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811.
Residence time and time of production were investigated during the enzymatic production of a specific structured lipid/human milk fat substitute (SL-HMFS), on a kg scale, made from lard and soybean oil fatty acids, using a packed-bed reactor and short path distillation. There were no effects of residence time or time of production on C18:2 and C18:3 incorporation or on acyl migration in the
sn -2 position. In addition, the SL-HMFS was compared to commercial human milk fat substitute (HMFS) regarding fatty acid composition, content of antioxidants and oxidative stability. Fats were stored at 60 °C for four days and the oxidative stability evaluated by analysis of peroxide value (PV) and volatile secondary oxidation products. SL-HMFS had a lower oxidative stability than did commercial HMFS products or lard, probably due to a lower level of tocopherol in SL-HMFS.
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812.
Low-fat and non-fat cream cheeses were produced with variations in pH (4.4, 4.7, 5.0), salt concentration (0.4%, 0.65%, 0.9%) and fat content (0%, 3%, 6%, 9%). The cheeses were evaluated by four spectroscopic methods; fluorescence spectroscopy, near infrared spectroscopy (NIR), fourier transform infrared spectroscopy (FT-IR) and low-field nuclear magnetic resonance relaxometry (LF-NMR), to identify and describe the variation in cream cheeses induced by the experimental variables. The four methods complemented each other and gave somewhat different information about the products. Only LF-NMR was affected by all three design parameters and showed that high pH and high salt content made the low-fat samples resemble samples with higher fat content, with respect to water mobility. The sensory parameter, creaminess, could be predicted from the spectroscopic measurements, where NIR and FT-IR performed the best in the chemometric models. The spectra measured by these methods contained more information related to creaminess, but the use of a larger number of components indicated that the information was complex.
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813.
Both satellite Planck and Herschel are cryogenic ones [1] and [2], the first one having a cold point around 0.1 K, the second one around 0.3 K. Not only are the detectors cooled, but also major subsystems and systems of the spacecrafts.The Centre Spatial de Liège (CSL) is involved in testing several parts of these spacecrafts [3], starting form optical tests on the mirrors or on the telescope, via cryogenic vibration testing of scientific focal plane instruments, ending with the full Planck spacecraft testing. Each test requires temperature lower than 20 K, in volumes ranging from 1 m
3 to 60 m
3 , cooling several kilograms to more than one ton, and withstanding heat load up to 150 W in stabilisation.The overall Planck spacecraft test challenge is very high, as it is the only way to measure the end-to-end cooling chain of the spacecraft. The space conditions reproduction must be as perfect as possible to avoid the test set-up influence on the spacecraft performances, especially linked to radiative cooling, mechanical perturbations and Helium residual pressure.Different challenges are presented, and the related CSL solutions are described, highlighting the Helium partial pressure problem, the related computations and trapping system by large sorption panel.
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814.
CH lines in the solar spectrum have been identified by direct comparison of measured laboratory and solar wavelengths and intensities. The comparisons of individual rotational lines are included in a series of tables arranged according to electronic and vibrational transitions.A detailed investigation of the presence of CH lines in the solar spectrum has been carried out recently as part of the preparation of a current edition of solar spectrum data to replace the 1928 compendium [
1 ].
1 Along with the study of atomic lines, a parallel survey of molecules in the sun is required for any complete revision of the “Solar Spectrum.” A preliminary résumé of the number of CH, OH, and CN lines in the solar spectrum was recently published [
2 ].Many lines of CH are familiar features in the solar spectrum. In his original table, Rowland [
3 ] attributed some of these lines to “C,” and numerous CH lines were included in the 1928 edition [
1 ]. Several authors have carried the work further. For example, Hunaerts [
4 ] and Richardson [
5 ] have each published a list of solar lines which may be ascribed to CH.The present results are based on a study of the rotational structure of individual bands, together with relative laboratory intensities measured along the different branches. It reveals more CH lines in the sun than have been recognized heretofore. A summary of the counts is included in ] they referred to solar lines. Consequently, if two CH lines contribute to one solar line, each CH line is counted here as a blend. Exception has been made in the case of
Open in a separate window Table 5 CH in the Solar Spectrum A
2 Δ—X
2 Π (0, 1)
Laboratory Sun
Q1c Q1d Q2c Q2d R1cd R1dc R2cd R2dc Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 16 16 2 21150.36 4726.734 16 16 2 21141.13 4728.797 15 3 21098.50 4738.351 15 3 21098.30 4738.396 15 15 3 21090.29 4740.196 14 3 21047.63 4749.804 14 3 21047.18 4749.906 14 14 4 21040.28* 4751.463 13 3 20998.06 4761.118 13 3 20997.21* 4761.219 13 3 20991.33 4762.545 13 3 20991.07 4762.602 24 2 20952.79* 4771.305 12 4 20948.90 4772.189 12 4 20948.05 4772.384 12 4 20943.28 4773.470 12 4 20942.98 4773.538 24 1 20931.95 4776.054 23 2 20914.78* 4779.975 23 2 20912.79* 4780.429 11 4 20901.20 4783.081 11 4 20900.28 4783.292 23 11 4 20896.39 4784.181 23 11 4 20895.80 4784.317 22 1 20878.04 4788.386 22 2 20876.51 4788.737 22 22 1 20860.86 4792.330 10 4 20854.80 4793.724 10 4 20853.60 4793.999 10 4 20850.71 4794.663 10 4 20849.84 4794.862 21 1 20842.57 4796.536 21 1 20841.93 4796.684 21 21 1 20827.31 4800.050 9 4 20809.64 4804.164 20 20 9 6 20808.15 4804.472 9 4 20806.18 4804.925 9 4 20805.12 4805.171 20 2 20795.31 4807.437 20 2 20794.70 4807.578 19 19 3 20775.59 4812.001 8 5 20765.81* 4814.267 8 6 20764.24* 4814.630 19 2 20763.51 4814.800 19 8 7 20763.02* 4814.913 8 6 20761.64* 4815.233 18 18 4 20743.87 4819.359 18 2 20733.14 4821.853 18 2 20732.67 4821.962 7 5 20723.41 4824.117 7 7 7 20721.43 4824.577 7 5 20719.61 4825.001 17 17 4 20713.57 4826.409 17 3 20703.79 4828.687 17 3 20703.31 4828.800 16 3 20684.76 4833.131 16 3 20684.56 4833.177 6 4 20682.62 4833.630 6 5 20681.02 4834.004 6 6 20680.25 4834.185 6 5 20678.88 4834.505 16 16 5 20675.54* 4835.285 15 4 20657.22 4839.573 15 4 20656.75 4839.684 15 15 5 20648.92 4841.520 5 5 20643.44 4842.804 5 5 20642.36 4843.058 5 5 20640.66 4843.457 5 5 20639.68 4843.686 14 5 20631.09 4845.704 14 6 20630.61* 4845.817 14 14 6 20623.71 4847.438 13 6 20606.45* 4851.499 13 4 7 20605.89 4851.630 4 6 20605.36* 4851.755 4 5 20602.47 4852.435 4 5 20601.78 4852.598 13 13 6 20599.91 4853.038 12 5 20583.50 4856.908 12 6 20582.64* 4857.110 12 6 20577.87 4858.236 12 6 20577.42 4858.343 3 4 20570.66 4859.939 3 4 20570.13 4860.065 ‡ 1 20566.39 4860.949 3 6 20565.74 4861.103 3 6 20565.43 4861.176 11 5 20562.10 4861.963 11 6 20561.04 4862.213 11 6 20557.26 4863.107 11 6 20556.64 4863.255 10 6 20542.32 4866.644 10 6 20541.10 4866.932 10 6 20538.26 4867.606 10 2 2 8 20537.45 4867.799 4867.874 11.5 u + 0.075 Co i M ‡ 2 20531.58 4869.190 2 2 7 20530.44 4869.460 4869.469 4.1 u + 0.009 Fe i M 9 6 20524.30 4870.916 4870.94 0.8 + 0.02 Ni i M 9 6 20522.84 4871.263 A 9 6 20520.91 4871.721 4871.683 3.1 −0.038 A 9 6 20519.81 4871.982 4871.935 9.2 u −0.047 Fe i p M 1 1 5 20515.74 4872.950 A 8 6 20508.01 4874.786 4874.793 4.3 w? + 0.007 Ni i M 8 6 20506.31 4875.190 4875.198 0.6 + 0.008 CH? P 8 6 20505.26 4875.439 4875.492 8.4 S + 0.053 V i M 8 6 20503.87 4875.771 4875.739 0.7 −0.032 Fe i p M ‡ 3 20497.98 4877.172 1 1 7 20496.23* 4877.589 4877.590 4.3 u + 0.001 Fe i M 7 6 20493.48 4878.243 4878.225 24.2 w −0.018 Fe i M 7 7 9 20491.43 4878.730 4878.721 0.6 −0.009 CH P 7 G 20489.56 4879.175 4879.150 0.4 −0.025 CH? P 6 5 20480.80* 4881.262 4881.267 0.4 + 0.005 CH? P 6 6 20479.27* 4881.627 A 6 G 20478.34* 4881.849 A 6 7 20476.93* 4882.185 4882.148 13.9 u −0.037 Fe i M 5 5 20470.05 4883.826 A 5 5 20468.83 4884.117 A ‡ 1 20468.24 4884.258 5 6 20467.00 4884.555 4884.598 4.3 o + 0.043 Cr ii M 5 7 20465.98 4884.798 4884.803 1.5 + 0.005 CH?— B 4 5 20461.26 4885.924 4885.950 2.4 s + 0.026 Cr i M 4 ‡ 6 20460.46 4886.116 4886.086 0.2 −0.030 CH? P ‡ 1 20459.83 4886.266 ‡ 1 20458.12 4886.674 4 ‡ 7 20457.36* 4886.856 4886.845 0.6 s −0.011 V i —CH? B 4 6 20456.67* 4887.021 4887.009 12.9 s −0.012 ‖Cr i Ni i M 3 4 20454.60 4887.514 4887.533 1.0 + 0.019 M 3 4 20454.11 4887.631 A ‡ 1 20453.37 4887.808 2 2 ‡ 3 20450.57 4888.477 3 6 20449.34 4888.768 A 3 ‡ 6 20449.01 4888.850 4888.829 1.5 −0.021 —CH? B ‡ 1 20444.50 4889.930 2 2 4 20442.89* 4890.315 3 2 20367.91 4908.318 3 2 20367.11 4908.510 ‡ 1 20366.17 4908.737 ‡ 1 20365.41 4908.919 3 2 20361.98 4909.746 3 2 20361.46 4909.871 4 1 20345.30 4913.773 4 1 20344.31 4914.011 ‡ 1 20343.19 4914.283 4 2 20340.94 4914.827 4 2 20340.23 4914.997 5 2 20325.13 4918.650 5 2 20323.98 4918.927 ‡ 2 20323.26 4919.101 5 3 20321.82 4919.451 5 3 20320.85 4919.686 6 2 20307.32 4922.963 6 2 20305.76 4923.342 6 2 20304.63 4923.614 6 3 20303.26 4923.948 22 1 20301.04 4924.487 22 1 20299.58 4924.839 7 4 20291.61 4926.775 7 7 5 20289.45 4927.299 7 4 20287.51 4927.770 21 2 20285.93 4928.154 22 2 20285.35 4928.294 22 21 2 20284.55 4928.489 8 4 20277.97 4930.088 8 4 20276.17 4930.526 8 4 20275.20 4930.762 8 20 20 5 20273.67 4931.134 21 1 20272.33 4931.460 21 1 20271.16 4931.744 9 4 20266.41 4932.901 9 4 20264.88 4933.273 19 9 19 5 20263.12 4933.702 9 4 20261.84 4934.013 20 2 20260.69 4934.294 20 2 20260.04 4934.453 10 3 20256.94 4935.206 10 3 20255.70 4935.509 18 18 3 20254.61 4935.773 10 3 20252.96 4936.176 10 4 20251.99 4936.412 19 3 20251.35 4936.569 19 3 20250.77 4936.710 11 3 20249.64 4936.986 11 4 20248.49 4937.265 17 17 3 20248.07 4937.369 11 3 20244.80 4938.166 11, 18 12 4 20244.16 4938.321 12 18 16 5 20243.38 4938.511 16 3 20242.97 4938.613 13 3 20241.03 4939.085 15 3 20240.55 4939.202 13, 15 4 20240.22 4939.282 14 3 20239.85 4939.373 14 3 20239.26 4939.518 12 3 20238.70 4939.654 12, 17 17 4 20238.13 4939.792 13 3 20234.42 4940.700 13, 16 16 5 20234.21 4940.750 14, 15 14, 15 5 20232.34 4941.208
Open in a separate window * Blend.
