Effect of particle size on coal char----NO reaction

Surface nitrogen complex formation upon reaction of coal char with NO at 600°C was studied by X-ray photoelectron spectroscopy. Particle size had a noticeable effect on the magnitude of changes, which was observed on the surface of the coal char in the nitrogen functional group. The surface increased its -NO, pyridine-N-oxide, and -NO₂ functional group contents with a decrease in particle size. The chemisorption processes of NO molecules on the char were simulated using the ab initio Hartree–Fock method and density functional theory. Molecular modeling was applied to determine the thermodynamics of the reactions. Mechanisms were proposed to explain the formation of the -NO, pyridine-N-oxide, and -NO₂ functional groups at 600°C.     

Nanobarrier-terminated growth of single-walled carbon nanotubes on quartz surfaces

Using carbon nanotubes as nanobarriers, the growth of single-walled carbon nanotubes (SWNTs) on a quartz surface can be terminated. First, carbon nanotube nanobarriers were grown on a quartz surface by the gas flow-directed growth mode. Then, the SWNTs were grown on the quartz surface via the lattice-oriented growth mode, in which growth of SWNTs can be terminated by hitting the nanotube nanobarriers. Moreover, using the carbon nanotube nanobarrier as a marker, the mechanism of the growth of SWNTs on the quartz surface can be studied; a base-growth mechanism is indicated. Based on this termination process and the base-growth mechanism, SWNT arrays with controlled lengths can be grown on a quartz surface by fixing the sites of both catalysts and nanobarriers.      

Sr掺杂量对La_(1-x)Sr_xMnO_(3-δ)离子导电性能的影响

本文从La1 -xSrxMnO3-δ材料的缺陷结构出发 ,探讨了材料在高温条件下离子 (氧离子 )导电的形成机制。分析了Sr掺杂量对氧离子导电性的影响 ,发现当Sr掺杂量x =0 .5时 ,La1 -xSrxMnO3-δ材料的离子电导率达到最大 ,因为在这一掺杂浓度时 ,材料中形成了最佳的氧空 (氧离子 )传输通道。     

碳纳米管

概述了碳纳米材料的发展及它们的性能和应用,同时介绍了一些比较成熟的制备纳米材料的技术。在此基础上分析了碳纳米管的形成过程和碳纳米管的微观结构,以及碳纳米管制备工艺对微观结构的影响。     

An author co-citation analysis of information science in China with Chinese Google Scholar search engine, 2004–2006

Author co-citation analysis (ACA) is an important method for discovering the intellectual structure of a given scientific field. Since traditional ACA was confined to ISI Web of Knowledge (WoK), the co-citation counts of pairs of authors mainly depended on the data indexed in WoK. Fortunately, Google Scholar has integrated different academic databases from different publishers, providing an opportunity of conducting ACA in wider a range. In this paper, we conduct ACA of information science in China with the Chinese Google Scholar. Firstly, a brief introduction of Chinese Google Scholar is made, including retrieval principles and data formats. Secondly, the methods used in our paper are given. Thirdly, 31 most important authors of information science in China are selected as research objects. In the part of empirical study, factor analysis is used to find the main research directions of information science in China. Pajek, a powerful tool in social network analysis, is employed to visualize the author co-citation matrix as well. Finally, the resemblances and the differences between China and other countries in information science are pointed out.     

Characterization and photoluminescence studies of CdTe nanoparticles before and after transfer from liquid phase to polystyrene

The major objective of this work was to detect the change of photoluminescence (PL) intensity of CdTe nanoparticles (NPs) before and after transfer from liquid phase to polystyrene (PS) matrix by electrospinning technique. Thio-stabilized CdTe NPs were first synthesized in aqueous, then enwrapped by cetyltrimethylammonium bromide (CTAB), and finally, transferred into PS matrix to form CdTe/PS nanofibres by electrospinning. Then, CdTe/PS nanofibres were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM) to observe their morphology and distribution, respectively. The selective area electronic diffraction (SAED) pattern proved that the CdTe NPs were cubic lattice. The PL spectrum indicated that CdTe NPs have been transferred into PS nanofibres, and the PL intensity of CdTe NPs in the nanofibres was even higher than that before CdTe NPs were introduced into PS nanofibres. Moreover, X-ray photoelectron spectra (XPS) revealed that thiol-stabilized CdTe NPs were enwrapped by CTAB, and PS acted as a dispersant in the process of electrospinning.     

基于MOOSE平台的棒状燃料元件性能分析程序开发与验证

为实现对压水堆棒状燃料元件的精细化模拟,本文基于有限元平台MOOSE开发了棒状燃料元件性能分析程序BEEs。针对程序的燃耗、氧化层厚度和燃料温度模块分别进行了对比验证,采用BR3 Rod实验算例验证了长期稳态工况下BEEs程序的整体分析功能。结果表明,BEEs程序能获得合理准确的模拟结果,初步具备了稳态工况燃料性能分析能力。     

基于MOOSE框架的五方程两相流分析程序开发

基于多物理场耦合框架MOOSE,采用五方程两相流模型开发了模块化程序ZEBRA,实现了高阶时间、空间离散格式两相流动传热问题的求解。采用Bartolomei开展的垂直圆管过冷沸腾实验对ZEBRA进行验证,在不同热流密度、质量流密度、压力工况下,将程序计算值与实验值进行了数值验证和计算分析。结果表明：ZEBRA中五方程模型预测值与实验值符合良好,沸腾起始点和空泡份额的预测合理,表明ZEBRA初步具备了处理两相流问题的能力。     

光谱式MEMS/CMOS兼容气敏传感器

光谱技术是化学分析的终极手段. 将光谱技术与MEMS (micro-electro-mechanical systems）和CMOS技术结合是解决当前气敏传感器灵敏度低、选择性差、体积大、功耗高、不便于阵列化和高度集成以至于无梯度立体矢量探测能力等问题的有效手段. 本文介绍了一种制作于（110）硅片上的集成光谱式MEMS/CMOS兼容气敏传感器,详述了该气敏传感器的工作原理、传感器结构和制造工艺.