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51.
This paper presents a generalized relevance model for automatic image annotation through learning the correlations between images and annotation keywords. Different from previous relevance models that can only propagate keywords from the training images to the test ones, the proposed model can perform extra keyword propagation among the test images. We also give a convergence analysis of the iterative algorithm inspired by the proposed model. Moreover, to estimate the joint probability of observing an image with possible annotation keywords, we define the inter-image relations through proposing a new spatial Markov kernel based on 2D Markov models. The main advantage of our spatial Markov kernel is that the intra-image context can be exploited for automatic image annotation, which is different from the traditional bag-of-words methods. Experiments on two standard image databases demonstrate that the proposed model outperforms the state-of-the-art annotation models.  相似文献   
52.
    
The microhardness and micromodulus on the surface of poly(vinyl chloride) (PVC)/styrene‐butadiene rubber (SBR) blends were determined using a nanoindenter. A flat surface was obtained by microtoming the sample at ?100°C in liquid nitrogen. Dozens of indents along a line with a spatial interval of 0.5 μm were performed. From the loading and unloading curves of each indentation, the stiffnesses of the unloading curve and the contact area between the sample and the indenter were evaluated, and the local modulus and hardness were calculated. Profiles of the local hardness and modulus were obtained from the lines of indents. Pure PVC and a miscible PVC/acrylonitrile‐butadiene rubber (NBR) (40/10) blend showed constant modulus and hardness values. In the case of an immiscible PVC/SBR (50/50) blend, which has a morphology of elongated PVC droplets in the SBR matrix, the hardness and modulus profiles showed regions of the different phases. At the interface between the SBR and PVC phases, a step change in the modulus and hardness profiles was observed. The force required to deform the material at the same displacement increased systematically across the interface from the SBR to the PVC phase because of the increasing contribution of the PVC phase. Polym. Eng. Sci. 44:609–614, 2004. © 2004 Society of Plastics Engineers.  相似文献   
53.
    
A new approach for improving the wear performances of nylon 6 (PA6)/clay nanocomposites was examined in this study. Two hybrid nanocomposites were prepared by melt blending a thermotropic liquid crystalline polymer (TLCP) and a well‐dispersed PA6/clay nanocomposite, but with and without the incorporation of maleic‐anhydride grafted polypropylene (MAPP) as compatibilizer. The addition of MAPP improved the compatibility between TLCP and matrix and thus enhanced the fibrillation of dispersed TLCP phase. Wear‐testing results revealed that the wear resistance of the compatibilized hybrid nanocomposite could be improved effectively, as indicated by the low values of specific wear rate and frictional coefficient, especially under high‐normal load (i.e., 80 N). Based on the characterization on the worn damage and the debris, it was suggested that abrasive wear was the main‐damage mechanism for all the materials under investigation, except for the compatibilized hybrid nanocomposite. For this system, the wear damage was caused by a combination of abrasive and adhesive wearing because of the formation of transfer film on the counter pin surface from the wear debris. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers  相似文献   
54.
    
It has been found, in this study, that there is no close correlation between the tensile and nanoindentation moduli of polyamide 6 (PA6) at high temperatures. It is demonstrated that heat modifies the surface of PA6 specimens, but its effect on the nanomechanical properties is minor. The main spurious factor which affects the nanoindentation results is adhesion, especially at low indentation depths. The overestimation in the measured indentation moduli can be corrected by performing indentations with loads high enough so that the modulus is independent of the applied load. It is concluded that the lack of strict correlations between the tensile and indentation moduli (after corrections of adhesion) is caused by the shift in the glass transition temperature of PA6 owing to the hydrostatic stress imposed by the indenter. Further proof is given with two examples on hydrostatic pressure‐dependent polymers: polytetrafluoroethylene and polycarbonate. Copyright © 2011 Society of Chemical Industry  相似文献   
55.
    
Nylon 66 nanocomposites were prepared by melt compounding of nylon 66 with organically modified montmorillonite (MMT). The organic MMT was pre‐modified with about 14 wt% of ammonium surfactant, much lower than the 35–46 wt% in most commercial organic MMT powders. Transmission electron microscope observation indicated that the MMT layers were well exfoliated in nylon 66 matrix. Dynamic mechanical analysis confirmed the constraint effect of exfoliated MMT layers on nylon 66 chains, which benefited the increased storage modulus, increased glass transition temperature and reduced magnitude of alpha relaxation peak. The effects of organic MMT loading levels on reinforcement and fracture behaviour of the nanocomposites were evaluated using tensile and three‐point bending tests. The addition of the organic MMT clearly increased Young's modulus and tensile strength but decreased ductility and fracture toughness of nylon 66. Copyright © 2004 Society of Chemical Industry  相似文献   
56.
    