‡ Satellite lines as follows:
Designation J Laboratory
Wave No. Wavelength
RQ 2c 1d ; RQ2d 1c 3; 3 20566.39 4860.949 RQ 2c 1d ; RQ2d 1c 2; 2 20531.58 4869.190 RQ 2c 1d ; RQ2d 1c 1; 1 20497.98 4877.172 QR 1 2d 5 20468.24 4884.258 QR 1 2d 4 20460.46 4886.116 QR 1 2d 4 20459.83 4886.266 QP 1 2d 4 20458.12 4886.674 QP 1 2d 4 20457.36 4886.856 QR 1 2c ; QR 1 2d 3; 3 20453.37 4887.808 QP 2 1c ; QP 2 1d 3; 3 20450.57 4888.477 QR 1 2c ; QR 1 2d 2; 2 20449.01 4888.850 QP 2 1c ; QP 2 1d 2; 2 20444.50 4889.930 PQ 1d 2c 3 20366.17 4908.737 PQ 1c 2d 3 20365.41 4908.919 PQ 1c 2d 4 20343.19 4914.283 PQ 1c 2d 5 20323.26 4919.101
Open in a separate window Table 10 CH in the Solar Spectrum C
2 Σ
+ —X
2 Π (0, 0)
Laboratory Sun
P1 P2 Q1 Q2 R1 R2 Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Rowl. est. ⊙—lab. A Solar identification Notes 26 0.2 32388.47 3086.622 3086.636 [−1] +0.014 M 26 0.2 32387.24 3086.739 3086.787 [ 4] +0.048 Co i A 25 0.25 32384.23 3087.027 3086.988 [−2] −0.039 M 25 0.25 32383.11 3087.133 A 24 0.35 32377.11 3087.705 3087.693 [−1] −0.012 M 24 0.35 32376.03 3087.809 3087.843 [ 0Nd?] +0.034 Co i —Cr ii ? M 23 0.5 32367.58 3088.615 3088.610 [−1] −0.005 M 23 0.5 32366.42 3088.725 3088.752 [ 2] +0.027 M 22 1 32355.73 3089.746 3089.745 [ 2] −0.001 OH M 22 1 32354.53 3089.860 3089.868 [ 2] +0.008 OH M 21 1.5 32341.55 3091.100 3091.071 [ 4] −0.029 Mg i M 21 2 32340.55 3091.196 3091.213 [ 1N] +0.017 CH OH‖ B 20 2 32325.75 3092.612 3092.598 [−3] −0.014 CH OH B 20 2.5 32324.78 3092.704 3092.712 [ 4] +0.008 Al i M 19 2.5 32308.24 3094.288 3094.295 [ 1] +0.007 CH— B 19 3.5 32307.55 3094.354 3094.364 [−1] +0.010 CH P 18 } 5
{ 32289.14 32288.60 3096.119 }3096.138 [ 2]
{ + 0.019 − 0.031 } OH Cr ii M 18 3096.169 17 } 6
{ 32268.92 32268.35 3098.058 3098.072 [ 0] +0.014 CH P 17 3098.113 A 16 } 8
{ 32247.47 32247.15 3100.119 }3100.150 [−1N]
{ + 0.031 + 0.001 } CH CH 16 3100.149 15 15 10 32224.58 3102.321 3102.299 [ 3] −0.022 CH—V ii B 14 14 11 32201.35 3104.559 3104.571 [ 2N] +0.012 CH—Ti ii ? B 13 13 13 32177.15 3106.894 3106.907 [ 1] +0.013 CH P 12 12 14 32152.07 3109.318 3109.333 [ 3] +0.015 OH CH B 11 11 14.5 32126.56 3111.786 3111.814 [ 2] +0.028 Fe i CH B 10 } 13.5
{ 32100.38 32100.05 3114.324 3114.316 [ 2] −0.008 Fe ii CH B 10 3114.356 3114.353 [ 1] −0.003 CH P 9 } 13.5
{ 32073.67 32073.16 3116.919 3116.917 [ 0] −0.002 CH P 9 8 3116.968 3116.982 [ 1] +0.014 CH P 9 32046.63 3119.548 3119.504 [ 3] −0.044 Fe i M 8 7 9 32045.49* 3119.659 3119.678 [ 1] +0.019 OH CH Cr i B 9 32019.32* 3122.209 3122.219 [ 0] +0.010 OH CH B 7 9 32018.18 3122.320 3122.317 [ 1] −0.003 Fe i CH B 6 11 31991.55 3124.920 3124.918 [ 2] −0.002 CH OH B 6 11 31990.06* 3125.065 3125.053 [ 2] −0.012 Cr ii —CH B 5 9 31963.71 3127.641 3127.671 [ 2d?] +0.030 |OH CH Ti i ? B 5 9 31961.62 3127.846 3127.846 [ 1] 0.000 CH P 4 7 31935.88 3130.367 3130.415 [ 1] +0.048 Be ii M 4 7 31933.06 3130.543 3130.567 [ 1] +0.024 |OH Fe ii M 3 5 31908.03 3133.099 3133.066 [ 1] −0.033 ‖Fe ii —Sc ii M 3 5 31904.23 3133.472 3133.491 [ 0] +0.019 Zr ii M 2 2.5 31880.74 3135.781 A 2 3 31874.92 3136.354 3136.345 [−1] −0.009 CH P 1 3 31844.93 3139.308 3139.306 [ 0] −0.002 CH P 16 16 } 90
{ 31802.95 31802.8 31802.75 31802.6 31802.35 31802.2 3143.452 } 3143.486
{ + 0.034 + 0.020 + 0.015 − 0.001 − 0.025 − 0.040 } V ii CH M 15 3143.466 15 3143.471 17 17 3143.487 [ 2N] B 14 3143.511 14 3143.526 13 } 77
{ 31801.75 31801.65 31801.45 3143.570 } 3143.575
{ + 0.005 − 0.005 − 0.025 CH 18 18 3143.580 [ 1N] B 13 3143.600 12 } 61
{ 31801.05 31800.5 31800.3 31800.25 3143.640 A 12 3143.694 A 19 19 3143.714 } 3143.764
{ + 0.050 + 0.045 − 0.019 − 0.039 } M 11 3143.719 11 } 51
{ 31799.6 31799.4 3143.783 [ 4] ‖Ti ii CH—OH B 10 3143.803 10 } 55
{ 31798.6 31798.5 3143.88 } 3143.896
{ + 0.02 + 0.01 − 0.03 CH Cr ii 9 3143.89 [ 0] B 20 20 } 57
{ 31798.1 31797.6 31797.5 3143.93 8 31,43.98 } 3143.996 [ 2]
{ + 0.02 + 0.01 CH Fe i B 9 3143.99 7 } 55
{ 31796.7 31796.4 31796.0 31795.9 3144.07 A 8 3144.10 }3144.116
{ + 0.02 − 0.02 − 0.03 CH 6 3144.14 [ 0] B 2 3144.15 A 7 5 } 74
{ 31795.3 31795.1 31795.0 3144.21 } 3144.236
{ + 0.03 + 0.01 0.00 CH 21 21 3144.23 [ 0] B 4, 3 3144.24 6 36 31794.1 3144.33 3144.326 [ 0] 0.00 CH OH| B 5 25 31793.0 3144.44 3144.453 [ 1] +0.01 CH Cr i B 4 22 31792.0 3144.53 3144.501 [ 1] −0.03 Fe i CH B 3, 22 22 26 31790.93 3144.640 3144.629 [ 0] −0.011 CH P 2 16 31789.78 3144.754 3144.737 [ 1] −0.017 Ti ii V ii —Fe ii | M 1 8 31788.13 3144.917 3144.925 [ 1 +0.008 CH Fe i B 23 23 6 31786.06 3145.122 3145.091 [ 3] −0.031 |Fe i —Cr ii (CH) M 24 } 4
{ 31779.59 31779.12
{ 3145.763 3145.809 3145.791 [ 1]
{ + 0.028 − 0.018 Cr ii ? CH—CH B 24 25 } 3
{ 31771.48 31770.96
{ 3146.566 3146.617 3146.598 [ 1]
{ + 0.032 − 0.019 CH—CH OH B 25 26 2 31761.53
{ 3147.551 3147.609 3147.599 [ 1]
{ + 0.048 − 0.010 Fe i —CH B 26 2 31760.95 1 4 31759.34 3147.768 3147.784 [ 1] +0.016 Fe i M 27 1 31749.88 3148.706 A 27 1 31749.32 3148.762 3148.797 [ 0N] +0.035 M 2 5 31738.48 3149.837 3149.852 [ 2] +0.015 OH M 2 6 31732.62 3150.419 3150.417 [−1] −0.002 CH P 3 6 31709.12 3152.754 3152.737 [ 1Nd?] −0.017 Co i —CH B 3 6 31705.16 3153.148 3153.191 [ 3] +0.043 |Fe i OH M 4 7 31680.54 3155.598 3155.622 [ 0] +0.024 CH P 4 7 31677.60 3155.891 3155.905 [ 0] +0.014 CH P 5 14 31652.28* 3158.416 3158.403 [ 1] −0.013 CH P 5 11 31650.11 3158.632 3158.633 [ 0] +0.001 CH P 6 10 31624.45 3161.195 3161.204 [ 3] +0.009 Ti ii M G 13 31622.73* 3161.367 3161.382 [ 1] +0.015 Fe i CH B 7 12 31596.93 3163.949 3163.930 [ 1] −0.019 Cr ii —CH B 7 13 31595.59 3164.083 3164.068 [ 0] −0.015 CH P 8 12 31569.75 3166.673 3166.674 [ 1] +0.001 CH Fe ii B 8 13 31568.73 3166.775 3166.767 [ 0] −0.008 CH P 9 14 31542.82 3169.376 3169.366 [ 1] −0.010 CH P 9 15 31542.22 3169.438 3169.427 [ 1] −0.011 CH P 10 } 18
{ 31516.27 31515.92 3172.047 3172.051 [ 3]
{ + 0.004 + 0.005 ‖Fe i Cr ii (CH) M 10 3172.082 3172.087 [ 4] 11 11 20 31489.89 3174.704 3174.697 [ 2] −0.007 CH P 12 12 18 31464.03 3177.313 3177.302 [ 2] −0.001 Co i —CH B 13 13 19 31438.33 3179.911 3179.901 [ 0] −0.010 CH P 14 14 17 31412.94 3182.481 3182.471 [ 2] −0.010 CH P 15 15 15 31387.76 3185.034 3185.022 [ 1N] −0.012 CH P 16 }11
{ 31363.00 31362.71
{ 3187.549 3187.578 3187.556 [ 0Nd?]
