Equilibrium Moisture Characteristics of High Oleic Sunflower Seeds and Kernels

The equilibrium moisture content (EMC) characteristics of high oleic sunflower seeds and kernels between 10 and 55°C were determined by equilibrating the samples to known relative humidities (RH) above saturated salt solutions. EMC of the kernels was lower than that of seeds in the range of 11 to 96% ERH and at 25 and 40°C. Hysteresis effect was found for the EMC properties of seeds and kernels at 25°C. Four EMC-ERH models (modified Henderson, Chung-Pfost, Halsey, and Guggenheim-Anderson-de Boer) and their estimated parameters were evaluated for goodness of fit. GAB and Halsey equations showed the best fitting of experimental data although GAB equation adjusted for temperature described the EMC data the best. Components of the seed as oil content or hull/kernel ratio did not explain the slight differences in EMC found between the varieties.     

Short-term frequency stability of clock generators for multigigahertz rapid-single-flux quantum digital circuits

Superconducting digital systems based on Josephson junctions have generally used a synchronous timing strategy. A master clock signal is used to delimit a data window during which the system changes state and data is transferred from one block to the next. The temporal stability of the clock signal has a profound effect on the performance of rapid single flux quantum (RSFQ) digital systems. In particular, short-term clock fluctuations, or clock jitter, can degrade system performance due to the hazard of timing constraint violations. The successful development of large-scale RSFQ digital systems will require highly stable multigigahertz on-chip clock sources. To meet this need, methods for characterizing and measuring the short-term stability of such sources are required. We identify the relevant figure of merit to characterize and compare various clocks: the cycle-to-cycle standard deviation of the clock periods. We present experimental techniques for the measurement of this figure of merit and apply them to the measurement of jitter in a clock generator used often in RSFQ systems, the ring oscillator. High-frequency phase noise measurements found the jitter of a 9.6-GHz clock to be in the range from 0.6% to 0.36% of the clock period. The measured values of clock jitter fell within the 95% confidence interval of our stochastic circuit simulations. This was sufficient evidence to conclude that thermal noise from the resistors in the circuit may be the dominant source of jitter in the ring oscillator.     

Nanoscale Crystallization in the Amorphous Alloy Fe79P14.2Si4.4Mn2.2V0.2 upon Pulsed Photon Annealing

The effect of pulsed photon annealing with energy densities from 1.4 to 42 J/cm² for various lengths of time on the structure of the amorphous alloy Fe₇₉P_14.2Si_4.4Mn_2.2V_0.2 was studied by x-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The results demonstrate that short-term irradiation with low energy densities leads to surface relaxation of the amorphous alloy, increases the strength of the surface layer, and reduces the internal-friction peak. Longer term photon annealing leads to crystallization of the alloy throughout the sample thickness.     

A kinetic model for the acid-oxygen pressure leaching of Ni–Cu matte

A semi-empirical mathematical model for the acid-oxygen pressure leaching of Ni–Cu matte is presented, based on data from batch leaching experiments. The primary controlling factor in the leaching process is found to be galvanic inhibition of the more highly oxidized copper and nickel sulfide species by less oxidized species, particularly Ni alloy and Ni₃S₂. The leaching rate of many species is greatly reduced by the presence of one or both of these phases, and others will not commence leaching until neither is present. The mathematical model is based on first-order chemical reaction controlled rate expressions, as the reactions occurring are electrochemical in nature. Mass transfer effects are included only empirically. Some possibly diffusion-related phenomena are noted, although the model is not extended to incorporate these effects on a fundamental level. The model is verified and extended by the inclusion of several different factors that were tested experimentally. The effects of variations in O₂ flow rate and partial pressure, initial particle size, reaction pulp density and initial acid concentration were all studied, and included in the model. Variations in O₂ flow rate and partial pressure are found to affect the reaction rates via the dissolved oxygen concentration in the solution phase.     

Defect-free sintering of two material powder injection molded components Part II Model

A defect-free, two-material component can be obtained via co-sintering by suitably altering the powder characteristics or compositions, as demonstrated in Part I. In this paper, a model to ascertain the suitability of material systems to be co-sintered without defects such as delamination or interface pores is presented. The model is based on the management of the stress induced due to the difference in shrinkage and an analysis of the in situ strength of the weaker material during sintering. Tool steel in combination with stainless steel admixed with boron and Fe-2Ni admixed with boron are two systems used to validate the model. The predictions of the model are in good agreement with the observations.     

Presenting information on the small-screen interface: effects of table formatting

This study explored strengths and limitations of table formatting choices by engaging twenty-eight participants in information searches in online tables, presented on a small-screen interface (Palm IIIc). Table length across conditions was held constant at three screens long (24 rows total) but varied from one to three screens wide (approximately 35, 70, and 105 characters per line). Target information was positioned in either the upper left, lower left, upper right, or lower right quadrants. Data collected were time on task, error rate, and level of participants' confidence in their answers. Experimenters found that increased horizontal scrolling imposed the heaviest burden on information search. This study supports restricting table widths to one screen on handheld computers. If necessary, however, tables can go to two screens wide without critical detriment to usability. While ruled line formatting is slightly better than interface character in providing visual support for the burden of horizontal scrolling, neither formatting option adequately compensates for the added burden.     

Influence of the Transport Properties of the Crystal/Heat Transfer Surface Interfacial on Fouling Behavior

One method to reduce fouling is to extend the induction time by a defined modification of the interfacial interactions between the heat transfer surface and the crystalline deposit. Since these interactions are a result of both molecular and mechanical forces, two approaches for fouling mitigation have been developed: (a) Modification of the energy related properties of the heat transfer surface and (b) Modification of the geometry related properties of the heat transfer surface.     

Characterisation of K, Na, and Li birnessites prepared by oxidation with H2O2 in a basic medium. Ion exchange properties and study of the calcined products

Birnessites containing Na, K or Li in the interlayer have been prepared by oxidation of Mn(II) cations with H₂O₂ in a basic medium with different alkaline cation/Mn molar ratios. The solids prepared have been characterised by elemental chemical analysis, powder X-ray diffraction, thermal analyses (differential thermal analysis and thermogravimetric analysis), FT-IR spectroscopy and surface texture assessment by adsorption of N₂ at –196°C. Crystalline birnessites are obtained for A/Mn ratios (A = K, Li) larger than 3.4, but MnO(OH) has been also identificed when such a ratio is smaller than 3.4. Ion exchange is topotactic, but is not complete for exchanging Na, K, or Mg for pre-existing Li. The solids are stable up to 400°C, and formation of spinels and solids with tunnel structures is observed at this temperature. Li-containing birnessites are transformed to LiMn₂O₄ spinel at 400°C, and co-crystallization of bixbyte (Mn₂O₃) is observed at higher temperatures. Bixbyte and cryptomelane are formed at 500°C for the K-containing birnessites.     

Fundamentals of oscillator performance

The oscillator is arguably the most essential part of any communication system: it defines a channel frequency, or timing and synchronisation in a digital system. The phase noise of any oscillator has a fundamental lower limit. It limits the achievable efficiency of spectrum use and degrades the error rate in practical applications. Any low-noise oscillator can be described as a positive-feedback Q-multiplier circuit. Such a model shows that phase noise is minimised if the square of the effective circuit Q and the signal-to-noise ratio in the oscillator are maximised. This simple fact is true for all oscillators and it provides the basis for more efficient and lower noise designs