Research on the friction and wear mechanism of Poly(vinyl alcohol)/hydroxylapatite composite hydrogel

Poly(vinyl alcohol)/Hydroxylapatite (PVA/HA) composite hydrogel was prepared with poly(vinyl alcohol) and hydroxylapatite as raw materials, using the method of repeated freezing and thawing. The morphologies of PVA/HA composite hydrogel were observed by means of high-accuracy 3D profiler and scanning electron microscope (SEM). The compressive elastic modulus and the stress relaxation characteristics of PVA/HA composite hydrogel were measured using the flat-head cylinder indenter. The friction and wear tests between PVA/HA composite hydrogel and bovine knee articular cartilage were performed on the micro-tribometer. The worn morphologies of PVA/HA composite hydrogel were observed with environmental scanning electron microscope (ESEM). The results showed that PVA/HA composite hydrogel has the cross-link network microstructure which is similar to that of the natural bovine knee articular cartilages. With the increase of freezing-thawing cycles and the HA content, the degree of cross-link and the crystallization of PVA/HA composite hydrogel both increase, the elastic modulus increases evidently, the rate of stress relaxation is improved and the value of balance stress decreases. The friction coefficient decreases with the increase of the freezing-thawing cycles and the HA content. The more the freezing-thawing cycles are, the earlier the friction coefficient reaches the stable balance value. The friction deformation depth between PVA/HA composite hydrogel and bovine knee articular cartilage is inversely proportional to freezing-thawing cycles and the HA content. The main wear mechanisms of PVA/HA composite hydrogel are plastic flowing and adhesive flaking. The wear severity degree decreases with the increase of freezing-thawing cycles and the HA content. Supported by Key Program of the National Natural Science Foundation of China (Grant No. 50535050), Program for New Century Excellent Talents in University (Grant No. NCET-06-0479) and Natural Science Foundation of Jiangsu Province (Grant No. BK2005403)     

A macro-meso constitutive law for concrete having imperfect interface and nonlinear matrix

The overall behavior of concrete depends on its meso structures such as aggregate shape, interface status, and mortar matrix property. The two key meso structure characters of concrete, bond status of interface and nonlinear property of matrix, are considered in focus. The variational structure principle is adopted to establish the macro-meso constitutive law of concrete. Specially, a linear reference composite material is selected to make its effective behavior approach the nonlinear overall behavior of concrete. And the overall property of linear reference composite can be estimated by classical estimation method such as self-consistent estimates method and Mori-Tanaka method. This variational structure method involves an optimum problem ultimately. Finally, the macro-meso constitutive law of concrete is established by optimizing the shear modulus of matrix of the linear reference composite. By analyzing the constitutive relation of concrete established, we find that the brittleness of concrete stems from the imperfect interface and the shear dilation property of concrete comes from the micro holes contained in concrete. Supported by the National Natural Science Foundation of China (Grant Nos. 50679022, 90510017, 50539090) and National Basic Research Program of China (Grant No. 2007CB714104)     

Discrimination for ablative control mechanism in solid-propellant rocket nozzle

The ablation in solid-propellant rocket nozzle is a coupling process resulted by chemistry, heat and mass transfer. Based on the heat and mass transfer theory, the aero-thermo-dynamic, and thermo-chemical kinetics, the thermal-chemical ablation model is established. Simulations are completed on the heat flow field and chemical ablation in the nozzle with different concentrations, frequency factors and activation energy of H2. The calculation results show that the concentration and the activation energy of H...     

陶瓷原料中二氧化硅分析方法的对比与选择

本文综合各种文献 ,对陶瓷原料中SiO2 的各种分析方法的优缺点 ,使用条件 ,应用侧重点进行了比较与评述     

LogGAN: a Log-level Generative Adversarial Network for Anomaly Detection using Permutation Event Modeling

Information Systems Frontiers - System logs that trace system states and record valuable events comprise a significant component of any computer system in our daily life. Each log contains...     

