转轮式分级器切割粒径的预测模型

针对转轮式分离器,建立不同结构参数及操作参数下的切割粒径预测模型有助于指导其设计和运行。基于相似理论以及对颗粒分离过程的分析,提出一种考虑结构参数的半经验模型,确定了模型参数,并通过实验以及文献报道的数据验证了模型的可靠性。与前人工作相比,此模型在不同的转轮分离器结构下显示出较好的通用性;此外,模型可以复现切割粒径随叶轮转速增大而先减小后增大的非单调关系,这是原有的半理论模型不能实现的。对不同结构转轮分离器性能的系统分析表明,较大的分离器入口面积及较小的导流角度可确保入口产生强旋流气流,进而使切割粒径对转速的敏感段在低转速区;而较小的分离器入口面积,或较高的入口风速可以提高对细颗粒的分离能力。对运行参数的研究表明,增大颗粒流率会减小切割粒径;调整叶轮转速可以灵活地改变切割粒径,适应不同的工作需求。     

甘肃塔哇地区水系沉积物地球化学特征及找矿效果

为了快速缩小找矿范围,提供有利靶区,在甘肃塔哇地区开展了1∶50 000水系沉积物测量工作。通过对水系沉积物地球化学参数特征、元素分布特征及其元素的相关性分析,圈定单元素异常571个,综合异常22处。结合地质工作成果优选出了3处金银找矿远景区,且已发现多个金银矿(化)体,为工作区内的找矿工作打下良好的基础。     

Synthesis and characterization of composite visible light active photocatalysts MoS2–g-C3N4 with enhanced hydrogen evolution activity

Molybdenum disulfide (MoS₂) and graphitic carbon nitride (g-C₃N₄) composite photocatalysts were prepared via a facile impregnation method. The physical and photophysical properties of the MoS₂–g-C₃N₄ composite photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microcopy (HRTEM), ultraviolet–visible diffuse reflection spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectroscopy. The photoelectrochemical (PEC) measurements were tested via several on–off cycles under visible light irradiation. The photocatalytic hydrogen evolution experiments indicate that the MoS₂ co-catalysts can efficiently promote the separation of photogenerated charge carriers in g-C₃N₄, and consequently enhance the H₂ evolution activity. The 0.5wt% MoS₂–g-C₃N₄ sample shows the highest catalytic activity, and the corresponding H₂ evolution rate is 23.10 μmol h⁻¹, which is enhanced by 11.3 times compared to the unmodified g-C₃N₄. A possible photocatalytic mechanism of MoS₂ co-catalysts on the improvement of visible light photocatalytic performance of g-C₃N₄ is proposed and supported by PL and PEC results.     

Regioselective acylation of pyridoxine catalyzed by immobilized lipase in ionic liquid

The regioselective acylation of pyridoxine catalyzed by immobilized lipase (Candida Antarctica) in 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF₆) has been investigated, and compared with that in acetonitrile (ACN). The acetylation of pyridoxine using acetic anhydride in [BMIM]PF₆ gave comparable conversion of pyridoxine to 5-monoacetyl pyridoxine with considerably higher regioselectivity (93%–95%) than that in ACN (70%–73%). Among the tested parameters, water activity (a _w) and temperature have profound effects on the reaction performances in either [BMIM]PF₆ or ACN. For the reaction in [BMIM] PF₆, higher temperature (50°C–55°C) and lower a _w (<0.01) are preferable conditions to obtain better conversion and regioselectivity. Mass transfer limitation and intrinsic kinetic from the ionic nature of ionic liquids (ILs) may account for a different rate-temperature profile and a lower velocity at lower temperature in [BMIM]PF₆-mediated reaction. Moreover, consecutive batch reactions for enzyme reuse also show that lipase exhibited a much higher thermal stability and better reusability in [BMIM]PF₆ than in ACN, which represents another advantage of ILs as an alternative to traditional solvents beyond green technology.     

