Profile of Triacylglycerols,Phenols, and Vitamin E of Manjari Medika Grape Seed Oil and Cake: Introducing a Novel Indian Variety

The aim of the study is to investigate the biochemical composition of grapeseed oil and cake from an unexplored Indian grape‐juice cultivar, Manjari Medika (MM). The composition of oil and residual seed cake is evaluated using various chromatographic and spectroscopic techniques. The findings demonstrate that the vitamin E content of MM‐seed oil (1.15–1.35 g kg^?1) is distinctively higher than the Codex standard, suggesting its superior quality as an edible oil. The predominant triacylglycerols include trilinolein (LLL, 43%), dilinoleoyl‐stearylglycerol (LSL, 19%), and dilinoleoyl‐palmitoylglycerol (LLP, 11%), which are earlier recognized as natural antioxidants. The seed‐cake is rich in polyphenols including acylated anthocyanins (e.g., pelargonidin‐3‐O‐coumaroyl glucoside) and certain other flavonoids (e.g., catechin). The profile of phytonutrients in MM seed‐oil and cake is significantly superior to its seeded female parent and two other widely cultivated wine‐grape varieties. In brief, the studied by‐products of this new grape‐juice cultivar can be an important source of high‐value ingredients for use in food supplements, nutraceuticals, and functional foods. Practical applications: This study reports the phytochemical profile of the seed‐oil and seed cake derived from a newly developed grape variety, Manjari Medika. High contents of selective antioxidants: lipids, vitamin E, and phenols in the seed‐oil and cake with health benefits suggest their potential for use in nutraceutical and functional foods. These byproducts can be utilised as ingredients of functional foods and nutraceuticals (e.g., grape seed oil capsule) and also as raw materials in food supply chains (e.g., for production of grape cookies or cake). MM can also be utilized as a colorant in the food industry.     

Identification of monofloral honey using voltammetric electronic tongue

Quality assessment of honey is often related to its floral origin which is a complex task to evaluate. Traditional technique of floral assessment is made by melissopalynological method. However, this method is quite time consuming and also often operator dependent. Thus, the fallout is a large range of error in interpretation of the result and hence there is considerable demand for instrumental methods to assess the identification of pollen in honey. In this pursuit, an electronic tongue based on cyclic voltammetry is developed to discriminate honey samples based on their floral types and is described in this paper. The technique has been investigated using platinum as the working electrode and the resultant current from the potentiostat has been considered for data analysis. The use of principal component analysis (PCA) and linear discriminate analysis (LDA) proves to be useful in clustering honey samples. Finally, classification performances are investigated using back-propagation multilayer perceptron (BP-MLP) and radial basis function (RBF) neural network models for identification of different floral origin of honey.     

Capillary forces between sediment particles and an air-water interface

In the vadose zone, air-water interfaces play an important role in particle fate and transport, as particles can attach to the air-water interfaces by action of capillary forces. This attachment can either retard or enhance the movement of particles, depending on whether the air-water interfaces are stationary or mobile. Here we use three standard PTFE particles (sphere, circular cylinder, and tent) and seven natural mineral particles (basalt, granite, hematite, magnetite, mica, milky quartz, and clear quartz) to quantify the capillary forces between an air-water interface and the different particles. Capillary forces were determined experimentally using tensiometry, and theoretically assuming volume-equivalent spherical, ellipsoidal, and circular cylinder shapes. We experimentally distinguished between the maximum capillary force and the snap-off force when the air-water interface detaches from the particle. Theoretical and experimental values of capillary forces were of similar order of magnitude. The sphere gave the smallest theoretical capillary force, and the circular cylinder had the largest force due to pinning of the air-water interface. Pinning was less pronounced for natural particles when compared to the circular cylinder. Ellipsoids gave the best agreement with measured forces, suggesting that this shape can provide a reasonable estimation of capillary forces for many natural particles.     

Effect of steam environment on severe core damage behaviour for VVER-1000 with the ASTEC V1 code

Severe accident studies for very low frequency events for VVER-1000 (V320) are carried out to estimate in-vessel damage progression under steam-rich and starved conditions. The analyses with code ASTEC, jointly developed by IRSN (France) and GRS, Germany), have shown the influence of steam environment on core heat-up followed by material relocation, hydrogen production, vessel failure and aerosol generation along with release to containment. Hydro-accumulator injection for studied transients also gives rise to a steam-rich environment enhancing the material oxidation depending on the injection time and period. The generated information along with PSA-Level 2 is helpful to decide Plant Damage State (PDS) and fruitfully develop accident management strategies for the plant.     