{ + 0.007 − 0.022 CH—CH B 16 17 } 10
{ 31338.25 31337.82 3190.066 3190.042 [ 1] −0.024 Fe i —CH B 17 3190.110 3190.104 [ 1] −0.006 CH P 18 } 8
{ 31313.65 31313.07 3192.573 3192.534 [−1] −0.039 —CH? B 18 3192.632 3192.617 [−1] −0.015 CH P 19 6 31289.07 3195.080 3195.085 [ 0] +0.005 CH OH B 19 7 31288.28 3195.161 3195.140 [−1] −0.021 Ru ii CH B 20 4 31264.33 3197.609 3197.596 [−1] −0.013 Y ii ?—CH B 20 8 31263.44* 3197.700 3197.710 [ 1N] +0.010 CH P 21 3 31239.60 3200.140 3200.137 [−1] −0.003 CH P 21 4 31238.63 3200.240 3200.295 [ 2Nd?] +0.055 Y ii — M 22 3 31214.62 3202.701 3202.695 [ 0] −0.006 CH OH B 22 4 31213.57 3202.809 3202.822 [ 0] −0.013 CH P 23 1.5 31189.12 3205.320 3205.333 [−1] +0.013 CH P 23 2 31188.04 3205.431 3205.408 [ 2] −0.023 Fe i —CH B 24 1 31163.39 3207.967 3207.989 [ 0] +0.022 CH— B 24 1.5 31162.11 3208.098 3208.094 [ 0] −0.004 CH P 25 1 31136.68 3210.719 3210.724 [−1] +0.005 CH OH B 25 1 31135.45 3210.845 3210.836 [ 2] −0.009 Fe i M 26 1 31108.98 3213.577 3213.564 [−2] −0.013 Ti ii Fe i M 26 1 31107.64 3213.716 3213.694 [−1] −0.022 M 27 1 31080.42 3216.530 3216.546 [ 0] +0.016 Cr ii M 27 1 31079.03 3216.674 3216.694 [ 1] +0.020 Y ii M 28 0.5 31050.36 3219.645 A 28 1 31049.00 3219.786 3219.805 [ 3] +0.019 Fe i M
Open in a separate window * Blend.The individual rotational bands are described in . Data on the laboratory analyses are given on the left hand side of each table, and the solar data are entered on the right. In
Open in a separate window Laboratory Sun
P1dc P1cd P2dc P2cd Q1c Q1d Q2c Q2d Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 3 141 23181.39* −0.028 Mn i —CH B 3, 2 2 140 23180.78* 4312.706 4312.709 8.8 + 0.003 CH P 4 ‡ 200? 23179.75* 4312.897 4312.875 35.5 w? −0.022 |Ti ii —CH B 4 ‡ 200? 23179.05* 4313.027 4313.035 19.5 wN + 0.008 |CH Fe i p B ‡ M 23177.73 4313.273 4313.237 1.5 −0.036 A ‡ } 160
{ 23177.15 23176.04 23175.66 4313.381 4313.418 2.0 + 0.037 A 3
4313.587 4313.658 } 4313.631 18.8
{ + 0.044 − 0.027 } CH—CH 3 B ‡ 6 23174.46* 4313.881 4313.890 2.6 s + 0.009 M 2 2 124 23172.72* 4314.206 4314.221 7.9 w + 0.015 CH P 3 7 23094.44 4328.829 4328.845 2.1 u + 0.016 CH P 3 6 23093.98 4328.915 4328.927 1.3 + 0.012 CH P ‡ 20
{ 23092.75 23092.26 4329.146 4329.144 1.2 −0.002 CH P ‡ 4329.238 A 3 20
{ 23088.52 23088.19 4329.939 A 3 4330.001 4330.024 8.1 s + 0.023 V i M 4 18 23067.73 4333.842 A 4 19 23066.89 4334.000 4334.018 2.3 + 0.018 CH P ‡ 10 23065.80 4334.204 4334.166 2.3 −0.038 Sm ii M 4 28 23063.39 4334.658 4334.672 3.9 + 0.014 CH P 4 28 23062.75 4334.778 4334.800 3.9 s + 0.022 CH—Ti i | B 5 40 23042.29* 4338.627 4338.627 3.2 0.000 CH P 5 40 23041.13 4338.845 4338.829 6.4 ud −0.016 Cr i Fe i p M 5 45 23038.95 4339.256 4339.259 8.1 u + 0.003 Fe i (CH) M 5 43 23037.92 4339.450 4339.456 27.4 s + 0.006 Cr i M 6 40 23018.16* 4343.175 4343.216 15.0 ud * + 0.041 |Cr i —Fe i p M 6 45 23016.49 4343.490 4343.494 10.4 + 0.004 CH P 6 50 23015.42* 4343.692 4343.705 18.6 u + 0.013 Fe i (CH) M 6 45 23013.97 4343.966 4343.968 11.5 u + 0.002 CH P 7 54 22995.12 4347.527 4347.545 9.0 + 0.018 CH P 7 7 115 22992.82* 4347.961 4347.973 13.1 + 0.012 CH P 7 64 22990.84 4348.336 4348.338 12.0 + 0.002 CH P 8 70 22972.96 4351.720 4351.710 0.5 −0.010 CH P 8 78 22971.08 4352.076 4352.072 16.8 −0.004 CH P 8 66 22970.14 4352.254 4352.261 12.2 + 0.007 CH P 8 77 22968.54 4352.558 4352.557 12.2 −0.001 CH P 9 70 22951.90 4355.713 4355.704 11.0 −0.009 CH P 9 78 22950.32 4356.013 4356.000 16.8 −0.013 CH P 9 77 22948.41 4356.375 4356.367 12.6 −0.008 CH P 9 77 22947.14 4356.617 4356.604 12.4 −0.013 CH P 10 110 22931.91* 4359.510 4359.493 13.8 −0.017 CH P 10 80 22930.62 4359.755 4359.744 15.6 w −0.011 Zr ii CH B 10 94 22927.76 4360.299 4360.289 13.3 −0.010 CH P 10 94 22926.72 4360.497 4360.480 13.5 s −0.017 Ti i CH B 11 100 22913.02 4363.105 4363.108 16.5 ud + 0.003 CH—Cr i B 11 103 22911.90 4363.318 4363.293 13.8 wd −0.025 CH P 11 110 22908.07 4364.048 4364.041 11.0 −0.007 CH P 11 110 22907.26 4364.202 4364.189 12.1 −0.013 CH P 12 100 22895.08* 4366.524 4366.500 14.4 −0.024 CH P 12 104 22894.13 4366.705 4366.675 16.5 −0.030 CH P 12 120 22889.32* 4367.622 4367.594 32.7 u −0.028 |Fe i —CH B 12 110 22888.68 4367.745 4367.723 3.2 −0.022 CH P 13 100 22878.29 4369.728 4369.714 6.2 u −0.014 Ti i —Fe i p (CH) M 13 100 22877.55 4369.870 4369.866 2.3 −0.004 CH P 13 } 150
{ 22871.46 22871.26 4371.033 } 4371.062 17.8 wd
{ + 0.029 − 0.010 } CH—CH B 13 4371.072 14 100 22862.50 4372.746 4372.743 9.1 −0.003 CH P 14 100 22861.86 4372.869 4372.844 15.8 −0.025 CH P 14 14 130 22854.73* 4374.233 4374.226 14.4 −0.007 CH P 15 90 22847.78 4375.563 4375.578 15.3 + 0.015 CH P 15 90 22847.20 4375.675 4375.658 15.8 −0.017 CH P 15 15 150 22838.96* 4377.253 4377.234 19.9 −0.019 CH P 16 } 100
{ 22833.79 22833.50 4378.244 } 4378.255 19.0
{ + 0.011 − 0.045 } CH—CH? B 16 4378.300 16 16 120 22824.21* 4380.282 4380.367 3.4 u + 0.085 Mg i (CH) M 17 17 125 22820.85* 4380.727 4380.724 21.0 −0.003 CH— B 17 } 90
{ 22810.49 22810.33 4382.716 4382.689 5.7 −0.027 CH P 17 4382.747 4382.764 22.4 + 0.017 CH—Fe i | B 18 18 90 22808.95* 4383.012 4382.998 16.4 −0.014 —CH B 19 19 } 130
{ 22798.05 * 22797.66 22797.15 4385.108 4385.124 14.1 + 0.016 CH P 18 4385.183 A 18 4385.281 4385.254 12.1 u −0.027 |Fe i —CH B 20 20 80 22787.78* 4387.084 4387.063 13.4 −0.021 CH P 19 60 22785.64 4387.496 4387.497 13.9 s + 0.001 Cr i (CH) M 19 55 22785.10 4387.600 4387.595 9.6 −0.005 CH P 21 21 66 22778.38* 4388.894 4388.870 10.7 −0.024 CH P 20 50 22774.41 4389.660 4389.638 10.2 −0.022 CH P 20 40 22773.73 4389.791 4389.776 6.8 −0.015 CH P 22 22 60 22769.83* 4390.543 4390.545 8.9 + 0.002 CH P 21 45 22763.95 4391.677 4391.668 11.8 u? −0.009 Ce ii —CH B 21 44 22763.20 4391.821 4391.768 15.2 s −0.053 Cr i (CH) M 23 23 44 22761.77* 4392.097 4392.071 12.3 s −0.026 V i CH B 22 24 24 60 22754.30* 4393.539 4393.524 16.2 ud? −0.015 —CH B 22 35? 22753.39 4393.715 4393.700 6.4 w −0.015 Fe i p—CH B 25 25 34 22747.36* 4394.879 4394.852 11.6 s −0.027 Ti i M 23 48 22745.11 4395.314 4395.289 3.4 −0.025 Fe i CH B 23 45 22744.16 4395.498 4395.504 15.0 ud + 0.006 CH—Fe i B 26 } 20
{ 22741.09 22740.72 4396.091 4396.079 5.0 −0.012 CH P 26 4396.163 4396.153 4.1 −0.010 —CH B 24 36 22736.52 4396.975 4396.961 10.2 −0.014 CH P 24 } 22
{ 22735.60 22734.82 4397.153 4397.143 5.0 u −0.010 CH P 27 4397.304 A 27 22734.38 4397.389 4397.381 3.4 u −0.008 M 25 28 24 22728.58* 4398.511 4398.491 7.7 −0.020 CH V ii B 28 16 22727.97 4398.629 4398.621 5.4 w −0.008 Ni i CH B 25 14 22727.44 4398.732 4398.712 4.3 w −0.020 CH P 26 14 22720.92 4399.994 4399.989 4.8 −0.005 CH P 26 20 22719.74 4400.223 4400.185 9.3 −0.038 Ni i CH? B 27 22713.45 4401.441 4401.451 15.0 u + 0.010 Fe i M 27 22712.19 4401.685 4401.668 2.5 −0.017 CH? P 28 22706.19 4402.848 4402.841 4.1 u −0.007 CH P 28 22704.86* 4403.106 4403.077 4.5 uN −0.029 CH P 29 22698.72 4404.297 4404.277 12.0 u −0.020 |Ti i —CH B 29 22697.44 4404.546 4404.548 5.2 + 0.002 CH? P 30 22691.10 4405.776 4405.732 6.4 sd −0.044 Ti i —CH? B 30 22689.73 4406.043 4406.036 3.0 u −0.007 CH? P 31 22683.17 4407.317 A 31 22681.62 4407.618 4407.652 14.1 sd * + 0.034 V i M 32 22674.32 4409.037 A 32 22672.69 4409.354 4409.359 2.9 uN + 0.005 M 33 22664.71 4410.907 A 33 22663.07* 4411.226 4411.227 5.4 uN + 0.001 CH—CH? M 34 22654.44 4412.906 4412.877 1.4 u −0.029 M 34 22653.18 4413.152 4413.121 2.5 −0.031 M
Open in a separate window * Blend.
‡ Satellite lines as follows:
Designation J Laboratory
Wave number Wavelength
RQ 2d 1c 3 23293.17* 4291.897 RQ 2c 1d ; RQ 2d 1c 2; 2 23261.34* 4297.769 RQ 2c 1d ; RQ 2d 1c 1; 1 23229.71* 4303.621 QR 1 2c 3 23179.75* 4312.897 QR 1 2d 2 23179.05* 4313.027 QP 2 1d 3 23177.73 4313.273 QP 2 1c 3 23177.15 4313.381 QP 2 1d ; QP 2 1c 2; 2 23174.46* 4313.881 RQ 1d 2c 3 23092.75 4329.146 RQ 1c 2d 3 23092.26 4329.238 RQ 1c 2d 4 23065.80 4334.204
Open in a separate window Table 6 CH in the Solar Spectrum A
2 Δ—X
2 Π (1,2)
Laboratory
P1cd P1dc P2cd P2dc Q1c Q1d Q2c Q2d R1cd R1dc R2cd R2dc Intensity Wave number cm−1 Wavelength A 13 13 1 21083.78 4741.660 13 13 2 21077.49 4743.076 12 12 4 21040.28* 4751.463 12 12 1 21034.82 4752.697 11 2 20998.22 4760.982 11 3 20997.21* 4761.219 11 1 20993.57 4762.035 11 1 20992.87 4762.194 10 2 20956.62 4770.432 10 2 20955.52 4770.682 10 2 20952.79* 4771.305 10 2 20951.91 4771.505 9 2 20916.02 4779.692 9 2 20914.78* 4779.975 9 2 20912.79* 4780.429 9 2 20911.85 4780.644 8 2 20876.26 4788.794 8 2 20874.73 4789.145 8 2 20873.82 4789.354 8 2 20872.56 4789.644 7 2 20837.84 4797.625 7 7 3 29835.83 4798.089 7 2 20834.15 4798.475 6 2 20800.39 4806.263 6 2 20798.97 4806.591 6 2 20798.14 4806.784 17 17 6 3 20796.78 4807.097 17 17 1 20787.35 4809.279 16 16 2 20774.31 4812.296 16 16 5 20765.81* 4814.267 5 6 20764.24* 4814.630 5 7 20763.02* 4814.913 5 6 20761.64* 4815.233 5 2 20760.55 4815.486 15 2 20752.52 4817.350 15 1 20751.93 4817.486 15 15 2 20744.41 4819.232 14 2 20731.59 4822.214 14 2 20730.92 4822.370 4 2 20729.75 4822.640 4 2 20728.91 4822.837 4 3 20726.33 4823.438 4 3 20725.64 4823.597 14 14 3 20724.38 4823.891 13 2 20711.85 4826.844 13 2 20710.99 4827.009 13 13 2 20705.27 4828.342 3 2 20696.75 4830.332 3 2 20695.97 4830.513 12 ‡ 2 20692.96 4831.216 12 3 4 20692.14 4831.408 3 3 20691.71 4831.508 12 2 20687.60 4832.467 12 2 20686.99 4832.610 11 5 20675.54* 4835.285 11 2 20674.45 4835.541 11 2 20670.88 4836.376 11 2 20670.20 4836.535 2 2 2 20665.81 4837.562 ‡ 4838.899 10 2 2 5 20659.09 4839.135 10 3 20658.03 4839.384 10 3 20655.35 4840.012 10 3 20654.55 4840.200 9 3 20644.23 4842.620 9 3 20642.80 4842.954 9 3 20641.02 4843.371 9 1 1 5 20639.87 4843.641 8 6 20630.61* 4845.817 8 3 20629.01 4846.191 ‡ 2 20628.34 4846.350 8 3 20627.96 4846.440 8 1 1 5 20626.65 4846.746 7 3 20618.58 4848.644 7 7 4 20616.61 4849.108 7 3 20614.78 4849.537 6 3 20607.97 4851.141 6 6 20606.45* 4851.499 6 6 20605.36* 4851.755 6 3 20604.23 4852.020 5 3 20598.95 4853.265 5 3 20597.80 4853.537 5 3 20596.06 4853.945 5 3 20595.01 4854.194 4 3 20591.61 4854.995 4 3 20590.65 4855.221 4 3 20587.97 4855.854 4 3 20587.27 4856.019 3 2 20585.87 4856.348 3 2 20584.67 4856.631 2 2 6 20582.64* 4857.110 3 3 20581.17 4857.459 3 3 20580.69 4857.572 2 2 2 20575.52 4858.791 3 2 20502.61 4876.070 3 ‡ 2 20501.28 4876.387 ‡ 2 20500.65 4876.535 3 1 20497.27 4877.340 3 7 20496.23* 4877.589 4 5 20480.80* 4881.262 4 6 20479.27* 4881.627 ‡ 6 20478.34* 4881.849 4 7 20476.93* 4882.185 4 1 20475.50 4882.526 5 2 20460.87 4886.017 5 1 20459.59 4886.322 ‡ 1 20458.64 4886.549 5 7 20457.36* 4886.856 5 6 20456.67* 4887.021 6 4 20442.89* 4890.315 6 2 20441.13 4890.735 6 2 20439.97 4891.014 6 2 20438.76 4891.302 7 2 20426.06 4894.343 7 7 3 20424.13 4894.807 7 2 20422.38 4895.227 8 2 20411.40 4897.859 8 2 20409.71 4898.265 8 2 20408.61 4898.528 8 2 20407.41 4898.816 9 2 20398.60 4900.933 9 2 20397.08 4901.296 9 2 20395.39 4901.704 9 2 20394.16 4901.999 10 2 20387.46 4903.610 10 2 20386.24 4903.905 10 2 20383.50 4904.563 10 2 20382.60 4904.779 11 2 20377.89 4905.913 11 2 20376.83 4906.169 11 2 20373.31 4907.017 11 2 20372.53 4907.205 12 2 20370.00 4907.814 12 2 20368.99 4908.057 12 2 20364.85 4909.055 12 13 2 20364.14 4909.227 13 2 20363.15 4909.463 14 2 20359.49 4910.347 14 2 20358.74 4910.529 13 2 20357.79 4910.756 13 2 20357.56 4910.812 15 2 20356.53 4911.062 15 2 20356.01 4911.186 17 17 2 20355.21 4911.379 16 2 20354.79 4911.481 16 2 20354.36 4911.583 14 14 3 20352.25 4912.094 15 15 2 20348.75 4912.939 16, 17 16 17 1 20346.28 4913.535
Open in a separate window * Blend.
