On the fire resistance of structural steel elements derived from standard fire tests or by calculation

Due to high costs, a fire resistance test of a load-bearing structural element is usually limited to one test specimen — in a few countries, to two test specimens. Accordingly, there are no possibilities of evaluating the test results statistically.For a single test specimen, the actual quality of the structural material represents a random sample from a wide variety. This applies also to the initial imperfections of the structural elements. In consequence of this, a standard fire resistance test is generally carried out on a test specimen with a load-bearing capacity which is greater — most often significantly greater — than the load-bearing capacity related to the characteristic values of the mechanical material strength and of the imperfections of the structural member. In current practice, no corrections of the test results with respect to this are made.In a conventional analytical design, a determination of the load-bearing capacity of a structure at room temperature conditions is based on the characteristics values of the strength and imperfections. Extended to a structural fire engineering design, this procedure will give an analytically determined fire resistance of a load-bearing structural element which is lower — normally essentially lower — than the corresponding value derived from a standard fire resistance test.Available methods for a simplified calculation of the temperature of fire exposed steel structures are, as a rule, based on the assumption of a uniformly distributed temperature structure at each time of fire exposure. The ECCS Recommendations for an analytical design of steel structures exposed to a standard fire follow this kind of approach. For certain types of steel structures, for example, beams with a slab on the upper flange, a considerable temperature variation arises over the cross section as well as in the longitudinal direction during a fire resistance test. A simplified, analytical method, which neglects this influence, gives a further underestimation of the fire resistance in relation to the corresponding result obtained in a standard fire resistance test.The described discrepancies between an analytical and an experimental determination of the fire resistance are further discussed and analysed in Sections 2 and 3, with particular reference to different types of steel structures. The discussion is focussed on the loading and restraint conditions, the scatter of material properties and geometrical imperfections, and the temperature variation over the structure or structural element. The discussion is summarized in Section 4 and alternative methods of correction are outlined briefly for obtaining an improved consistency between the analytical and the experimental approaches.In Section 5, one of these methods is further developed to a design basis which can be applied easily in practice. Principally, the method is characterized by a correction of the analytically determined load-bearing capacity, based on the characteristic value of the structural material properties, the characteristic value of the imperfections of the structure, and a uniformly distributed steel temperature across and along the structure. Two different sequences of the design procedure are dealt with, defined according to Figs. 10 and 11. The resultant correction factors, ? and κ, belonging to the respective sequences, are given by Figs. 8 and 12 for columns, isostatic beams, and hyperstatic beams. The straight line curves in Figs. 9 and 13 show corresponding, simplified relationships for the ? and κ factors.The derived method of correction must be characterized as an approximate approach. This is in consequence of the present state of knowledge, which does not allow a solution of high accuracy. The task to develop a correction procedure which leads to improved consistency between an analytically and an experimentally determined fire resistance, should also be seen in the context of the inadequate reproducibility of the standard fire resistance test.     

Preparation of compounds A2CuCl4−xBrx (A=K,Rb,NH4,Tl; x=0,1,2) and crystal structures of compounds Rb2CuCl4−xBrx with ordered distribution of the anions

The systems AX-CuX₂ (A=K,Rb,NH₄,Tl; X=Cl,Br,I) have been surveyed in search of compounds A₂CuX₄ having the K₂NiF₄ or a related structure. For compounds A₂CuX_4?xX′_x, where x=1,2 and X′ is a halogen ion larger than X, and having such a structure, it is expected that a special ordering exists between the X and X′ anions. The compounds Rb₂CuCl₄,Rb₂CuCl₃Br and Rb₂CuCl₂Br₂ are found to crystallize in the (NH₄)₂CuCl₄ structure which is related to the K₂NiF₄ structure. The expected ordering between C1 and Br ions is demonstrated.     