Characterization of Cu-SiO2 Composite Synthesized by Hydrogen Reduction of Chalcopyrite Concentrate Followed by Acid Leaching

A Ghatshila chalcopyrite concentrate (average particle size, 50 μm) containing primarily CuFeS₂ and SiO₂ (Cu 16 pct, Fe 26 pct, S 14 pct, Si 5 pct, and O 33 pct) was reduced by a stream of hydrogen in a horizontal tube furnace at 1323 K (1050 °C), producing a mixture of Cu (26 pct), SiO₂, Fe₂O₃, Fe₃O₄, Cu₂O, and Fe. Subsequent acid leaching with 1 M HCl solution of the reduction product removed all iron oxides and iron, and other impurities too, leaving a Cu (53.3 pct) + SiO₂ mixture, with a small percentage of Cu₂O in it. This result compares well with the predicted final mixture of Cu (59 pct)-SiO₂ based on a mass balance on the starting concentrate. Elemental chemical analyses were done by energy-dispersive X-ray spectroscopy, which were crosschecked by atomic absorption spectroscopy in the majority of cases. The phase identification and microstructural characterization of Cu-SiO₂ mixtures were done by X-ray diffraction, Fourier transform infrared spectroscopy, Rietveld analysis, scanning electron microscopy, and high-resolution transmission electron microscopy (HRTEM). It was found that Cu-SiO₂ composites were formed in the final product, with a copper grain size of 385 nm.     

Investigation of Eccentric Open Eye Formation in a Slab Caster Tundish

Metallurgical and Materials Transactions B - Inert gas shrouding in tundish can result in the formation of a tundish open eye (TOE) due to the presence of reversed flows on the upper surface of the...     

Template-free synthesis of flower-shaped zero-valent iron nanoparticle: Role of hydroxyl group in controlling morphology and nitrate reduction

Well-dispersed single phasic flower-like zero valent iron nanoparticles have been synthesized under aerobic conditions using a facile approach without the addition of any additives or templates. The role of hydroxyl groups of polyhydroxy alcohols in controlling surface morphology of nanoparticles has been thoroughly investigated. The obtained nanoparticles have been characterized by TEM, FE-SEM, XRD and BET surface area analyzer. Electron microscopy analyses reveal that the solvent plays a pivotal role in determining the morphology of the particles. With increase in viscosity of the solvent, formations of ‘petal-like’ structures, which are joined at the center are formed. The nitrate removal efficiency of the iron nanoparticles synthesized in different solvents has been studied and it is seen that the “flower-like” iron nanoparticles were most active in the removal of nitrate. Experiments have been done by varying (i) nitrate concentrations, (ii) nanoparticle dose, and (iii) type of nanoparticles. The results conclude that highest removal efficiency (～100%) was achieved when the nanoparticle dose was 2.88 g/L, even for high nitrate concentrations up to 400 mg/L. The major highlight of this work is the fact that even though the nanoparticles synthesized in glycerol-water mixture have larger size in comparison to the other nanoparticles, still they remove the nitrates with highest efficiency.”     

0.40% Bipolar Strain in Lead Free BNT–KNN System Modified with Li,Ta and Sb

In this work we demonstrate a large electric field‐induced bipolar strain ~0.40% in Li, Ta and Sb modified BNT–KNN ((1?x) Bi_0.5Na_0.5TiO₃–xK_0.47Na_0.47Li_0.06 Nb_0.74Sb_0.06Ta_0.2O₃) system. The morphotropic phase boundary (MPB) of the system between rhombohedral and tetragonal phases lies in the range 0.02 ≤ x ≤ 0.06, beyond which all compositions (up to x < 0.15) were found to be tetragonal. A clear trade‐off between the large strain values and achievable d₃₃, k_p for a particular composition was noted. It is shown that while for x = 0.03, d₃₃ 169 pC/N, k_p 49% and strain ~0.13% were obtained, for x = 0.08 with 0.40% strain, d₃₃ and k_p values decreased drastically.     

Exploring the Influence of Methylene Diphenyl Diisocyanate as a Modifier for Ethylene Vinyl Acetate/Thermoplastic Polyurethane Blends

Ethylene vinyl acetate (EVA)/thermoplastic polyurethane (TPU) blend at various blend ratios has been modified via reactive processing with 4,4′-methylene diphenyl diisocyanate (MDI). Modification of the blends with even small amount of MDI shows significant improvement in physico-mechanical properties for EVA/TPU 50/50 and 30/70 blends, and it is also supported by the superior melt rheological behavior and dramatic improvement in oil resistance property. After the treatment of electron beam (dose range: 50–150?kGy), radiation crosslinked EVA/TPU (30:70) blend reveals further improvement in various properties. This particular material can find potential application as cable sheathing component.