‡ Satellite lines as follows :
Designation J Laboratory
Wave number Wavelength
RQ 2d 1c 3 20692.96 4831.216 RQ 2c 1d ; RQ 2d 1c 2; 2 20660.10 4838.899 RQ 2c 1d ; RQ 2d 1c 1; 1 20628.34 4846.350 PQ 1d 2c 3 20501.28 4876.387 PQ 1c 2d 3 20500.65 4876.535 PQ 1c 2d 4 20478.34 4881.849 PQ 1c 2d 5 20458.64 4886.549
Open in a separate window Table 11 CH in the Solar Spectrum C
2 Σ
+ —X
2 Π (1, 1)
Laboratory Sun
P Q R Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Rowl. est. ⊙—lab. A Solar identification Notes 19 1 32050.51 3119.171 3119.198 [ 1Nd?] +0.027 M 18 (CH) 32045.67* 3119.642 3119.678 [ 1] +0.036 OH CH Cr i M 17 1 32038.34 3120.355 3120.372 [ 3 ] +0.017 Cr ii M 16 1.5 32029.60 3121.207 3121.160 [ 4 ] −0.047 V ii M 15 (CH) 32019.19* 3122.222 3122.219 [ 0 ] −0.003 OH CH M 14 2 32006.57 3123.453 3123.443 [−1 ] −0.010 OH M 13 (CH) 31990.65* 3125.007 3124.998 [ 4 ] −0.009 Cr ii M 12 4.5 31974.16 3126.619 3126.617 [ 1 ] −0.002 CH OH—OH B 11 3 31956.69 3128.328 3128.289 [ 1 ] −0.039 Sc ii OH | M 10 (OH) 31936.86 3130.271 3130.267 [ 3 ] −0.004 |V ii —OH M 8 (OH) 31895.65 3134.315 3134.337 [ 1 ] +0.022 |OH Cr ii M 7 1.5 31873.48 3136.495 3136.506 [ 2 ] +0.011 V ii M 6 1.3 31850.58 3138.751 3138.786 [ 0 ] +0.035 A 5 1.5 31826.96 3141.080 3141.106 [−1 ] +0.026 CH? P 2 2 31670.8 3156.57 3156.565 [ 0 ] −0.01 —CH B 3 31670.2 3156.63 A 4 2 31669.0 3156.75 3156.727 [ −1 ] −0.02 CH P 5 2 31667.2 3156.93 3156.916 [ 0 ] −0.01 —CH B 6 6 31665.2 3157.13 3157.143 [ 1 ] +0.01 |OH—Fe i p M 7 3 31663.0 3157.35 A 8 4 31660.1 3157.64 3157.634 [−1 ] −0.01 CH P 9 4 31658.8 3157.77 3157.751 [ 0 ] −0.02 CH OH? B 10 (CH) 31652.9* 3158.36 3158.351 [ 0 ] −0.01 Fe ii p— M 11 6 31648.4 3158.80 3158.783 [ 1 ] −0.02 Co i CH B 12 6 31643.3 3159.31 3159.349 [ 0 ] +0.04 Fe ii p?—V ii ? M 13 6 31637.2 3159.92 3159.935 [ 0N ] +0.02 CH— B 14 5 31630.3 3160.61 3160.612 −1 0.00 Cr i CH B 15 (CH) 31622.2* 3161.42 3161.423 [ 0 ] 0.00 M 16 6 31612.9 3162.35 3162.353 [ 1 ] 0.00 Fe i CH B 17 4 31602.1 3163.43 3163.423 [ 2 ] −0.01 Nb ii —CH B 18 4 31589.5 3164.69 3164.685 [ 1 ] −0.01 Mn ii —CH B 19 3 31575.1 3166.14 3166.130 [ 0 ] −0.01 CH P 20 3 31558.4 3167.81 3167.790 [ 1 ] −0.02 Fe i —CH B 21 (CH) 31540.6 3169.60 3169.616 [ 0 ] +0.02 OH M 6 2 31503.07 3173.376 3173.408 [ 1 ] +0.032 Fe i M 7 2 31473.45 3176.362 3176.351 [ 1 ] −0.011 Fe i M 8 2 31444.83 3179.253 A 9 3 31417.00 3182.070 3182.061 [ 1 ] −0.009 Fe i —CH B 10 (CH) 31385.15 3185.299 3185.327 [ 2 ] +0.028 Fe ii M 11 4 31355.47 3188.314 3188.335 [ 0 ] +0.021 CH P 12 4 31325.15 3191.400 3191.414 [ 0 ] +0.014 Fe i p CH B 13 4 31294.43 3194.533 3194.524 [−1 ] −0.009 CH P 14 (CH) 31263.55* 3197.689 3197.710 [ 1N ] +0.021 CH M 15 3 31231.66 3200.954 3200.962 [ 1 ] +0.008 OH M 16 2.5 31199.10 3204.295 3204.284 [ 2Nd?] −0.011 M 17 2 31165.79 3207.720 3207.711 [ 0 ] −0.009 Fe i M 18 1.5 31131.80 3211.222 3211.209 [−1 ] −0.013 CH? P 19 1 31096.37 3214.881 3214.864 [−2 ] −0.017 CH? P 20 31059.68 3218.678 3218.684 [−1 ] +0.006 Cr i M 21 31021.21 3222.670 A
Open in a separate window * Blend.Under the general heading, “Laboratory,” the respective rotational quantum numbers of the
P ,
Q , and
R branches are entered as indicated by the respective headings. Lines of weak satellite branches are indicated by the symbol ‡, and a summary of the satellite lines is included in footnotes to the tables.These entries are followed by an intensity column. Intensities have been determined from measurements of the emission from the reaction zone of an acetylene-oxygen flame. A question mark (?) after the intensity number indicates a questionable intensity measurement caused by some overlapping from a strong neighboring line.(CH) indicates a weak line masked by a stronger CH line, whereas “M” indicates masking by some other emission in the laboratory source. In ]. In , and the laboratory analysis is from Gerö [
6 ]; in it is from N. H. Kiess and Broida [
7 ]; in , from Gerö [
6 ]; and in from Heimer [
8 ]. Fagerhölm’s measurements [
10 ] of the A
2 Δ—X
2 Π and B
2 Σ
− —X
2 Π bands do not fit the solar data so well as those of Gerö and have been used only as a check for errors. An asterisk in the wave number column is used to indicate a blend of two or more CH lines.
Table 3 CH in the Solar Spectrum A
2 Δ—X
2 Π (1, 1)
Laboratory Sun
Q1c Q1d Q2c Q2d R1dc R1cd R2dc R2cd Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙–lab. A Solar identification Notes 29, 28 3? 23886.86* 4185.222 A 29, 28 4? 23883.64* 4185.787 4185.779 4.5 −0.008 M 27 6? 23880.52 4186.334 4186.336 9.3 uN + 0.002 CN—Cr i M 30 27 M 23879.45* 4186.521 A 26 4 23872.78 4187.691 4187.720 7.2 + 0.029 M 26 4 23871.58 4187.901 4187.812 20.8 u −0.089 Fe i M 25 5 23861.81 4189.616 4189.565 16.7 u −0.051 Fe i M 25 5 23860.75 4189.802 4189.816 3.8 s + 0.014 V i M 24 23 23 13 23848.12* 4192.021 4192.016 12.4 u −0.005 CN?—CH B 24 6? 23847.29 4192.167 4192.204 3.6 + 0.037 CH P 23 (CH) 23831.96* 4194.864 4194.848 15.5 u −0.016 CH M 23 8? 23831.30 4194.980 4194.996 11.2 sd? + 0.016 CH Cr I—CN B 22 22 11 23828.76* 4195.427 4195.415 3.6 −0.012 Cr ii —CH B 22 10 23813.78 4198.066 4198.068 23.1 uN + 0.002 Fe i — M 22 10 23813.08 4198.189 4198.242 32.9 u + 0.053 Fe i M 21 21 15 23807.69* 4199.140 4199.105 43.6 u −0.035 Fe i M 21 14 23793.81 4201.589 4201.577 7.4 w −0.012 —CH B 21 12 23793.07 4201.720 4201.715 17.1 w −0.005 |Ni i Fe i M 20 20 18 23785.01 4203.144 4203.129 9.5 sd −0.015 —CH B 20 16 23772.11 4205.426 4205.390 9.8 wN −0.036 Mn ii —CH B 20 14 23771.49 4205.535 4205.544 21.2 s + 0.009 Fe i (CH) M 19 19 16 23760.89* 4207.411 4207.408 14.0 wN −0.003 CH P 19 19 23748.98 4209.521 4209.500 6.4 u −0.021 CH P 19 18 23748.45 4209.615 4209.602 7.1 u −0.013 CH P 18 18 33 23735.48* 4211.916 4211.895 15.4 u −0.021 |Zr ii —CH B 18 } 26
{ 23724.56 23724.27 4213.854 4213.839 4.7 u −0.015 CH P 18 4213.906 4213.909 10.7 + 0.003 CH P 17 17 39 23709.04 4216.613 4316.599 11.6 uN −0.014 CH P 17 17 } 36
{ 23699.07 23698.85 4218.387 4218.426 } 4218.392 12.6 uN
{ + 0.005 − 0.034 } CH—CH B 16 16 43 23681.72* 4221.477 4221.469 12.8 −0.008 CH P 16 16 45 23672.66* 4223.093 4223.091 15.6 −0.002 CH P 15 } 45
{ 23653.77 23653.58 4226.465 4226.431 52.5 u −0.034 Fe i M 15 4226.499 A 15 15 54 23645.54* 4227.936 4227.944 15.6 s + 0.008 CH P 14 42 23625.14 4231.587 4231.609 9.7 uN + 0.022 CH—Zr ii B 14 40 23624.66 4231.673 4231.688 9.7 uN + 0.015 CH–Fe i B 14 14 63 23617.71* 4232.919 4232.927 15.1 u + 0.008 |CH—V i ? B 13 40 23595.95 4236.822 4236.806 12.0 u −0.016 CH V ii B 13 40 23595.30 4236.939 4236.958 7.8 u + 0.019 CH P 13 13 62 23589.28* 4238.020 4238.029 26.2 s + 0.009 Fe i M 12 46 23566.19 4242.172 4242.162 12.0 −0.010 Tm ii —CH| B 12 46? 23565.38* 4242.318 4242.283 5.2 wN * −0.035 −CH B 12 45? 23560.54 4243.189 4243.203 14.8 + 0.014 CH— B 12 45? 23560.12 4243.265 A 11 41 23536.30 4247.561 4247.560 18.1 wN −0.001 CH— B 11 45 23535.34 4247.734 4247.726 11.5 −0.008 CH P 11 48 23531.47 4248.432 4248.414 15.3 s −0.018 |Fe I p—CH B 11 48 23530.89 4248.537 4248.534 9.4 w −0.003 CH P 10 41 23506.18 4253.003 4253.004 8.9 + 0.001 CH P 10 45 23505.04 4253.209 4253.210 9.4 s + 0.001 |CH P 10 46 23502.12 4253.738 4253.735 9.2 −0.003 CH P 10 50 23501.31 4253.885 4253.912 16.4 sd + 0.027 CH—Fe i B 9 42 23475.98 4258.475 4258.488 9.4 u + 0.013 CH—Ti i B 9 56 23474.60* 4258.725 4258.731 12.9 w + 0.006 CH— B 9 44 23472.61 4259.086 4259.098 9.4 uN + 0.012 CH P 9 48 23471.55 4259.278 4259.305 14.3 sd? + 0.027 V i Fe i (CH) M 8 40 23445.69 4263.976 4263.980 9.6 w + 0.004 CH P 8 44 23444.06 4264.273 4264.281 2.3 U + 0.008 CH P 8 42 23442.96 4264.473 4264.468 13.4 s −0.005 CH P 8 46 23441.63 4264.715 4264.741 20.2 U + 0.026 Fe i (CH) M 7 44 23415.51 4269.472 4269.478 9.1 w + 0.006 CH—La ii B 7 7 82 23413.48* 4269.842 4269.849 17.8 U + 0.007 CH—Fe i p B 7 46 23411.70 4270.167 4270.170 15.0 sd + 0.003 |Ti i CH B 6 42 23385.46 4274.958 4274.959 20.1 uN + 0.001 CH P 6 80 23383.88* 4275.247 4275.258 15.0 + 0.011 CH P 6 104 23383.17* 4275.377 4275.386 24.3 + 0.009 CH P 6 50 23381.73 4275.640 4275.661 10.5 ud* + 0.021 CH La ii B 5 50 23355.75* 4280.396 4280.403 14.2 w + 0.007 Cr i CH B 5 60 23354.59 4280.609 4280.632 7.2 + 0.023 Fe i p CH B 5 60 23352.70* 4280.956 4280.964 11.4 + 0.008 CH P 5 50 23351.87 4281.108 4281.100 18.0 s −0.008 |Mn i —CH B 4 30 23326.34 4285.794 4285.815 13.8 s + 0.021 Co i —Fe i (CH) M 4 40 23325.56 4285.937 4285.938 1.8 + 0.001 CH P 4 (CH) 23322.56* 4286.488 4286.477 26.6 uN −0.011 Fe i —CH M 4 M 23322.08 4286.576 4286.587 11.2 uN + 0.011 CH P 3 (CH) 23297.42* 4291.113 4291.121 26.1 U + 0.008 CH M 3 (CH) 23296.85* 4291.219 4291.220 14.2 u + 0.001 CH Ti i M ‡ (CH) 23293.17* 4291.897 4291.839 2.6 sd −0.058 V i — M 3 M 23292.69 4291.985 4291.979 6.5 w −0.006 Cr i —CH B 3 (CH) 23292.36* 4292.046 4292.055 12.3 + 0.009 CH M 2 2 56 23269.80* 4296.207 4296.217 8.1 + 0.010 CH P ‡ (CH) 23263.96* 4297.286 4297.291 20.9 + 0.005 CH M 2 2 120 23262.70* 4297.518 4297.530 17.4 wd? + 0.012 CH— B 19 19 (CH) 23253.34* 4299.248 4299.249 49.3 sN + 0.001 |Fe i Ti I (CH) M 1 1 } 80