KOH活化焦油渣制备活性炭的研究

以武钢焦化公司焦油渣为原料,KOH为活化剂,采用正交实验研究了活化温度、活化时间、碱炭比（氢氧化钾与焦化除尘灰的质量比）和炭化温度对所制活性炭吸附性能的影响,得出制备焦油渣基活性炭影响因素主次顺序为活化温度、活化时间、碱炭比、炭化温度,最佳活化条件为活化温度为800℃,活化时间为100min,碱炭比为4：1,炭化温度为400℃。在此条件下制备活性炭的碘吸附值为1300．765mg／g。     

Assembly of 4‐Substituted 3‐Nitro‐1,2,3,4‐tetrahydropyridines via Organocatalytic Michael Addition

An organocatalytic Michael addition of protected 2‐amino‐1‐nitroethanes to α,β‐unsaturated aldehydes followed by treatment with TFA afforded 4‐substituted 3‐nitro‐1,2,3,4‐tetrahydropyridines with good diastereoselectivity and excellent enantioselectivity. Good yields were observed in the case of β‐aryl‐substituted α,β‐unsaturated aldehydes as the substrates, while moderate yields were obtained when β‐alkyl‐substituted α,β‐unsaturated aldehydes were used.     

伊通墙材在钢结构住宅中的应用

主要介绍了伊通产品在钢结构住宅中的应用优势,分析了伊通产品在不同钢结构建筑形式和部位的一些应用问题.研究表明,伊通轻质加气混凝土产品具有自重轻、保温防火性能好等优点,是钢结构住宅理想的配套材料.已经形成了成熟的生产和应用技术体系,并且开发了一系列的专用配套材料.     

Production of Cell Membrane-Bound α- and β-Glucosidase by Lactobacillus acidophilus

Hydrolytic enzymes, viz. α- and β-glucosidase, were produced from indigenous isolate, Lactobacillus acidophilus, isolated from fermented Eleusine coracana. Production of these enzymes was enhanced by optimizing media using one factor at a time followed by response surface methodology. The optimized media resulted in a 2.5- and 2.1-fold increase in α- and β-glucosidase production compared with their production in basal MRS medium. Localization studies indicated 80% of the total activity to be present in the cell membrane-bound fraction. Lack of sufficient release of these enzymes using various physical, chemical, and enzymatic methods confirmed their unique characteristic of being tightly cell membrane bound. Enzyme characterization revealed that both α- and β-glucosidase exhibited optimum catalytic activity at 50 °C and pH 6.0 and 5.0, respectively. K _m and V _max of α-glucosidase were 4.31 mM and 149 μmol min⁻¹ mL⁻¹ for p-nitrophenyl-α-d-glucopyranoside as substrate and 3.8 mM and 120 μmol min⁻¹ mL⁻¹ for β-glucosidase using p-nitrophenyl-β-d-glucopyranoside as the substrate.     

装配式轻钢框架-复合轻墙结构抗震性能试验研究

为适应装配式建筑在村镇低层住宅结构发展的需求,提出了一种装配式轻钢框架-复合轻墙结构。该结构由轻钢框架作为竖向承重体系,单排配筋再生混凝土薄墙板作为抗侧力构件与轻钢框架共同抵抗水平地震作用,再生混凝土薄墙板复合EPS保温模块和粉煤灰砌块层形成保温墙体。通过4个装配式轻钢框架-复合轻墙结构和1个轻钢空框架的低周反复荷载试验,分析了墙板分布钢筋间距和墙体构造形式(是否复合粉煤灰砌块层)对该结构抗震性能的影响。研究结果表明：轻钢框架与单排配筋再生混凝土薄墙板协同工作良好,结构具有明确的两道抗震防线,由于复合EPS保温模块和粉煤灰砌块,实现了抗震节能一体化;减小墙板分布钢筋间距和复合粉煤灰砌块层可显著提高结构承载力和延性。基于JGJ 138—2016《组合结构设计规范》及相关文献,给出了装配式轻钢框架-复合轻墙结构的受剪承载力计算式,计算结果与试验结果符合较好。