Polypropylene hybrid composites reinforced with short glass fiber (SGF) and toughened with styrene–ethylene butylenes–styrene (SEBS) elastomer were prepared using extrusion and injection‐molding techniques. Moreover, hybrids compatibilized with SEBS‐grafted maleic anhydride (SEBS‐g‐MA) and hybrid compatibilized with PP grafted with maleic anhydride (PP‐g‐MA) were also fabricated. The matrix of the latter hybrid was designated as mPP and consisted of 95% PP and 5% PP‐g‐MA. Tensile dilatometry was carried out to characterize the fracture mechanisms of hybrid composites. Dilatometric responses showed that the elastic deformation was the dominant deformation mechanism for the SGF/SEBS/PP and SGF/SEBS‐g‐MA/PP hybrids. However, cavitation deformation prevailed over shearing deformation for both hybrids at the higher strain regime. The cavitation strain resulted from the debonding of glass fibers and from the crazing of the matrix in the SGF/SEBS/PP hybrid. In contrast, the cavitation was caused by the debonding of SEBS particles from the matrix of the SGF/SEBS‐g‐MA/PP hybrid. The use of PP‐g‐MA resulting in elastic deformation was the main mode of deformation in the low‐strain region for the SGF/SEBS/mPP and SEBS/SEBS‐g‐MA/mPP hybrids; thereafter, shearing appeared to dominate at the higher strain regime. This was attributed to the MA functional group improving the bonding between the SGF and PP. The correlation between fracture morphology and dilatometric responses also is presented in the article. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 441–451, 2003  相似文献   
57.
    
Polymer blending is one of the most effective methods for providing new, desirable biocomposites for tissue‐engineering applications. In this study, electrospun poly(L ‐lactide)/poly(ε‐caprolactone) (PLLA/PCL) blend fibrous membranes with defect‐free morphology and uniform diameter were optimally prepared by a 1 : 1 ratio of PLLA/PCL blend under a solution concentration of 10 wt %, an applied voltage of 20 kV, and a tip‐to‐collector distance of 15 cm. The fibrous membranes also showed a porous structure and high ductility. Because of the rapid solidification of polymer solution during electrospinning, the crystallinity of electrospun PLLA/PCL blend fibers was much lower than that of the PLLA/PCL blend cast film. To obtain an initial understanding of biocompatibility, adipose‐derived stem cells (ADSCs) were used as seed cells to assess the cellular response, including morphology, proliferation, viability, attachment, and multilineage differentiation on the PLLA/PCL blend fibrous scaffold. Because of the good biocompatibility and nontoxic effect on ADSCs, the PLLA/PCL blend electrospun fibrous membrane provided a high‐performance scaffold for feasible application in tissue engineering using ADSCs. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011  相似文献   
58.
    
BACKGROUND: This research investigated the effect of platinum (Pt) on the reactivity of tungsten oxide (WO3) for the visible light photocatalytic oxidation of dyes. RESULTS: Nanocrystalline tungsten oxide (WO3) photocatalysts were synthesised by a sol‐gel process and employed for the photocatalytic degradation of Methyl Orange under visible light. For comparison commercial bulk WO3 materials were also studied for the same reaction. These materials were fully characterised using X‐ray diffraction (XRD), UV‐visible diffuse reflection spectroscopy and transmission electron microscopy (TEM). The photocatalytic oxidation of iso‐propanol was used as a model reaction to follow the concomitant reduction of molecular oxygen. No reactions occured in the absence of platinum, which is an essential co‐catalyst for the multi‐electron reduction of oxygen. The platinised WO3 catalysts were stable for multiple oxidation–reduction cycles. The results from the catalytic activity measurements showed that platinised nanocrystalline WO3 is a superior oxidation photocatalyst when compared with bulk WO3. Methyl Orange was completely decolourised in 4 h. CONCLUSIONS: The enhanced performance of nanocrystalline Pt‐WO3 is attributed to improved charge separation in the nanosized photocatalyst. Platinum is an essential co‐catalyst to reduce oxygen. This photocatalyst could be applied to the treatment of organic pollutants in wastewater, with the advantage of using visible light compared with the widely studied TiO2, which requires UV light. Copyright © 2011 Society of Chemical Industry  相似文献   
59.
    
Compatibilized polypropylene (PP)/polyamide (PA6) blends with and without β nucleating agent (β‐NA) are prepared, and are designated as Blend‐0.3 and Blend‐0, respectively. The melting and crystallization characteristic of the blends crystallized under different cooling rates and different crystallization temperatures are studied. It is observed that high β‐PP content can be developed in Blend‐0.3 only at slow cooling rates (<5°C/min), whereas high α‐PP content is formed at fast cooling rates. Isothermal crystallization analysis of Blend‐0 indicates that PA6 is an effective NA for α‐PP in the lower temperature range, whereas the α‐nucleating effect disappears in the higher temperature range. Blend‐0.3 can, therefore, be viewed as a system containing both α‐ and β‐NAs, simultaneously. PA6 is competing with β‐NA in inducing PP crystallization. Under the normal injection of Blend‐0.3, the melt will be cooled through the higher temperature that favors the effectiveness of β‐NA rapidly because of the faster cooling rate. However, the α‐nucleation effect from PA6 predominate at the lower temperature. This explains the difficulty in obtaining high β‐PP content in Blend‐0.3 from injection molding. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers  相似文献   
60.
Under‐pricing in construction tenders is a common phenomenon and is commonly explained by the need of cash flows and penetration strategy. However, these explanations involve profit cutting and therefore are not plausible in explaining a long‐term persistent phenomenon of under‐pricing. A real options model is proposed and using the binomial lattice method a real‐life construction project tender was analysed to examine how management flexibility and uncertainty provide real options value. When uncertainties of cost items in a tender exist and choices are available to defer and switch modes of construction, then a valuable option is available to the bidders. It amounts to about 4% of the lump sum tendered in our case. The under‐priced portion is the options value which the bidder is willing to pay for the flexibility and the uncertainty. These findings enable contractors to be more competitive and to estimate construction costs more accurately in devising their bid strategies.  相似文献   
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