Studies on engineering properties of PVC–PMMA semi‐interpenetrating polymer networks

Semi1 and semi2 interpenetrating polymer networks (IPNs) of PVC and in situ formed PMMA have been synthesized using diallyl phthalate and ethylene glycol dimethacrylate as the crosslinkers of PVC and PMMA, respectively. These two types of IPNs have been compared w.r.t their physical, mechanical, and thermal properties and an endeavor has been made to find a correlation of these properties with the morphology generated in these systems. The semi1 IPNs displayed a decrease in their mechanical parameters and the physical properties as well, while in contrast, the semi2 IPNs exhibited a marginal increase in the corresponding values after an initial drop upto about 15% of crosslinked PMMA incorporation when compared to the crosslinked PVC in the case of semi1 IPN and linear PVC in the case of semi2 IPN. The various samples of semi1 and semi2 IPNs showed a two‐stage degradation typical of PVC, while confirming the increased stability with the samples having higher percentages of PMMA. The influence of crosslinking of the major matrix in semi1 IPN was almost counterbalanced by the influence of crosslinking in the dispersed PMMA phase in the case of semi2 IPN. The softening characteristics as detected by the extent of penetration of the probe, as has been detected by thermomechanical analysis, are in conformity with their mechanicals. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1725–1735, 2005     

一种高效又经济的混炼方法——在配方中添加塑解剂Acimel

一种高效又经济的混炼方法———在配方中添加塑解剂ＡｃｉｍｅｌＤｒ．ＣｈａｋｒａｂｏｒｔｙＳ（ＩＣＩＩｎｄｉａＬｉｍｉｔｅｄ）橡胶是一种弹性体，相对分子质量比较高，在加工温度下有较高的粘度。若不加入配合剂，橡胶本身是无法使用的。由于要加入的配合剂大多...     

Measurement of AC conductivity and dielectric properties of flexible conductive styrene–butadiene rubber‐carbon black composites

Flexible conductive polymer composites were prepared using styrene–butadiene rubber (SBR) as a matrix and conductive carbon black as filler. The filler loading was varied from 10 to 60 phr. The effect of frequency, filler loading, temperature, and applied pressure on the AC conductivity, permittivity, and loss factor of the composites was studied. The AC conductivity of low and high loaded composites was found to be frequency dependent and independent respectively. The permittivity and the loss factor were continuously decreasing with increasing frequency. The increase in filler loading increased the AC conductivity, dielectric constant, and loss factor of the composites. Increase in temperature imposed increase in conductivity and permittivity of the composites. With increasing applied pressure the properties showed exponential increase. The effect of time under a constant compressive stress was studied and dielectric relaxation times were evaluated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 986–995, 2007     

Epoxy/poly(methyl methacrylate) interpenetrating polymer networks—morphology,mechanical and thermal properties

Full and semi-IPNs were prepared from epoxy and poly methyl methacrylate (PMMA), by the sequential mode of synthesis and were characterized by measurements of ultimate tensile strength (UTS), elongation at break, modulus, and toughness. Aromatic polyamine adducts and ethylene glycol dimethacrylate were used as the crosslinkers for epoxy and comonomer/crosslinker for methyl methacrylate monomer, respectively. Higher UTS and modulus of the semi-IPNs over full IPNs were attributed to the higher probability of interpenetration. The weight retention in the thermal decomposition of the IPNs and semi-IPNs were higher than the epoxy homopolymer. This enhancement was presumably related to the presence of the unzipped methyl methacrylate monomer which acted as radical scavangers in the epoxy degradation. © 1994 John Wiley & Sons, Inc.     

Oxidation of Hf2SnC and Nb2SnC in Air in the 400–600°C Temperature Range

The oxidation behavior in air of fully dense, predominantly (92+vol.%) single phase, samples of Nb₂SnC and Hf₂SnC was studied in the 400–600°C temperature range. The oxidation products in both cases were SnO, SnO₂ and either Nb₂O₅ or HfO₂. The oxidation is characterized by an initial incubation period, the duration of which decreased with increasing temperatures, followed by a period of near-linear oxidation kinetics. Oxidation at temperatures as low as 400°C for 72 hr resulted in the total disintegration of bulk samples, and their total conversion to oxides. Comparison with published results indicate that the oxidation kinetics of Hf₂SnC are poorer than those of Hf or HfC. Similarly, Nb₂SnC is more prone to oxidation than pure Nb metal.     

