The mechanism of CO oxidation over Cu(110): Effect of CO gas energy

The effect of the temperature of gas phase CO upon the kinetics of the oxygen titration reaction: CO_g +O_a CO_2,g, has been studied. It is found that the reaction's rate is independant of CO gas temperature between 300 and 623 K. The activation energy (6.5 kcal/mole), dependence upon CO pressure (first-order), and independence upon oxygen coverage for 0.1 _o 0.4 are all independant of the CO gas phase temperature. This result rules out any Eley-Rideal type mechanism whereby CO reacts directly from the gas phase with an oxygen adatom without first being accommodated to the surface temperature in an absorbed state. The result is instead interpretable in terms of a Langmuir-Hinshelwood mechanism.Camille and Henry Dreyfus Foundation Teacher-Scholar Fellowship.     

Extensions of principle component analysis with applications on vision based computing

This paper mainly focuses on the principle component analysis (PCA) and its applications on vision based computing. The underlying mechanism of PCA given and several significant factors, involved with subspace training are discussed theoretically in detail including principle components energy, residuals assessment, and decomposition computation. The typical extensions, including probabilistic PCA (PPCA), kernel PCA (KPCA), multi-dimensional PCA and robust PCA (RPCA), have been presented with critical analysis on both mechanisms and computations. Combining with the studies on, such as, image compression, visual tracking, image recognition and super-resolution image reconstruction, PCA and its extensions applied to computer vision are critically reviewed and evaluated on the targeted issues in each application as well as the role they played at specific tasks to the characteristics, cost and suitable situations of each PCA based vision processing technique.     

Upper Bounds on Number of Steals in Rooted Trees

Inspired by applications in parallel computing, we analyze the setting of work stealing in multithreaded computations. We obtain tight upper bounds on the number of steals when the computation can be modeled by rooted trees. In particular, we show that if the computation with n processors starts with one processor having a complete k-ary tree of height h (and the remaining n ? 1 processors having nothing), the maximum possible number of steals is \({\sum }_{i=1}^{n}(k-1)^{i}\binom {h}{i}\).     

A study of the graphical mediating representations used by collaborating authors

Abstract

Though they have access to sophisticated authoring support systems, many authors use conventional media for the earliest stages of generating and organising ideas. This paper gives an overview of a study of six pairs of collaborating authors who were videoed in aprewriting task and who also underwent a structured post-interview concerning their use of external representations in the study and in their everyday work. Pairs were studied so that the behaviour was more externalised, there were natural verbal protocols and these protocols could be interpreted by the interlocutor rather than by the researcher. The analysis focuses on the part that the mediating representations play in the cognitive task and in coordinating cooperative cognition. The properties of the marks produced and the affordances of conventional media are considered. The study is interpreted within a ‘shared cognitive’ framework which draws on insights from distributed cognition, socially shared cognition, situated action and most importantly from Soviet psychology. It is suggested that the mediating representations perform two important and highly related functions. First, they support ‘idea sketching’ which is a form of reflexive communication where the individual mediates her own creative cognition through external representations. Second, they mediate cooperative cognition, providing the common grounding necessary to coordinate shared thought.     

Automatic bandwidth selection for circular density estimation

Given angular data θ₁,…,θ_n∈[0,2π) a common objective is to estimate the density. In case that a kernel estimator is used, bandwidth selection is crucial to the performance. A “plug-in rule” for the bandwidth, which is based on the concentration of a reference density, namely, the von Mises distribution is obtained. It is seen that this is equivalent to the usual Euclidean plug-in rule in the case where the concentration becomes large. In case that the concentration parameter is unknown, alternative methods are explored which are intended to be robust to departures from the reference density. Simulations indicate that “wrapped estimators” can perform well in this context. The methods are applied to a real bivariate dataset concerning protein structure.     

Parallel and distributed simulation of sediment dynamics in shallow water using particle decomposition approach

This paper describes the parallel simulation of sediment dynamics in shallow water. By using a Lagrangian model, the problem is transformed to one in which a large number of independent particles must be tracked. This results in a technique that can be parallelised with high efficiency. We have developed a sediment transport model using three different sediment suspension methods. The first method uses a modified mean for the Poisson distribution function to determine the expected number of the suspended particles in each particular grid cell of the domain over all available processors. The second method determines the number of particles to suspend with the aid of the Poisson distribution function only in those grid cells which are assigned to that processor. The third method is based on the technique of using a synchronised pseudo-random-number generator to generate identical numbers of suspended particles in all valid grid cells for each processor. Parallel simulation experiments are performed in order to investigate the efficiency of these three methods. Also the parallel performance of the implementations is analysed. We conclude that the second method is the best method on distributed computing systems (e.g., a Beowulf cluster), whereas the third maintains the best load distribution.     

GaP/GaNP Heterojunctions for Efficient Solar‐Driven Water Oxidation

The growth and characterization of an n‐GaP/i‐GaNP/p⁺‐GaP thin film heterojunction synthesized using a gas‐source molecular beam epitaxy (MBE) method, and its application for efficient solar‐driven water oxidation is reported. The TiO₂/Ni passivated n‐GaP/i‐GaNP/p⁺‐GaP thin film heterojunction provides much higher photoanodic performance in 1 m KOH solution than the TiO₂/Ni‐coated n‐GaP substrate, leading to much lower onset potential and much higher photocurrent. There is a significant photoanodic potential shift of 764 mV at a photocurrent of 0.34 mA cm^?2, leading to an onset potential of ≈0.4 V versus reversible hydrogen electrode (RHE) at 0.34 mA cm^?2 for the heterojunction. The photocurrent at the water oxidation potential (1.23 V vs RHE) is 1.46 and 7.26 mA cm^?2 for the coated n‐GaP and n‐GaP/i‐GaNP/p⁺‐GaP photoanodes, respectively. The passivated heterojunction offers a maximum applied bias photon‐to‐current efficiency (ABPE) of 1.9% while the ABPE of the coated n‐GaP sample is almost zero. Furthermore, the coated n‐GaP/i‐GaNP/p⁺‐GaP heterojunction photoanode provides a broad absorption spectrum up to ≈620 nm with incident photon‐to‐current efficiencies (IPCEs) of over 40% from ≈400 to ≈560 nm. The high low‐bias performance and broad absorption of the wide‐bandgap GaP/GaNP heterojunctions render them as a promising photoanode material for tandem photoelectrochemical (PEC) cells to carry out overall solar water splitting.