Stability Analysis for Time-delay Systems via a Novel Negative Condition of the Quadratic Polynomial function

This paper studies the stability analysis problem for time-varying delay systems. An appropriate Lyapunov-Krasovskii functional (LKF) is constructed where its derivative is a quadratic polynomial function of the delay. A novel negative condition of the mentioned quadratic function with two variable parameters is developed to ensure that the LKF derivative is negative, reducing conservatism on some similar results. Besides, an extended version of Bessel-Legendre inequality is introduced to be employed in the stability analysis of time-varying delay systems. Then, some stability criteria with less conservatism are derived for two kinds of the time-varying delay. Finally, the effectiveness of the proposed stability criteria is demonstrated through three examples.

     

Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

Optimization of uncertain acoustic metamaterial with Helmholtz resonators based on interval model

Uncertainties existing in the acoustic metamaterial may strongly affect its unusual properties. Aiming at this actuality, the interval model is introduced to treat with uncertainties existing in the acoustic metamaterial with Helmholtz resonators. Frequency intervals in which the sound intensity transmission coefficients are certainly less than the required value and the effective bulk moduli are certainly negative are defined as conservative approximations. Frequency intervals in which the sound intensity transmission coefficients may be less than the required value and the effective bulk moduli may be negative are defined as unsafe approximations. The proportion of the conservative approximation and the unsafe approximation is defined as an approximate precision. Based on the quantification of uncertainties of the sound intensity transmission coefficients and the negative effective bulk moduli, an optimization model for the interval acoustic metamaterial with Helmholtz resonators is constructed. Numerical results showed that even suffering from effects of interval parameters, unusual properties of the optimized acoustic metamaterial (such as the bandgap of the sound transmission and the negative effective bulk modulus) could be improved.     

Performance evaluation of anti-radiation based on the gamma degradation process

In the environment of space radiation, the high-energy charged particles or high-energy photons acting on a spacecraft can cause either temporary device degradation or permanent failure. The traditional probability model is difficult to obtain reliable estimation of unit radiation resistance performance with small samples. Considering that different products will change differently after high-energy particle radiation, we construct a model based on the gamma degradation process. This model can efficiently describe the law of unit radiation resistance variation with the total radiation dose levels under the effect of the total dose and displacement damage. Finally, the proposed model is used to assess the anti-radiation performance of the N-channel power MOSFET device STRH60N20FSY3 produced by STM to obtain average unit radiation resistance, survival probability, survival function, etc.     

Theoretical Investigation of the Viscous Damping Coefficient of Hydraulic Actuators

The viscous damping coefficient(VDC) of hydraulic actuators is crucial for system modeling,control and dynamic characteristic analysis.Currently,the researches on hydraulic actuators focus on behavior assessment,promotion of control performance and efficiency.However,the estimation of the VDC is difficult due to a lack of study.Firstly,using two types of hydraulic cylinders,behaviors of the VDC are experimentally examined with velocities and pressure variations.For the tested plunger type hydraulic cylinder,the exponential model B=αυ~(-β),(α0,β0)or B=α_1e~(-β_1υ)+α_2e~(-β_2υ)(α_1,α_20,β_1,β_20),fits the relation between the VDC and velocities for a given pressure of chamber with high precision.The magnitude of the VDC decreases almost linearly under certain velocities when increasing the chamber pressure from 0.6 MPa to 6.0 MPa.Furthermore,the effects of the chamber pressures on the VDC of piston and plunge type hydraulic cylinders are different due to different sealing types.In order to investigate the VDC of a plunger type hydraulic actuator drastically,a steady-state numerical model has been developed to describe the mechanism incorporating tandem seal lubrication,back-up ring related friction behaviors and shear stress of fluid.It is shown that the simulated results of VDC agree with the measured results with a good accuracy.The proposed method provides an instruction to predict the VDC in system modeling and analysis.