Emotion Recognition From Facial Expressions and Its Control Using Fuzzy Logic

This paper presents a fuzzy relational approach to human emotion recognition from facial expressions and its control. The proposed scheme uses external stimulus to excite specific emotions in human subjects whose facial expressions are analyzed by segmenting and localizing the individual frames into regions of interest. Selected facial features such as eye opening, mouth opening, and the length of eyebrow constriction are extracted from the localized regions, fuzzified, and mapped onto an emotion space by employing Mamdani-type relational models. A scheme for the validation of the system parameters is also presented. This paper also provides a fuzzy scheme for controlling the transition of emotion dynamics toward a desired state. Experimental results and computer simulations indicate that the proposed scheme for emotion recognition and control is simple and robust, with good accuracy.     

A comparative study on the metaheuristic-based optimization of skew composite laminates

Engineering with Computers - Plate structures are the integral parts of any maritime engineering platform. With the recent focus on composite structures, the need for optimizing their design and...     

Self-consistent non-linear physics based predictive model for the computation of THz-signal attenuation in fog with varying visibility in tropical climatic zone

Microsystem Technologies - Absorptive and dispersive properties of atmospheric hydrometeors, affect the propagation of millimetre-wave and submillimeter wave signals. In adverse weather condition,...     

HSWOA: An ensemble of hunger games search and whale optimization algorithm for global optimization

The search for food stimulated by hunger is a common phenomenon in the animal world. Mimicking the concept, recently, an optimization algorithm Hunger Games Search (HGS) has been proposed for global optimization. On the other side, the Whale Optimization Algorithm (WOA) is a commonly utilized nature-inspired algorithm portrayed by a straightforward construction with easy parameters imitating the hunting behavior of humpback whales. However, due to minimum exploration of the search space, WOA has a high chance of trapping into local solutions, and more exploitation leads it towards premature convergence. The concept of hunger from HGS is merged with the food searching techniques of the whale to lessen the inherent drawbacks of WOA. Two weights of HGS are adaptively designed for every whale using the respective hunger level for balancing search strategies. Performance verification of the proposed hunger search-based whale optimization algorithm (HSWOA) is done by comparing it with 10 state-of-the-art algorithms, including three very recently developed algorithms on 30 classical benchmark functions. Comparison with some basic algorithms, recently modified algorithms, and WOA variants is performed using IEEE CEC 2019 function set. Statistical performance of the proposed algorithm is verified with Friedman's test, boxplot analysis, and Nemenyi multiple comparison test. The operating speed of the algorithm is determined and tested with complexity analysis and convergence analysis. Finally, seven real-world engineering problems are solved and compared with a list of metaheuristic algorithms. Numerical and statistical performance comparison with state-of-the-art algorithms confirms the efficacy of the newly designed algorithm.     

Thin film evaporation in microchannels with interfacial slip

We investigate the role of interfacial slip on evaporation of a thin liquid film in a microfluidic channel. The effective slip mechanism is attributed to the formation of a depleted layer adhering to the substrate–fluid interface, either in a continuum or in a rarefied gas regime, as a consequence of intricate hydrophobic interactions in the narrow confinement. We appeal to the fundamental principles of conservation in relating the evaporation mechanisms with fluid flow and heat transfer over interfacial scales. We obtain semi-analytical solutions of the pertinent governing equations, with coupled heat and mass transfer boundary conditions at the liquid–vapor interface. We observe that a general consequence of interfacial slip is to elongate the liquid film, thereby leading to a film thickening effect. Thicker liquid films, in turn, result in lower heat transfer rates from the wall to liquid film, and consequently lower mass transfer rates from the liquid film to the vapor phase. Nevertheless, the total mass of evaporation (or equivalently, the net heat transfer) turns out to be higher in case of interfacial slip due to the longer film length. We also develop significant physical insights on the implications of the relative thickness of the depleted layer with reference to characteristic length scales of the microfluidic channel on the evaporation process, under combined influences of the capillary pressure, disjoining pressure, and the driving temperature differential for the interfacial transport.