{ 23252.00 * 23249.13 * 4299.496 4299.483 18.1 u −0.013 CH Fe i p B 18 18 4300.026 4300.053 38.6 w + 0.027 Ti ii M 17 M 23245.09 4300.774 4300.744 11.8 uN −0.030 M 17 M 23244.61 4300.863 4300.827 23.0 u −0.036 Fe i M 19 19 (CH) 23243.12* 4301.138 4301.103 41.6 s −0.035 Ti i (V ii ) M 16 } 88
{ 23239.89 23239.69 4301.736 } 4301.749 15.1
{ + 0.013 − 0.024 } CH—CH B 16 4301.773 18 18 50? 23239.22* 4301.860 4301.927 34.4 u + 0.067 Ti ii M 17 17 M 23235.12* 4302.619 4302.539 38.4 S −0.080 Ca i M 15 M 23234.75 4302.688 4302.65 19.5 −0.04 M 15 ‡ (CH) 23234.38* 4302.756 4302.754 24.2 −0.002 CH M 1 1 68 23232.47* 4303.110 4303.089 9.3 w?N −0.021 CH P 16 16 88 23230.85* 4303.410 4303.426 16.7 + 0.016 CH P 14 M 23229.30* 4303.697 4303.723 13.2 w + 0.026 CH— B 14 (CH) 23228.59* 4303.829 4303.835 28.6 u + 0.006 CH M 15 15 M 23226.26* 4304.261 4304.256 14.6 w −0.005 CH P 13 M 23223.84 4304.709 4304.721 9.0 + 0.012 CH P 13 M 23223.09 4304.848 4304.852 13.0 uN + 0.004 CH—Fe i B 14 14 88 23221.71* 4305.104 4305.110 19.0 + 0.006 CH Fe i B 12 48 23218.55 4305.690 4305.713 15.6 u + 0.023 Sc ii M 12 M 23217.78 4305.833 4305.847 5.8 + 0.014 CH P 13 13 (CH) 23217.08* 4305.962 4305.918 36.2 S −0.044 Ti i (CH) M 11 M 23213.41 4306.643 4306.599 12.5 uN −0.044 Fe i M 12 M 23212.73 4306.769 A 12 11 (CH) 23212.33* 4306.844 4306.855 29.2 + 0.011 CH M 10 M 23208.67 4307.523 } 4307.564 28.8
{ + 0.041 − 0.014 } CH?—CH B 11 (CH) 23208.37* 4307.578 M 11 10 M 23207.52* 4307.736 4307.748 40.2 s +0.012 Ca i M 10 M 23204.74 4308.252 4308.289 12.8 +0.037 A 9 M 23204.18* 4308.356 4308.381 14.2 + 0.025 CH P
Open in a separate window Laboratory Sun
P1dc P1cd P2dc P2cd Q1c Q1d Q2c Q2d Intensity Wave number cm−1 Wavelength A Wave length A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 10 M 23203.77* 4308.432 4308.441 11.1 + 0.009 CH P 9 M 23202.76 4308.620 4308.595 25.1 −0.025 CH—CH B 9 M 23200.84 4308.976 4309.040 31.6 u + 0.064 Fe i M 8 (CH) 23200.17* 4309.100 4309.130 13.2 + 0.030 CH M 9 M 23199.74 4309.181 4309.205 13.2 + 0.024 CH P 8 M 23198.31 4309.446 4309.458 21.6 w + 0.012 CH Fe i p B 8 M 23197.31* 4309.632 4309.634 21.8 u + 0.002 ‖Y ii CH B 7 M 23196.30 4309.820 4309.834 9.5 sN + 0.014 CH V i B 8 M 23195.88 4309.898 4309.900 16.5 uN + 0.002 CH P 7 7 M 23194.19* 4310.212 4310.225 18.3 + 0.013 CH P 6 (CH) 23192.87* 4310.457 4310.467 29.2 + 0.010 CH M 7 M 23192.41 4310.543 4310.559 9.3 + 0.016 CH P 6 (CH) 23191.64* 4310.686 4310.704 22.7 s + 0.018 CH— M 6 5 M 23190.56* 4310.886 4310.897 10.0 + 0.011 CH P 6 5 (CH) 23189.12* 4311.154 4311.167 17.9 + 0.013 CH M 4 M 23188.26 4311.314 4311.322 5.6 + 0.008 CH P 5 4 (CH) 23187.27* 4311.498 4311.509 39.6 + 0.011 CH M 5 3, 2 3, 2 (CH) 23186.06* 4311.723 4311.718 19.0 −0.005 CH M ‡ M 23185.33* 4311.859 4311.888 4.4 u + 0.029 M 4 ‡ (CH) 23184.15* 4312.078 4312.086 23.0 + 0.008 CH M 4 (CH) 23183.74* 4312.155 4312.150 14.8 −0.005 CH M 3 ‡ M 23181.72* 4312.531 4312.504 4.6 u −0.027 Cr i ?—CH B 3 (CH) 23181.39* 4312.592 4312.564 20.9 −0.028 Mn i —CH M ‡ (CH) 23179.75* 4312.897 4312.875 35.5 w? −0.022 |Ti ii —CH M 2 2 (CH) 23179.05* 4313.027 4313.035 19.5 wN + 0.008 |CH Fe i p M 3 } 24
{ 23104.00 23103.46 * 4327.038 4327.110 18.2 w + 0.072 Fe i M 3 4327.139 4327.157 2.0 u? + 0.018 CH P ‡ 8 23102.23 4327.370 4327.317 1.4 −0.053 A ‡ 8 23101.32 4327.540 A 3 6 23098.25 4328.115 A 3 6 23097.89 4328.183 4328.203 2.0 + 0.020 CH? P 4 20 23077.53 4332.001 4332.006 1.2 o + 0.005 CH— B 4 14 23076.75 4332.148 } 4332.169 1.0
{ + 0.021 − 0.037 CH P ‡ 23076.44 4332.206 A ‡ 23075.60 4332.364 A 4 8 23073.37 4332.783 4332.831 4.8 s + 0.048 V i A 4 12 23072.71 4332.906 4332.918 8.3 u + 0.012 CH— B 5 20 23052.10 4336.780 4336.791 2.3 u + 0.011 CH P 5 14 23050.92 4337.002 4337.055 30.4 U + 0.053 Fe i M ‡ M 23050.18 4337.142 A 5 20 23048.79 4337.403 4337.411 4.8 u + 0.008 CH P 5 20 23047.87 4337.576 4337.566 23.3 s −0.010 Cr i M 6 20 23027.55 4341.404 4341.371 19.6 w? −0.033 Ti ii M ‡ 20? 23026.97 4341.513 4341.551 4.8 uN + 0.038 Fe i p A 6 20 23025.95 4341.705 4341.710 5.8 w + 0.005 CH P G 20 23024.93 4341.898 4341.924 4.8 u? + 0.026 CH P 6 20 23023.50 4342.168 4342.180 6.4 U + 0.012 Gd ii CH B 7 18 23003.77 4345.892 4345.895 5.8 u + 0.003 CH P 7 7 43 23001.62* 4346.298 4346.295 12.0 U −0.003 CH P 7 22 22999.68 4346.665 4346.673 3.7 u + 0.008 CH P 8 21 22980.73 4350.249 4350.249 6.4 u 0.000 CH P 8 22 22978.93 4350.589 4359.585 8.3 u −0.004 Fe i —CH B 8 21 22978.01 4350.764 4350.760 3.9 −0.004 CH P 8 26 22976.47 4351.055 4351.056 20.0 s + 0.001 Cr i M 9 20 22958.39 4354.482 4354.514 8.3 uNN* + 0.032 Mg i M 9 18 22956.88 4354.768 4354.762 5.7 −0.006 CH Fe i ? B 9 28 22955.02 4355.121 4355.093 23.0 s −0.028 Ca i (CH) M 9 24 22953.82 4355.349 4355.351 8.0 u + 0.002 CH P 10 20 22936.77 4358.586 4358.512 21.8 u −0.074 Fe i M 10 36 22935.49 4358.830 4358.820 15.6 uN −0.010 —CH P 10 30? 22932.73 4359.354 4359.341 6.6 −0.013 CH B 10 110 22931.91* 4359.510 4459.493 13.8 −0.017 CH P 11 28 22915.87* 4362.562 4362.533 12.1 w? −0.029 —CH B 11 32 22914.81* 4362.764 4362.746 10.3 u −0.018 CH P 11 40? 22911.09 4363.473 4363.467 5.5 u −0.006 CH P 11 30? 22910.33 4363.617 4363.602 6.2 w −0.015 Mo ii —CH B 12 M 22895.53 4366.438 4366.413 5.5 uN −0.025 —CH B 12 (CH) 22895.08* 4366.524 4366.500 14.4 −0.024 CH M 12 M 22889.92* 4367.508 4367.475 5.7 u −0.033 CH P 12 (CH) 22889.32* 4367.622 4367.594 32.7 u −0.028 |Fe i —CH M 13 28 22876.01 4370.164 4370.154 6.2 −0.010 CH P 13 32 22875.25 4370.309 4370.292 5.9 −0.017 CH P 13 } 50?
{ 22869.46 22869.24 4371.415 } 4371.426 11.9 wd?
{ + 0.011 − 0.031 } CH—CH 13 4371.457 B 14 38 22857.00 4373.799 4373.791 7.8 u −0.008 CH P 14 34? 22856.50 4373.894 4373.888 7.8 0.006 CH Fe i p B 14 14 48 22849.59* 4375.217 4375.202 12.6 −0.015 CH P 15 (CH) 22838.96* 4377.253 4377.234 19.9 −0.019 CH M 15 M 22838.10 4377.418 4377.374 8.4 u −0.044 Fe i —CH B 15 15 48 22830.26* 4378.921 4378.913 10.0 −0.008 CH P 16 (CH) 22820.85* 4380.727 4380.724 21.0 −0.003 CH— M 16 M 22820.27* 4380.838 4380.852 9.6 wN + 0.014 CH— B 16 16 40 22811.40* 4382.542 4382.521 8.2 −0.021 CH P 17 } 32
{ 22803.22 22803.00 4384.114 } 4384.120 8.4
{ + 0.006 − 0.036 CH—CH B 17 4384.156 17 17 31 22792.92* 4386.095 4386.063 9.8 −0.032 —CH B 18 18 M 22786.09* 4387.410 4387.398 10.5 u −0.012 —CH B 18 18 30? 22775.14* 4389.519 4389.504 4.6 −0.015 CH P 19 19 M 22769.35* 4390.635 4390.630 7.5 u −0.005 CH P 19 18? 22757.45 4392.931 4392.924 4.8 u −0.007 CH P 19 18? 22756.89 4393.039 4393.025 6.1 s? −0.014 CH F i p B 20 20 15? 22752.83* 4393.823 4393.808 6.4 u −0.015 CH V i B 20 28? 22739.85* 4396.331 4396.309 8.2 −0.022 CH P 20 20? 22739.39 4396.420 4396.430 4.1 u + 0.010 CH P 21 21 (CH) 22736.52* 4396.975 4396.961 10.2 −0.014 CH M 21 22722.42 4399.704 } 4399.778 26.4 w?
{ + 0.074 − 0.061 } Ti ii (Cr i ) M 21 22721.72 4399.839 22 22 22719.74* 4400.223 4400.185 9.3 −0.038 Ni i CH? M 22 (CH) 22704.86* 4403.106 4403.077 4.5 uN −0.029 CH M 22 (CH) 22704.16 4403.242 4403.187 14.5 u −0.055 A 23 23 22703.21* 4403.426 4403.374 10.7 s −0.052 ‖Cr i Zr ii A 23 22687.27 4406.521 4406.504 4.5 u −0.017 CH P 24 23 24 22686.36* 4406.696 4406.652 18.2 S −0.044 V i M 24 25 25 22669.17* 4410.039 4410.014 5.7 −0.025 —CH? B 24 22668.37 4410.195 4410.167 5.7 −0.028 —CH? B 25 22650.69 4413.637 4413.599 8.8 w −0.038 |Fe i CH? B 25 22649.72 4413.826 4413.853 6.6 u + 0.027 Cr i M 26 22631.45 4417.390 4417.412 3.4 s + 0.022 Co i M 26 22630.37 4417.600 4417.574 2.5 u −0.026 CH P 27 22611.22 4421.342 4421.334 4.8 u −0.008 Co i —CH B 27 22610.08 4421.565 4421.573 7.9 S + 0.008 V i M 28 22589.60 4425.573 A 28 22588.33 4425.822 4425.769 5.0 uN −0.053 Fe i p—Fe i p A 29 22566.49 4430.105 A 29 22565.28 4430.343 4430.368 6.1 s + 0.025 Ti i M 30 22541.17 4435.081 A 30 22539.67 4435.376 4435.328 5.9 u −0.048 Ni i ? A 31 22513.21 4440.589 4440.630 4.3 + 0.041 Fe i A 31 22512.03 4440.823 4440.827 10.4 u + 0.004 M 32 22482.25 4446.705 A
Open in a separate window * Blend.