Pathways of sulfide oxidation by haloalkaliphilic bacteria in limited-oxygen gas lift bioreactors

Physicochemical processes, such as the Lo-cat and Amine-Claus process, are commonly used to remove hydrogen sulfide from hydrocarbon gas streams such as landfill gas, natural gas, and synthesis gas. Biodesulfurization offers environmental advantages, but still requires optimization and more insight in the reaction pathways and kinetics. We carried out experiments with gas lift bioreactors inoculated with haloalkaliphilic sulfide-oxidizing bacteria. At oxygen-limiting levels, that is, below an O(2)/H(2)S mole ratio of 1, sulfide was oxidized to elemental sulfur and sulfate. We propose that the bacteria reduce NAD(+) without direct transfer of electrons to oxygen and that this is most likely the main route for oxidizing sulfide to elemental sulfur which is subsequently oxidized to sulfate in oxygen-limited bioreactors. We call this pathway the limited oxygen route (LOR). Biomass growth under these conditions is significantly lower than at higher oxygen levels. These findings emphasize the importance of accurate process control. This work also identifies a need for studies exploring similar pathways in other sulfide oxidizers such as Thiobacillus bacteria.     

Social acceptance of carbon dioxide storage

This article discusses public acceptance of carbon capture and storage (CCS). Responses by citizens are described in relation to responses by professionally involved actors. Interviews with members of the government, industry and environmental NGOs showed that these professional actors are interested in starting up storage projects, based on thorough evaluation processes, including discussions on multi-actor working groups. As appeared from a survey among citizens living near a potential storage site (N=103), public attitudes in general were slightly positive, but attitudes towards storage nearby were slightly negative. The general public appeared to have little knowledge about CO₂-storage, and have little desire for more information. Under these circumstances, trust in the professional actors is particularly important. NGOs were found to be trusted most, and industry least by the general public. Trust in each of the three actors appeared to depend on perceived competence and intentions, which in turn were found to be related to perceived similarity of goals and thinking between trustee and trustor. Implications for communication about CCS are discussed.     

Repetition Estimation

International Journal of Computer Vision - Visual repetition is ubiquitous in our world. It appears in human activity (sports, cooking), animal behavior (a bee’s waggle dance), natural...     

A novel,efficient route for the crosslinking and creep improvement of high modulus and high strength polyethylene fibres

A new route is presented for the chemical crosslinking of solution‐spun, ultra‐drawn Ultra‐High‐Molecular‐Weight Polyethylene (UHMW‐PE) fibres. UHMW‐PE fibres with a range of draw ratio's, Young's moduli and tensile strengths were impregnated with a radical initiator using supercritical carbon dioxide as a carrier. After impregnation, the drawn fibres were crosslinked with ultra‐violet light and fibres with a high gel content (> 90%) were obtained. It was found that the chemical crosslinking strongly reduces the plateau creep rate of the fibres and that the threshold stress for irreversible creep is enhanced. Simultaneously, the high Young's modulus and the high tensile strength of the drawn fibres are preserved which illustrates that the long term properties of the fibres (i. e. creep) are improved without a large sacrifice short term mechanical properties such as Young's modulus.     

MATCHING UNEMPLOYMENT AND VACANCIES IN REGIONAL LABOR MARKETS: AN EMPIRICAL ANALYSIS FOR THE NETHERLANDS

ABSTRACT In this paper we analyze regional developments in unemployment and vacancies in the Netherlands during the 1980s. Our purpose is to establish to what extent the differences in unemployment and vacancy rates are due to difference in regional labor market performance. The analysis is carried out by considering labor market dynamics using the concept of the matching function. We find a constant returns to scale matching function with coefficients of 0.25 for unemployment and 0.75 for vacancies. Efficiency rises substantially during the recession in the beginning of the 1980s. Regional differences in efficiency appear to be small for most regions, suggesting that a reduction in regional unemployment should by stimulating regional labor demand.     

Affordances, perceptual complexity, and the development of tool use.

Perceiving the affordance of a tool requires the integration of several complementary relationships among actor, tool, and target. Higher order affordance structures are introduced to deal with these forms of complex action from an ecological-realist point of view. The complexity of the higher order affordance structure was used to predict the difficulty of perceiving the tool function. Predictions were tested in 3 experiments involving children between 9 mo and 4 yrs old. In a classical tool use task dating back to W. K?hler (1921), a desirable target was obtained by using a hook as a tool. The relative positions of the hook and the target were systematically varied to obtain structures differing in complexity. The observed difficulty of the task was found essentially in accordance with the theoretical complexity of the higher order affordance structures involved in perceiving the tool function. (PsycINFO Database Record (c) 2010 APA, all rights reserved)