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141.
Silicon - A composite prepared from titanium (IV) silsesquioxane and phosphoric acid (TTiP) was prepared and occluded into the H-FAU zeolite (ZTTiP). The material was chemically modified with... 相似文献
142.
Barros Benaia Gonçalves de França Freitas Ana Dolores Santiago de Tabosa José Nildo Lyra Maria do Carmo Catanho Pereira de Mergulhão Adália Cavalcanti do Espirito Santo Silva Aleksandro Ferreira da Oliveira Wagner da Silva Fernandes-Júnior Paulo Ivan Sampaio Everardo Valadares de Sá Barretto 《Nutrient Cycling in Agroecosystems》2020,117(1):93-101
Nutrient Cycling in Agroecosystems - The association between sorghum and N2-fixing bacteria has been assessed only under limited conditions. We investigated biological nitrogen fixation (BNF) in... 相似文献
143.
Evelyn Alves Nunes Simonetti Thais Cardoso de Oliveira Ádamo Enrico do Carmo Machado Amanda Alvarenga Coutinho Silva Alan Silva dos Santos Luciana de Simone Cividanes 《Ceramics International》2021,47(13):17844-17876
The development of highly selective, stable, and sensitive materials for the various gas emissions is a challenging task concerning the numerous applications: environmental control, security systems, energy, and, more recently, biological monitoring. One of the major challenges to reach this activity's requirements is developing nanostructured functional and smart materials that can selectively detect and monitor the gases at high temperatures. The semiconductor materials based on metallic oxides have gained increasing attention within this scenario, especially titanium dioxide (TiO2), due to their excellent properties. The literature presents multiple sensors based on TiO2 nanoparticles to detect various gases: CO, ethanol, benzene, toluene, NO2, O2, CO, SO2, NOx, NH3, Cl2, H2S, alkanes, among others. This review initially explores some aspects of TiO2 and its properties regarding the sensor sensitivity's influence. Then, the insertion of noble metals (Ag, Pt, Au, and Ru) and carbon structures (graphene, carbon nanotube, and other carbon forms) was also explored in the search to improve the TiO2 capacity as a gas sensor. This review focuses on the most significant achievements related to TiO2 and TiO2 combined with carbon structures or noble metals for gas sensor applications. Several studies were presented, highlighting the synthesis methods employed, the sensor response/recovery times, and some detection mechanisms after the carbon and noble metal insertion. Finally, the influence of a triple combination between TiO2-carbon-metal was also explored. 相似文献
144.
Nakamura Ana Paula Rizzato Fernandes Daniela Silvestrini Vieira Eduardo Guimarães Filho Newton Luis Dias do Carmo Devaney Ribeiro 《SILICON》2021,13(1):221-229
Silicon - This study describes an organofunctionalization of 3-chloropropyl silica gel (SG) with 5-amino-1,3,4-thiadiazolyl-2-thiol, and was characterized by spectroscopic techniques as infrared... 相似文献
145.
Olivier Dumont Carolina Carmo Valentin Fontaine François Randaxhe Sylvain Quoilin Vincent Lemort 《Journal of Building Performance Simulation》2018,11(1):19-35
This paper presents an innovative technology that can be used to deliver more renewable electricity production than the total electrical consumption of a building while covering the heat demand on a yearly basis. The technology concept uses a heat pump (HP), slightly modified to revert its cycle and generate electricity, coupled to a solar thermal collector roof. This reversible HP/organic Rankine cycle unit presents three operating modes: direct heating, HP and organic Rankine cycle. This work focuses on describing the dynamic model of the multi-component system followed by a techno-economic analysis of the system under different operational conditions. Sensitivity studies include: building envelope, climate, appliances, lighting and heat demand profiles. It is concluded that the HP/ORC unit can turn a single-family house into a PEB under certain weather conditions (electrical production of 3012?kWh/year and total electrical consumption of 2318?kWh/year) with a 138.8?m2 solar roof in Denmark. 相似文献
146.
Trama-Freitas Bianca Franco Fernanda Martins Rui C. Gando-Ferreira Licínio M. Quinta-Ferreira Maria Emília Quinta-Ferreira Rosa Maria do Carmo Devaney R. 《SILICON》2021,13(1):259-265
Silicon - The presence of heavy metals in water is one of the major concerns in the public health area. So, the characterization of inorganic compounds toxicity and their detection, speciation and... 相似文献
147.
do Carmo Devaney Ribeiro Barbosa Priscila Fernanda Pereira Junior Suelino Gabriel 《SILICON》2021,13(3):799-811
Silicon - Octa(3-aminopropyl)octasilsesquioxane and DAB-AM-16 dendrimer, due to their specific chemical and physical properties, give wide application in various fields of science. Because they... 相似文献
148.
149.
PS/EPDM blends prepared by in situ‐polymerization of styrene in the presence of EPDM are immiscible and show two phases. Furthermore, the dynamic mechanical behavior of injected specimens is quite different from that of noninjected blends. This is attributed to the differences in morphology before and after injection molding. The morphology of the noninjected blends consists of PS spherical domains covered by a thin layer of EPDM, whereas the injected blends show elastomeric dispersed phase morphology in a rigid matrix. SEM analysis was important to elucidate the changes in the dynamic mechanical behavior of PS/EPDM blends, but TEM analysis is more precise for morphological characterization and yielded the real average diameter of EPDM particles. Comparing the average diameters for the PS/EPDM blends obtained from SEM and TEM analyses, the diameters obtained from the SEM analysis are wider than those of TEM which is due to the solvent extraction effect on the blend morphology. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
150.
Fabiana Pires de Carvalho Maria do Carmo Gonçalves Maria Isabel Felisberti 《应用聚合物科学杂志》2012,124(4):2846-2856
In this study, the structural and morphological properties of poly(methyl methacrylate)/poly(acrylonitrile‐g‐(ethylene‐co‐propylene‐co‐diene‐g‐styrene) (PMMA‐AES) blends were investigated with emphasis on the influence of the in situ polymerization conditions of methyl methacrylate. PMMA‐AES blends were obtained by in situ polymerization, varying the solvent (chloroform or toluene) and polymerization conditions: method A—no stirring and air atmosphere; method B—stirring and N2 atmosphere. The blends were characterized by infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and dynamic mechanical analysis (DMA). The results showed that the PMMA‐AES blends are immiscible and present complex morphologies. This morphology shows an elastomeric dispersed phase in a glassy matrix, with inclusion of the matrix in the elastomer domains, suggesting core shell or salami morphology. The occlusion of the glassy phase within the elastomeric domains can be due to the formation of graft copolymer and/or phase inversion during polymerization. However, this morphology is affected by the polymerization conditions (stirring and air or N2 atmosphere) and by the solvent used. The selective extraction of the blends' components and infrared spectroscopy showed that crosslinked and/or grafting reactions occur on the elastomer chains during MMA polymerization. The glass transition of the elastomer phase is influenced by morphology, crosslinking, and grafting degree and, therefore, Tg depends on the polymerization conditions. On the other hand, the behavior of Tg of the glassy phase with blend composition suggests miscibility or partial miscibility for the SAN phase of AES and PMMA. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献