‡ Satellite lines as follows:
Designation J Laboratory
Wave number Wavelength
RQ 2c 1cd ; RQ 2d 1c 3; 3 23293.17* 4291.897 BQ2d 1c 2 23263.96* 4297.286 BQ 2d 1c 1 23234.38* 4302.756 QP2 1d ; QR1 2d ; QR1 2c 4; 2; 2, 3 23185.33* 4311.859 QP2 1c 4 23184.15* 4312.078 QP2 1d 3 23181.72* 4312.531 QP2 1d; QP2 1c 2; 2 23179.75* 4312.897 PQ 1c 2d 3 23102.23 4327.370 PQ 1d 2c 3 23101.32 4327.540 PQ 1c 2d 4 23076.44 4332.206 PQ 1d 2c 4 23075.60 4332.364 PQ 1d 2c 5 23050.18 4337.142 PQ 1c 2d 6 23026.97 4341.513
Open in a separate window Table 4 CH in the Solar Spectrum A
2 Δ—X
2 Π (2, 2)
Laboratory Sun
Q1c Q1d Q2c Q2d R1dc R1cd R2dc R2cd Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 20 20 7 23587.31* 4238.374 4238.395 9.7 ud? + 0.021 CH La ii B 23, 22 6 23584.39* 4238.899 4238.944 9.7 sN + 0.045 Cr i M 22 4 23583.67 4239.028 4239.044 3.8 + 0.016 Fe i p CH B 23 3 23583.23 4239.108 4239.145 2.4 + 0.037 A 21 } 5
{ 23581.18 23580.53 4239.476 4239.485 2.1 u + 0.009 CH P 21 4239.592 4239.599 2.6 u + 0.007 CH P 24 2 23579.75 4239.733 4239.733 19.8 u 0.000 Mn i —Fe i M 24 2 23578.80 4239.904 4239.953 16.5 u + 0.049 Fe i M 19 19 8 23577.18* 4240.195 4240.199 4.7 w? + 0.004 CH P 20 6 23574.93 4240.600 4240.610 2.2 + 0.010 CH P 20 6 23574.29 4240.715 4240.702 14.1 u −0.013 Cr i M 25 2 23570.94 4241.318 4241.328 1.2 u + 0.010 CH—- B 25 2 23569.86 4241.512 4241.521 2.8 sd + 0.009 CH B 19 (CH) 23565.38* 4242.318 4242.283 5.2 wN * −0.035 —CH M 18 19 18 (CH) 23564.69* 4242.443 4242.455 20.0 + 0.012 CH M 18 } 9
{ 23554.22 23553.81 4244.328 4244.340 3.1 u + 0.012 CH P 18 4244.403 4244.403 3.3 u 0.000 CH—Fe i B 17 17 12 23550.06* 4245.078 4245.082 6.6 wN + 0.004 CH— B 17 } 6
{ 23540.65 23540.32 4246.776 } 4246.837 40.3 w?
{ + 0.061 + 0.002 } Sc ii M 17 4246.835 16 16 11 23533.52* 4248.062 4248.055 7.3 w?N −0.007 CH P 16 (CH) 23524.74* 4249.648 4249.637 23.0 ud −0.01l —CH M 16 M 23524.50 4249.691 —CH A 15 15 13 23515.35* 4251.345 4251.331 8.2 s −0.014 B 15 15 18 23507.64* 4252.739 4252.756 11.8 u + 0.017 CH P 14 M 23496.01 4254.844 4254.846 3.3 u + 0.002 CH P 14 (CH) 23495.17* 4254.996 4254.979 27.0 ud −0.017 Fe i —CH M 14 14 24 23488.93* 4256.127 4256.136 5.2 0 + 0.009 CH— B 13 M 23475.27 4258.603 4258.619 19.2 u + 0.016 Fe i M 13 (CH) 23474.60* 4258.725 4258.731 12.9 w + 0.006 CH— M 13 13 22 23468.90* 4259.759 4259.764 8.2 w? + 0.005 CH— B 12 15 23453.31 4262.591 4262.585 4.7 w −0.006 CH P 12 15 23452.66 4262.709 4262.710 7.3 + 0.001 CH P 12 } 20
{ 23447.98 23447.58 4263.560 } 4263.608
{ + 0.048 − 0.024 } CH—CH B 12 4263.632 8.7 ud? 11 (CH) 23430.54* 4266.733 4266.742 10.3 + 0.009 CH M 11 16? 23429.67 4266.891 4266.968 19.0 u + 0.077 Fe i M 11 M 23425.88 4267.582 4267.588 4.9 s + 0.006 CH P 11 (CH) 23424.91* 4267.759 4267.749 13.1 uN −0.010 CH M 10 10 23406.90 4271.042 4271.057 6.1 + 0.015 CH—Cr i B 10 10 23405.76 4271.250 4271.164 52.2 u −0.086 Fe i M 10 10 23402.96 4271.761 4271.774 177.0 s + 0.013 Fe i M 10 10 23402.13 4271.913 4271.949 18.2 uN + 0.036 Fe i p CH B 9 8? 23382.42 4275.514 4275.513 2.6 −0.001 CH P 9 8? 23380.90 4275.791 A 9 8? 23379.27 4276.090 4276.103 4.7 + 0.013 CH— B 9 23378.17 4276.291 4276.274 4.4 −0.017 —CH B 8 8 (CH) 23357.76* 4280.028 4280.037 15.0 wd? + 0.009 CH M 8 (CH) 23355.75* 4280.396 4280.403 14.2 w + 0.007 Cr i CH M M 23355.21 4280.495 4280.494 2.8 s * −0.001 Gd ii M 8 (CH) 23353.65 4280.781 4280.788 13.7 + 0.007 Sm ii CH M 7 10? 23332.39 4284.683 4284.686 11.7 u + 0.003 Ni i M 7 7 M 23330.41* 4285.046 4285.008 17.5 s −0.038 CH Ti i | M 7 (CH) 23328.63* 4285.373 4285.371 7.9 −0.002 CH M 6 14 23306.74 4289.398 4289.372 30.5 s −0.026 Ca i M 6 14 23305.26 4289.670 } 4289.729 53.6 S
{ + 0.059 − 0.086 } Cr i M 6 14 23304.47 4289.815 6 14 23303.01 4290.084 4290.057 4.9 u −0.027 CH P 5 14 23280.93 4294.153 4294.142 50.5 s −0.011 Fe i Ti ii M 5 14 23279.84 4294.354 4294.370 6.3 u + 0.016 CH P 5 16 23278.19 4294.659 4294.623 7.2 ud −0.036 W i —CH B 5 16 23277.23 4294.836 4294.859 1.6 + 0.023 CH P 4 M 23254.96 4298.949 4298.994 27.2 s + 0.045 Ca i M 4 (CH) 23253.88* 4299.148 4299.138 24.2 u? −0.010 CH M 4 M 23251.70 4299.551 4299.483 18.1 u −0.068 CH Fe i p M 4 M 23250.98 4299.684 4299.645 19.1 s −0.039 ‖Ti i Fe i M 3 (CH) 23229.30* 4303.697 4303.723 13.2 W + 0.026 CH— M 3 (CH) 23228.59* 4303.829 4303.835 28.6 u + 0.006 CH M 3 3 (CH) 23224.53* 4304.581 4304.571 25.1 w −0.010 Fe i CH M 2 (CH) 23204.18* 4308.356 4308.381 14.2 + 0.025 CH M (CH) 23203.77* 4308.432 4308.441 11.1 + 0.009 CH M 2 2 (CH) 23197.31* 4309.632 4309.634 21.8 u + 0.002 ‖Y ii CH M 1 1 (CH) 23189.12* 4311.154 4311.167 17.9 + 0.013 CH M 1 1 28 23169.49* 4314.807 4314.807 16.2 s 0.000 Ti i M 11, 10, 9, 8 } 100 {23125.56* 4323.004 4323.013 15.5 + 0.009 CH P
Open in a separate window Laboratory Sun
P1dc P1cd P2dc P2cd Q1c Q1d Q2c Q2d Intensity Wave Number ber cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 2 12, 7, 2 } {23125.26* 4323.059 4323.063 6.5 + 0.004 CH P 12, 11, 10 13, 9 13, 6, 5 4 } 150
{ 23124.49 * 23124.26 * 4323.204 4323.247 } 4323.226 23.6
{ + 0.022 − 0.021 } CH—CH B 8 14, 3 90 23123.67* 4323.357 4323.367 11.1 u +0.010 CH Fe i p B 14, 7
{ 9 , 8 , 7 6 , 5 , 4 3 } } 120
{ 23122.98 * 23122.25 * 4323.487 4323.512 24.7 u + 0.025 CH— B 6 10 4323.622 4323.611 18.7 uN −0.011 CH P 9, 8, 7, 6 5 11 15 } 155
{ 23121.14 * 23120.47 * 23119.78 * 4323.830 4323.851 26.6 + 0.021 CH P 10, 5 15, 4 4323.955 4323.973 13.2 + 0.018 CH P 11, 4 12 4324.084 4324.087 9.9 + 0.003 CH P 12, 3 3 60 23119.23* 4324.188 4324.176 9.2 −0.012 CH P 13 16 13 16 } 60
{ 23118.20 * 23118.04 * 4324.381 } 4324.412 17.8
{ + 0.031 + 0.002 } CH CH B 2 2 4324.410 14 14 31 23115.79* 4324.831 4324.819 9.9 w −0.012 —CH B 17 17 25 23114.36* 4325.099 4325.141 16.6 s + 0.042 Ti i M 15 15 28 23113.03* 4325.348 4325.356 15.5 u + 0.008 CH P 16 18 16 18 43 23109.38* 4326.031 4326.052 13.2 uN + 0.021 CH P 17 20 23104.87 4326.875 } 4326.917 8.6 w
{ + 0.042 − 0.020 } CH—CH B 17 18 23104.54 4326.937 19 19 20 23103.46* 4327.139 4327.157 2.0 u? + 0.018 CH P 18 } 14
{ 23099.13 23098.73 4327.951 4327.917 16.2 u −0.034 Fe i M 18 4328.025 4328.035 6.2 + 0.010 CH P 20 20 15 23095.65* 4328.602 4328.610 8.1 u + 0.008 CH P 19 } 20
{ 23092.07 23091.55 4329.274 4329.289 6.9 u + 0.015 CH P 19 4329.371 4329.391 6.0 u + 0.020 CH P 21 21 12 23086.07* 4330.399 4330.408 5.3 uN * + 0.009 CH P 20 4 23083.08 4330.960 4330.956 9.7 u −0.004 Fe i M 20 10 23082.71 4331.029 4331.053 3.5 w + 0.024 CH— B 22 22 10 23074.38* 4332.593 4332.583 6.7 uN −0.010 Cr i —CH B 21 } 10
{ 23071.89 23071.36 4333.061 4333.051 2.8 u −0.010 CH Fe i p B 21 4333.160 4333.206 3.2 u + 0.046 Ni i ? CH? B 23 23 12 23060.07* 4335.282 4335.274 7.6 u −0.008 CH P 3 3? 23046.10 4337.909 4337.925 24.0 w + 0.016 Ti ii M 3 M 23045.62 4338.000 A 24 24 8? 23042.30* 4338.625 4338.627 3.2 + 0.002 CH P 3 3 4 23040.32* 4338.998 4339.010 2.3 u + 0.012 CH P 25 6 23020.97 4342.645 A 25 2 23020.54 4342.726 A 4 4? 23019.34 4342.952 4342.990 1.7 u ?+ 0.038 CH? P 4 (CH) 23018.16* 4343.175 4343.216 15.0 ud * + 0.041 Cr i Fe i p M 4 (CH) 23015.42* 4343.692 4343.705 18.6 u + 0.013 Fe i M 4 M 23014.66 4343.835 4343.854 0.8 + 0.019 CH—Fe i p B 26 4? 22996.59 4347.249 4347.242 9.9 s −0.007 Fe i M 26 4? 22995.86 4347.386 4347.370 0.8 −0.016 —CH B 5 M 22993.38 4347.855 4347.841 15.4 w? −0.014 Fe i M 5 M 22992.02 4348.113 4348.104 2.5 −0.009 CH P 5 M 22990.15 4348.466 4348.492 2.3 u + 0.026 CH P 5 4 22989.26 4348.635 4348.636 1.7 u +0.001 CH P 6 4 22967.77 4352.704 4352.743 32.6 s + 0.039 Fe i M 6 } 2
