reinforced with submicron-sized Al₂O₃ and Al_xV_y (Al₃V, Al₁₀V) phases, high energy mechanical milling (HEMM) and sintering were employed. By increasing the milling time, the size of mechanically milled powder was significantly reduced. In this study, the average powder size of 59 μm for Al, and 178 μm for V₂O₅ decreased with the formation of a new product, Al-Al₂O₃-Al_xV_y, with a size range from 1.3 μm to 2.6 μm formed by the in-situ combustion reaction during sintering of HEM milled Al and V₂O₅ composite powders. The in-situ reaction between Al and V₂O₅ during the HEMM and sintering transformed the Al₂O₃ and Al_xV_y (Al₃V, Al₁₀V) phases. Most of the reduced V reacted with excess the Al to form Al_xV_y (Al₃V, Al₁₀V) with very little V dissolved into Al matrix. By increasing the milling time and weight percentage of V₂O₅, the hardness of the Al-Al₂O₃-Al_xV_y composite sintered at 1173 K increased. The composite fabricated with the HEMM Al-20wt.%V₂O₅ composite powder and sintering at 1173 K for 2 h had the highest hardness.     

Multiridge detection and time-frequency reconstruction

The ridges of the wavelet transform, the Gabor transform, or any time-frequency representation of a signal contain crucial information on the characteristics of the signal. Indeed, they mark the regions of the time-frequency plane where the signal concentrates most of its energy. We introduce a new algorithm to detect and identify these ridges. The procedure is based on an original form of Markov chain Monte Carlo algorithm especially adapted to the present situation. We show that this detection algorithm is especially useful for noisy signals with multiridge transforms. It is a common practice among practitioners to reconstruct a signal from the skeleton of a transform of the signal (i.e., the restriction of the transform to the ridges). After reviewing several known procedures, we introduce a new reconstruction algorithm, and we illustrate its efficiency on speech signals and its robustness and stability on chirps perturbed by synthetic noise at different SNRs     

Simple K-band MMIC VCO utilizing a miniaturized hairpin resonator and a three-terminal p-HEMT varactor with low phase noise and high output power properties

Presents a fully monolithic K-band MMIC voltage-controlled oscillator (VCO) implemented by using a 0.25 /spl mu/m AlGaAs/InGaAs pseudomorphic HEMT (p-HEMT) technology. The use of a half-wavelength miniaturized hairpin-shaped resonator and a three-terminal p-HEMT varactor was effective in reducing the chip size and simplifying fabrication processes of the microwave MMIC VCO without impairing the performance of the circuit. The VCO provides a typical output power of 11.5 dBm at 20.8 GHz and a free-running phase noise of -82 dBc/Hz at 100 kHz offset and -95 dBc/Hz at 1 MHz offset. It also shows a tuning range of 70 MHz with little reduction in output power and high yield properties. The chip size of the MMIC VCO is 1.5 /spl times/ 2.0 mm/sup 2/.     

Lineage of non-cranial neural crest cell in the dental mesenchyme: using a lacZ reporter gene during early tooth development

The tooth is one of the ectodermal organs controlled by reciprocal interactions between the epithelium and the mesenchyme. Mesenchymal cells in the developing tooth, so-called dental mesenchymal cells, are derived from two different origins: the cranial neural crest (CNC) and the non-CNC. These CNC-derived cells migrate, proliferate and differentiate into odontoblasts, cementoblasts, fibroblasts, osteoblasts and chondroblasts. Tooth germs of wild-type mice were transplanted into the kidney of adult lacZ-transgenic mice. After 1 week of transplantation, a few lacZ-expressing cells and many red blood cells were found near or inside the blood vessels in the pulp of wild-type tooth germs. This result shows that circulating cells of the adult host could invade the dental pulp during tooth development, through the blood vessels, and be a part of dental pulp tissue. Therefore, it can be suggested that these circulating progenitor cells could be the origin of non-CNC-derived cells in tooth germ and their migration pathways would be the blood vessels invading the dental pulp during tooth development. If variations of this experiment were suitably adjusted, such as the embryonic stage of the tooth germ, duration of transplantation, etc., this transplantation experiment using adult lacZ-transgenic mice could be a good system to reveal the origin and migration pathway of cells in developing organs as well as in dental mesenchymal cells.     

On Striping Traffic over Multiple IEEE 802.11(b) Wireless Channels

Due to interference, path loss, multipath fading, background noise, and many other factors, wireless communication normally cannot provide a wireless link with both a high data rate and a long transmission range. To address this problem, striping network traffic in parallel over multiple lower-data-rate but longer-transmission-range wireless channels may be used. In this paper, we propose a new striping method and evaluate its performances over multiple IEEE 802.11(b) channels under various conditions. Our extensive simulation results show that this method is quite effective for such an application. S.Y. Wang is an Associate Professor of the Department of Computer Science and Information Engineering at National Chiao Tung University, Taiwan. He received his Master and Ph.D. degree in computer science from Harvard University in 1997 and 1999, respectively. His research interests include wireless networks, Internet technologies, network simulations, and operating systems. He is the author of the NCTUns 2.0 network simulator and emulator, which is being widely used by network and communication researchers. More information about the tool is available at http://NSL.csie.nctu.edu.tw/nctuns.html. C.H. Hwang received his master degree in computer science from NCTU in 2002 and currently is working for a network company. C.L. Chou currently is a third-year Ph.D. student at the Department of Computer Science and Information Engineering, National Chiao TungUniversity (NCTU), Taiwan. He received his master degree in computer science from NCTU in 2002.     

A power-driven multiplication instruction-set design method for ASIPs

This paper presents a novel power-driven multiplication instruction-set design method for application-specific instruction-set processors (ASIPs). Based on a dual-and-configurable-multiplier structure, our proposed method devises a multiplication instruction set for low-power ASIPs. Our method exploits the execution sequences of multiplication instructions and effective bit widths of variables to reduce power consumed by redundant multiplication bits while minimizing the multiplication execution time. Experimental results on a set of DSP programs demonstrate that our proposed method achieves significant power reduction (up to 18.53%) and execution time improvement (up to 10.43%) with 18% area overhead.     

Curved Projection Integral Imaging Using an Additional Large‐Aperture Convex Lens for Viewing Angle Improvement

In this paper, we propose a curved projection integral imaging system to improve the horizontal and vertical viewing angles. The proposed system can be easily implemented by additional use of a large‐aperture convex lens in conventional projection integral imaging. To obtain the simultaneous display of 3D images through real and virtual image fields, we propose a computer‐generated pickup method based on ray optics and elemental images, which are synthesized for the proposed system. To show the feasibility of the proposed system, preliminary experiments are carried out. Experimental results indicate that our system improves the viewing angle and displays 3D images simultaneously in real and virtual image fields.     

Data retention characteristics of MANOS-type flash memory device with different metal gates at various levels of charge injection

We investigated the impact of charge injection and metal gates (Al and Pt) on the data retention characteristics of metal–alumina–nitride–oxide–silicon (MANOS) devices for NAND flash memory application. Through the theoretical and experimental results, the highly injected charge (ΔV_TH) could cause the band bending of Al₂O₃, which reduced the tunneling distance across Al₂O₃. Thus, the dominant charge loss path is not only toward SiO₂ but also toward Al₂O₃ direction. Compared to low-metal work function (Ф_M), ONA stack with high-Ф_M showed better data retention characteristics, even if ΔV_TH is high. This could be explained by Fermi level alignment for different Ф_M, which results in the reduction of electric field across the Al₂O₃ compensated by the ΔФ_M (Ф_Pt ? Ф_Al).