{ 22965.78 22965.27 4353.081 4353.053 2.5 −0.028 CH P 6 4353.177 4353.172 6.9 o? −0.005 —CH B 6 3 22963.88 4353.441 4353.435 2.3 uN — 0.006 CH P 7 4 22942.48 4357.502 4357.514 8.7 +0.012 Cr i Fe i pFe i p M 7 7 7 22940.47* 4357.883 4357.869 5.5 u −0.014 CH P 7 3 22938.68 4358.224 4358.170 8.7 s −0.054 Nd ii M 8 22917.66 4362.221 4362.216 5.5 u −0.005 CH P 8 22915.87* 4362.562 4362.533 12.1 w? −0.029 —CH M 8 22914.81* 4362.764 4362.746 10.3 u −0.018 CH M 8 22913.71 4362.974 4362.953 3.9 u −0.021 Cr i Cr ii M 9 22892.74 4366.970 A 9 22891.49 4367.208 4367.195 2.5 −0.013 Ni i —CH B 9 22889.92* 4367.508 4367.475 5.7 u −0.033 CH P 9 22888.68* 4367.745 4367.723 3.2 −0.022 CH M 10 22868.46 4371.606 4371.582 2.7 −0.024 CH P 10 22867.24 4371.840 4371.794 4.1 u −0.046 M 10 22864.72 4372.322 4372.335 6.2 sd * + 0.013 CH— B 10 22863.79 4372.500 4372.493 3.0 −0.007 CH P 11 22844.21 4376.247 4376.216 5.2 −0.031 CH P 11 22843.32 4376.418 4376.405 5.7 −0.013 CH P 11 22839.67 4377.117 4377.087 2.7 −0.030 CH P 11 22838.96* 4377.253 4377.234 19.9 −0.019 CH M 12 22820.27* 4380.838 4380.852 9.6 wN + 0.014 CH— M 12 22819.45 4380.996 4380.990 2.7 ut −0.006 CH P 12 22814.66 4381.915 4381.885 3.0 u −0.030 CH P 12 22814.24 4381.996 4381.989 2.5 u −0.007 CH—Fe i B 13 6 22796.15 4385.473 A 13 6 22795.43 4385.612 4385.611 2.5 −0.001 CH P 13 13 12 22789.68* 4386.718 4386.694 5.2 uN −0.024 CH P 14 4 22772.02 4390.120 4390.114 2.7 −0.006 CH P 14 4 22771.50 4390.221 4390.222 3.6 w + 0.001 CH P 14 14 20? 22764.84* 4391.505 4391.488 8.6 −0.017 CH P 15 22747.67 4394.820 } 4394.852 11.6 s
{ + 0.032 − 0.027 } Ti i M 15 22747.36* 4394.879 15 15 22739.85* 4396.331 4396.309 8.2 −0.022 CH M 16 22723.53 4399.488 4399.482 3.6 s −0.006 CH? P 16 22723.29 4399.535 A 16 16 22714.65* 4401.209 A 17 17 22698.72* 4404.297 4404.277 12.0 u −0.020 |Ti i —CH M 17 17 22689.14* 4406.157 4406.157 5.7 u 0.000 CH V i B 18 18 22673.67* 4409.163 4409.128 11.6 u −0.035 Fe i M 18 22663.07* 4411.226 } 4411.227 5.4 uN
{ + 0.001 − 0.038 CH—CH? B 18 22662.87 4411.265 19 19 22648.10* 4414.142 4414.124 4.3 u −0.018 —CH? B 19 22636.64 4416.377 4416.360 2.9 −0.017 —CH? B 19 22636.20 4416.462 4416.475 8.2 Sd? + 0.013 ‖V i —Ti i ? M 20 20 22621.65* 4419.303 4419.273 3.6 −0.030 Fe i p M 20 22609.31 4421.715 4421.763 7.7 s +0.048 Ti i M 20 22608.76 4421.823 A 21 21 22594.30* 4424.653 A 21 22580.76 4427.305 4427.317 34.6 S + 0.012 Fe i M 21 22580.24 4427.407 A 22 22 22565.75* 4430.250 A 22 22551.22 4433.105 A 22 22550.46 4433.254 4433.230 22.3 u −0.024 Fe i M 23 22520.17 4439.217 A 23 22519.35 4439.379 4439.358 4.3 −0.021 M 24 22487.19 4445.728 A 24 22486.45 4445.874 4445.849 1.1 u −0.025 Zr ii ? A 25 22452.10 4452.677 A 25 22451.15 4452.865 A 26 22414.34 4460.178 A 26 22413.37 4460.371 4460.361 6.3 −0.010 Mn i M 27 22373.38 4468.343 A 27 22372.25 4468.569 A
Open in a separate window Table 7 CH in the Solar Spectrum B
2 Σ
− —X
2 Π (0, 0)
Laboratory Sun
P1 P2 Q1 Q2 R1 R2 Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 7 25 25823.37 3871.363 3871.392 226 +0.029 CN (CH) M 6 27 25822.18 3871.542 3871.563 24.5 +0.021 CH CN—Ni i B 7 34 25821.35 3871.666 3871.651 15.7 −0.015 La ii CH B 8 33 25820.64 3871.773 3871.758 41.8 −0.015 Fe i (CH) M 6 30 25819.84 3871.893 3871.903 14.4 +0.010 CH P B 8 30 25818.73 3872.059 3872.062 25.8 +0.003 CN CH B 5 20 25817.23 3872.284 3872.273 20.9 −0.011 |CN—CH B 5 27 25814.51 3872.692 3872.732 31.8 +0.040 |CN V i ? CH? B 9 26 25813.61 3872.827 3872.834 21.9 +0.007 CH P 9 27 25811.97 3873.073 3873.090 30 +0.017 CH— B 4 16 25808.78 3873.552 3873.575 20.9 +0.023 CN CH? B 4 21 25805.46 3874.050 3874.060 47.6 +0.010 Fe i (CH) M 10 24 25802.18 3874.543 3874.524 23.4 −0.019 —CH B 10 26 25800.65 3874.773 3874.776 22.4 +0.003 CH CN B 3 13 25797.09 3875.308 3875.290 24.5 −0.018 Ti i —CN M 3 17 25792.77 3875.956 3875.948 19.3 −0.008 CN—CH B 11 24 25785.97 3876.978 3876.978 26.9 0.000 CN—CN (CH) M 11 25 25784.56 3877.191 3877.198 19.1 +0.007 CH P 2 8 25782.80 3877.455 3877.451 19.1 −0.004 CN CH B 2 12 25776.44 3878.412 3878.412 33.2 0.000 CH CN—CN B 1 4 25774.08 3878.768 3878.747 61.9 −0.021 Fe i |V ii CN M 12 22 25764.70 3880.180 3880.190 25.7 +0.010 CH P 12 23 25763.37 3880.380 3880.394 22 +0.014 CN (CH) M 1 8 25756.06 3881.482 3881.490 3.2 +0.008 CH P 13 20 25737.87 3884.225 3884.222 10.8 −0.003 CH P P 13 20 25736.60 3884.416 3884.440 9.5 +0.024 CH P 1 10 25723.40 3886.410 3886.428 31.6 +0.018 CH— B 2 20 25706.87 3888.909 3888.938 20.8 +0.029 CH P 1 14 } 27
{ 25705.52 25705.08 3889.113 3889.105 39.4 −0.008 CH P 3889.180 3889.231 14.7 +0.051 CH— B P 14 18 25703.82 3889.370 3889.358 22.1 −0.012 CH Fe i B 2 31 25700.66 3889.848 3889.848 22.1 0.000 CH P 1 5 25698.25 3890.213 3890.196 16.4 −0.017 V i —Mg i ? M 3 29 25695.99 3890.555 3890.568 16.7 +0.013 ‖CH—Nd ii B 3 39 25691.81 3891.188 3891.198 20.4 +0.010 CH P 4 38 25682.60 3892.584 3892.591 16.4 +0.007 CH P 1 20? 25680.35 3892.925 3892.898 26.2 −0.027 |Fe i V i (CH) M 4 47 25679.40 3893.069 3893.074 30.3 +0.005 CH P 5 15 } 49
{ 25666.16 25665.63 3895.077 3895.088 21.2 +0.011 CH—Ce ii B 3895.157 3895.167 12.6 +0.010 CH P 15 20? 25664.45 3895.337 3895.334 19.3 u −0.003 CH— B 5 54 25663.66 3895.457 3895.448 42.3 u −0.009 Fe i p—CH| B 2 13 25656.61 3896.527 3896.534 5.9 +0.007 Zr i ? CH? B 2 18 25650.29 3897.487 3897.458 28.4 u −0.029 Fe i (CH) M 6 51 25646.44 3898.072 3898.094 18.7 s * +0.022 CH P 6 58 25644.34 3898.391 3898.394 22.4 u +0.003 CH P 7 55 25623.25 3901.600 3901.598 20 u −0.002 CH P 7 65 25621.54 3901.860 3901.866 21.4 u +0.006 CH P 3 25? 25620.87 3901.962 3901.977 13.3 u +0.015 CH—Cr i B 16 6 25618.96 3902.253 3902.262 21.5 s +0.009 V i (CH) M 16 7 25617.86 3902.421 3902.430 14.9 u +0.009 Gd ii —CH B 3 23 25616.58 3902.616 3902.632 15.9 +0.016 CH P 8 59 25596.57 3905.667 3905.679 46.1 +0.012 |CH Fe i p B 8 64 25595.02 3905.904 3905.905 25.9 u +0.001 CH P 4 23 25582.80 3907.770 3907.774 12.8 u +0.004 Cr i CH B 4 27 25579.53 3908.268 3908.274 13.8 +0.006 CH P 9 59 25566.07 3910.327 3910.334 24.3 +0.007 CH P 9 64 25564.66 3910.542 3910.534 30.4 −0.008 CH P 17 M 25563.94 3910.653 3910.667 16 u +0.014 M 17 1 25562.81 3910.825 3910.849 26.1 u +0.024 Fe i M 5 28 25542.01 3914.010 3914.013 16.6 +0.003 CH P 5 32 25539.32 3914.422 3914.426 26.1 u +0.004 CH P 10 59 25531.63 3915.601 3915.612 23 +0.011 CH P 10 63 25530.36 3915.796 3915.811 32 s ?+0.015 CH—Cr i B 6 18 30 25498.30 3920.720 3920.729 27.8 u +0.009 CH— B 6 33 25496.00 3921.073 3921.049 42.1 s −0.024 Cr i (CH) M 11 57 25492.92 3921.547 3921.556 27.8 w +0.009 CH P 11 59 25491.85 3921.712 3921.716 26.8 u +0.004 CH P 7 32 25451.42 3927.941 3927.933 159 S −0.008 Fe i (CH) M 7 12 86 25449.63* 3928.218 3928.217 49.4 u −0.001 CH P 12 63 25448.80 3928.346 3928.345 32.8 −0.001 CH P 8 13 80 25401.73* 3935.625 3935.645 31 uN +0.020 CH P 13 65? 25401.03 3935.734 3935.73 18 0.00 CH P 8 38 25399.72 3935.937 3935.979 59.4 s +0.042 Co i (CH) M 14 65? 25348.77 3943.848 3943.820 39.6 uN −0.028 CH P 9 14 78 25348.16* 3943.943 3943.918 8.9 −0.025 Ce ii —CH| B 9 37 25346.65 3944.178 3944.179 33.1 uN +0.001 |CH— B 10 34 25291.71 3952.746 3952.756 6.3 +0.010 CH P 10 15 79 25290.26* 3952.973 3952.982 28 s * +0.009 CH P 15 50? 25289.46 3953.098 3953.084 12.5 o ?−0.014 CH P 11 33 25231.54 3962.172 3962.184 21.4 u +0.012 CH— B 11 35.5 25230.12 3962.395 3962.398 8.8 +0.003 CH P 16 } 36
{ 25225.46 25224.93 3963.127 3963.115 44.9 u −0.012 Fe i (CH) M 16 3963.211 3963.233 28.5 u +0.022 CH P 12 31 25167.58 3972.242 3972.267 15.8 w? +0.025 CH P 12 32 25166.26 3972.450 3972.44 13.3 uN −0.01 Co i CH B 17 } 18
{ 25153.89 25153.48 3974.404 3974.396 27.3 u −0.008 Fe i (CH) M 17 3974.469 3974.497 25.9 u +0.028 CH— B 13 27.5 25099.63 3982.996 3983.008 15.3 +0.012 CH— B 13 30 25098.41 3983.190 3983.199 16.5 u +0.009 CH— B 18 } 4
{ 25074.46 25074.17 3986.994 }3986.994 13.7 uN
{ 0.000 − 0.046 CH— B 18 3987.040 M 14 25 25027.29 3994.509 3994.514 17.6 u + 0.005 CH—Co i | B 14 26 25026.13 3994.693 3994.683 16.5 u −0.010 Ti i Nd ii CH B 19 24986.23 4001.074 4001.110 6.0 + 0.036 A 15 20 24950.24 4006.845 4006.825 10.5 uN −0.020 —CH B 15 21 24949.16 4007.018 4006.997 14.5 u −0.021 CH P 16 17.5 24868.31 4020.046 4020.029 8.5 u? −0.017 —CH B 16 18 24867.27 4020.214 4020.193 10.7 u −0.021 —CH B 17 13 24780.76 4034.249 4034.232 12.9 u −0.017 —CH B 17 13 24779.74 4034.415 4034.386 9.9 −0.029 CH P 18 6.5 24686.90 4049.587 4049.565 10.1 u −0.022 CH P 18 5.5 24685.91 4049.750 4049.731 11.6 u −0.019 CH P 19 24585.82 4066.237 4066.220 6.4 u −0.017 —CH B 19 24584.86 4066.396 4066.373 18.7 s −0.023 Co i M 20 24476.39 4084.417 A
Open in a separate window * Blend.
‡ Satellite line as follows:
Designation J Laboratory Wave number Wavelength PQ 12 1 25698.25 3890.213
Open in a separate window Table 8 CH in the Solar Spectrum B
2 Σ
− —X
2 Π (1, 0)
Laboratory Sun
P1 P2 Q1 Q2 R1 R2 Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ ⊙—lab. A Solar identification Notes 3 0.9 27561.60 3627.202 3627.169 5 −0.033 B 2, 1 1.0 27559.78 3627.442 3627.456 3.2 +0.014 CH P 4 } 1.9
{ 27558.31 27557.74 3627.635 3627.623 11.3 −0.012 Mg i ? CH B 3 3627.710 3627.715 0.7 +0.005 V ii Ti ii M 4 1.5 27554.95 3628.078 3628.098 21.8 +0.020 Fe i M 2 0.9 27553.45 3628.275 3628.279 6.8 +0.004 CH P 5 1.4 27548.01 3628.992 3629.006 4.4 +0.014 CH P 5 1.8 27545.17 3629.366 3629.352 4.4 −0.014 CH P 1 0.7 27542.25 3629.751 3629.737 14 −0.014 Mn i M 6 1.2 27530.49 3631.301 3631.265 45.4 −0.036 A 6 1.5 27528.25 3631.596 3631.586 31.2 −0.010 M 1 1.0 27515.40 3633.292 3633.308 6.6 +0.016 CH P 7 1.1 27505.35 3634.620 3634.618 5 −0.002 CH P 7 1.0 27503.40 3634.878 3634.865 5.1 −0.013 CH P 1 1.5 27497.52 3635.655 3635.652 4.7 −0.003 Ti i p? CH B 1 2 ‡ 2.1 27492.88* 3636.269 3636.238 16.5 −0.031 Fe i M 2 2.3 27486.64 3637.094 3637.058 10.7 −0.036 Fe i M 1 1.1 27475.26 3638.601 3638.605 2 +0.004 CH P 3 2.4 27472.90 3638.913 3638.905 4.4 −0.008 CH P 8 M 27472.28 3638.996 3639.030 9.1 +0.034 V i — M 8 M 27470.15 3639.277 3639.285 14.3 +0.008 M 3 2.9 27468.73 3639.466 3639.450 18.7 −0.016 Co i M 2 M 27448.48 3642.151 3642.147 22.8 −0.004 —CH B 4 2.9 27447.38 3642.297 3642.281 5.9 −0.016 CH P 4 3.6 27444.25 3642.712 3642.682 31.8 −0.030 Ti i M 2 1.5 27442.25 3642.978 3642.971 5.4 −0.007 CH P 9 0.1? 27429.39 3644.686 3644.695 15.8 +0.009 Cr ii M 9 0.1? 27428.09 3644.859 A 5 3.2 27415.56 3646.525 3646.504 6.6 −0.021 CH P 5 3.9 27413.08 3646.855 3646.837 9.9 −0.018 —CH B 3 1.3 27406.76 3647.696 3647.669 59.6 −0.027 Co i M 3 1.8 27402.50 3648.263 3648.228 14 −0.035 Fe i p—CH B 6 3.6 27377.09 3651.649 3651.654 28 +0.005 Ni i Cr ii M 6 4.0 27375.02 3651.925 3651.921 25.6 −0.004 —CH B 4 1.8 27359.76 3653.962 3653.979 20.2 +0.017 Fe i M 4 2.1 27356.49 3654.398 3654.386 5.1 −0.012 CH P 7 3.5 27331.61 3657.725 3657.711 21.2 −0.014 Ni i Fe i | M 7 3.6 27329.83 3657.963 A 5 2.1 27306.82 3661.046 3661.038 10.4 −0.008 CH P 5 2.3 27304.15 3661.404 3661.372 22.6 −0.032 Sm ii Fe i —V ii M 8 2.2 27278.56 3664.839 3664.828 13 −0.011 CH P 8 2.3 27277.08 3665.038 3665.028 13.9 −0.010 —CH B 6 2.2 27247.74 3668.984 3668.969 23 −0.015 Ti i M 6 2.6 27245.47 3669.290 3669.244 35 −0.046 Ni i M 9 1.0 27217.46 3673.066 3673.087 32.7 +0.021 Fe i — M 9 1.0 27216.18 3673.239 3673.226 17.2 −0.013 —CH B 7 2.4 27182.16 3677.836 3677.855 38.5 +0.019 Cr ii M 7 2.6 27180.21 3678.100 3678.100 12.9 0.000 CH P 8 2.2 27109.90 3687.640 3687.660 41.7 +0.020 Fe i M 8 2.5 27108.14 3687.878 3687.866 7.6 −0.012 CH P 9 1.2 27030.43 3698.482 3698.477 7.3 −0.005 —CH B 9 1.2 27028.86 3698.697 3698.694 6.8 −0.003 CH P 10 0.5 26942.95 3710.490 A 10 0.5 26941.64 3710.670 3710.638 10.8 −0.032
Open in a separate window * Blend.
‡ Satellite line as follows:
Designation J Laboratory Wave No. Wavelength PQ 1 2 1 27492.88 3636.269
Open in a separate window Table 9 CH in the Solar Spectrum B
2 Σ
− — X
2 Π (1, 1)
Laboratory Sun
P1 P2 Q1 Q2 R1 R2 Intensity Wave number cm−1 Wavelength A Wavelength A Disk int. Δλ/λ Spot ⊙—lab. A Solar identification Notes 4 1 24835.75 4025.316 4025.308 3.5 −0.008 CH P 3 2 24835.22 4025.402 4025.429 11.9 u +0.027 |Ni i Cr i M 4 2 24832.45 4025.851 4025.823 15.9 u −0.028 M 3 5 3.5 24830.76* 4026.125 4026.168 10.7 sd +0.043 Cr i M 2 0.5 24829.60 4026.313 4026.310 1.7 −0.003 CH P 5 1 2.5 24828.06* 4026.562 4026.542 10.4 s −0.020 Ti i M 2 1 24823.62 4027.283 4027.251 2.4 s −0.032 Zr i —CH B 6 0.5 24819.66 4027.926 4027.943 7.0 u +0.017 CH— B 6 0.5 24817.25 4028.317 4028.346 22.3 u +0.029 Ti ii M 1 0.5 24810.17 4029.466 4029.443 2.5 u −0.023 CH P 7 0.5 24801.91 4030.808 4030.763 53.1 S −0.045 Mn i M 7 0.5 24799.95 4031.127 4031.116 4.2 u −0.011 Cr i M 1 0.5 24783.46 4033.809 4033.790 2.4 u −0.019 CH P 1 2 24765.72 4036.699 4036.670 1.5 −0.029 CH P 2 2 24762.79 4037.177 4037.121 10.9 u −0.056 M 1 ‡ 0.5 24761.26 4037.426 4037.438 1.2 +0.012 CH P 2 3.5 24756.88 4038.140 4038.124 3.2 s −0.016 M 3 3.5 24746.14 4039.893 4039.864 2.2 s −0.029 M 1 1.5 24743.41 4040.339 4040.310 4.0 s —.0.029 Ti i —CH B 3 4 24742.16 4040.543 4040.514 6.9 u −0.029 —CH B 4 4.5 24724.98 4043.350 4043.346 5.9 uN −0.004 CH P 4 4.5 24721.89 4043.856 4043.906 22.0 u +0.050 Fe i M 2 0.5 24718.50 4044.410 4044.380 1.7 −0.030 CH P 2 1 24712.51 4045.391 4045.390 25.0 u −0.001 Co i M 5 4 24698.42 4047.699 4047.673 5.4 s −0.026 Y i —CH B 5 5 24696.01 4048.093 4048.072 5.9 u −0.021 —CH B 3 1 24680.01 4050.718 4050.680 14.1 u −0.038 Fe i M 3 2 24675.90 4051.392 A 6 4 24666.30 4052.969 4052.940 7.9 u −0.029 Ti i —CH B 6 5 24664.35 4053.290 4053.271 15.0 u −0.019 Fe i M 4 2 24637.26 4057.747 4057.733 3.2 −0.014 CH P 4 3 24634.33 4058.229 4058.221 24.9 s −0.008 Co i Fe i ‖ M 7 3.5 24628.23 4059.234 4059.222 5.7 u −0.012 CH P 7 4 24626.54 4059.513 4059.502 5.7 u −0.011 CH P 5 4 24589.48 4065.632 4065.587 3.7 u −0.045 Ti i CH B 5 3.5 24587.06 4066.032 4066.004 3.0 u −0.028 Fe i p—CH B 8 2 24583.70 4066.588 4066.590 19.7 u +0.002 Fe i M 8 3 24582.18 4066.839 4066.820 7.6 u −0.019 CH P 6 2.5 24536.85 4074.352 4074.332 4.4 sN −0.020 Ti i W i M 6 3 24534.69 4074.711 4074.684 14.0 u −0.027 Fe i p M 9 1.5 24532.00 4075.158 4075.103 15.2 u −0.055 M 9 0.5 24530.85 4075.349 4075.316 7.6 uN −0.033 —CH B 7 3 24478.67 4084.036 4083.999 4.9 u −0.037 CH? P 7 3.5 24476.75 4084.357 4084.327 6.4 u −0.030 CH P 8 2.5 24414.86 4094.710 4094.698 5.9 u −0.012 CH P 8 2.5 24413.13 4095.000 4094.938 25.4 s −0.062 Ca i M 9 1 24344.81 4106.493 4106.432 19.5 u −0.061 Fe i M 9 1 24343.31 4106.746 4106.730 3.8 u −0.016 CH P 10 0.3 24268.04 4119.483 4119.526 7.1 s +0.043 Fe ii p M 10 0.3 24266.88 4119.680 4119.671 5.6 sd ?−0.009 Fe i p—CH B
Open in a separate window * Blend.
‡ Satellite line as follows:
Designation J Laboratory Wave No. Wavelength PQ 1 2 1 24761.26 4037.426
Open in a separate window Under the general heading, “Sun,” the solar wavelengths are from the new solar ledger now in course of preparation. These wavelengths differ slightly from those published in 1928, because a running correction has since been made to reduce them to the 1928 International Solar Standards [
11 ]. In addition, some new measurements have been averaged in for a number of lines. This work is in progress for the region short of 4000 A. Consequently, some solar wavelengths quoted in the present paper may differ slightly from those in the final solar ledger. The changes are so slight that they will not likely affect the CH identifications.The second solar column contains the reduced equivalent widths of the solar lines furnished by Minnaert and his colleagues at the Utrecht Observatory. The equivalent widths have been measured in milliangstroms (mA) from the Utrecht Solar Atlas [
12 ]. The tabular entries have been reduced from the measured values by dividing by X, and by allowing for the effect of blending when there is more than one contributor effective in producing the solar line. Details of the method are described by Minnaert in his 1951 paper [
13 ]. These measured intensities replace the Rowland eye estimates for all solar lines except those in . In this spectral region the measured intensities have not yet been completed, and in their place the Rowland estimates are entered in brackets, —3 being substituted for Rowland’s 0000,
— 2 for 000, etc., as was done in 1928 [
1 ].In the solar column headed, “Spot,” the intensity behavior of the solar atomic lines in the spot spectrum is described as follows:
d double S greatly N diffuse strengthened NN very diffuse u unchanged o obliterated w weakened s strengthened W greatly weakened
These letters have been substituted for the estimated spot intensities published in more detail in 1933 [
14 ]. Although the spot behavior was studied especially for atomic lines, in many cases it was noted in the 1933 paper when a line was a blend of an atomic and a molecular line in the spot spectrum as judged by the observed Zeeman effect, and the molecular contributor has turned out to be CH. An asterisk in this column indicates that the spot behavior refers to two adjacent solar lines; i.e., two disk lines are blended in the spot spectrum.Following the spot column there is one headed “⊙–lab.” This is the difference, expressed in A, between the solar and laboratory wavelengths, another criterion used in making the identification of the solar line. Residuals greater than ±0.030 A are tolerated only if the solar line is very faint or blended, and in either case the CH identification is subject to question.The next column gives the final adopted solar identification. Here the symbol |, preceding or following the chemical symbol, indicates that the line so marked is a stronger contributor to the solar line than other contributors. The symbol ‖ denotes a predominant contributor. Parentheses are used in this column for lines masked in the solar spectrum. Only the more important masked CH lines are thus noted in the tables. For those CH lines marked (CH) or (M) in the laboratory intensity column, if the solar identification refers to the CH line responsible for the masking, M is entered in the last column (see below).In the last column four letters are used to indicate the judgment of the authors regarding the assigned identifications of the solar lines. They are as follows:
P The CH line is present in the solar spectrum, as indicated in the preceding column. B The CH line is present in the solar spectrum but blended. A blend means that there are at least two contributors to the solar intensity. M The CH line of the band in question is masked in the solar spectrum. This category includes CH lines too faint to contribute appreciably to solar lines. In some cases the solar identification may read “CH” but it refers to a CH line in another band. A The CH line is absent from solar spectrum. Ends of branches at high J -values, where the line is too faint to be expected in the sun, are not counted as absent. Although there are a few wavelength agreements, these weak lines have been arbitrarily excluded from the count. The present paper is one of a series planned to include the data on individual molecules present in the sun. A general survey of the molecular program was presented by the authors in Liège in 1956 [
15 ]. It is hoped that the format adopted in the present tables may serve as a guide to those interested in preparing papers on molecular spectra in a style useful for astrophysical purposes.The authors are most grateful to Mrs. Isabel D. Murray for her very accurate and painstaking work in helping to prepare the tables.
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