Effect of Sintering Temperature on Magnetic and Electrical Properties of GdBaCo<Subscript>2</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>5 + <Emphasis Type="Italic">δ</Emphasis></Subscript>

In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo₂ O _{5 + δ} synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples.     

Reducing Hysteresis and Enhancing Performance of Perovskite Solar Cells Using Low‐Temperature Processed Y‐Doped SnO2 Nanosheets as Electron Selective Layers

Despite the rapid increase of efficiency, perovskite solar cells (PSCs) still face some challenges, one of which is the current–voltage hysteresis. Herein, it is reported that yttrium‐doped tin dioxide (Y‐SnO₂) electron selective layer (ESL) synthesized by an in situ hydrothermal growth process at 95 °C can significantly reduce the hysteresis and improve the performance of PSCs. Comparison studies reveal two main effects of Y doping of SnO₂ ESLs: (1) it promotes the formation of well‐aligned and more homogeneous distribution of SnO₂ nanosheet arrays (NSAs), which allows better perovskite infiltration, better contacts of perovskite with SnO₂ nanosheets, and improves electron transfer from perovskite to ESL; (2) it enlarges the band gap and upshifts the band energy levels, resulting in better energy level alignment with perovskite and reduced charge recombination at NSA/perovskite interfaces. As a result, PSCs using Y‐SnO₂ NSA ESLs exhibit much less hysteresis and better performance compared with the cells using pristine SnO₂ NSA ESLs. The champion cell using Y‐SnO₂ NSA ESL achieves a photovoltaic conversion efficiency of 17.29% (16.97%) when measured under reverse (forward) voltage scanning and a steady‐state efficiency of 16.25%. The results suggest that low‐temperature hydrothermal‐synthesized Y‐SnO₂ NSA is a promising ESL for fabricating efficient and hysteresis‐less PSC.     

Multicolor Photo‐Crosslinkable AIEgens toward Compact Nanodots for Subcellular Imaging and STED Nanoscopy

Aggregation induced emission (AIE) has attracted considerable interest for the development of fluorescence probes. However, controlling the bioconjugation and cellular labeling of AIE dots is a challenging problem. Here, this study reports a general approach for preparing small and bioconjugated AIE dots for specific labeling of cellular targets. The strategy is based on the synthesis of oxetane‐substituted AIEgens to generate compact and ultrastable AIE dots via photo‐crosslinking. A small amount of polymer enriched with oxetane groups is cocondensed with most of the AIEgens to functionalize the nanodot surface for subsequent streptavidin bioconjugation. Due to their small sizes, good stability, and surface functionalization, the cell‐surface markers and subcellular structures are specifically labeled by the AIE dot bioconjugates. Remarkably, stimulated emission depletion imaging with AIE dots is achieved for the first time, and the spatial resolution is significantly enhanced to ≈95 nm. This study provides a general approach for small functional molecules for preparing small sized and ultrastable nanodots.     

Bogdanov–Takens bifurcation in a neutral BAM neural networks model with delays

In this study, the authors first discuss the existence of Bogdanov–Takens and triple zero singularity of a five neurons neutral bidirectional associative memory neural networks model with two delays. Then, by utilising the centre manifold reduction and choosing suitable bifurcation parameters, the second‐order and the third‐order normal forms of the Bogdanov–Takens bifurcation for the system are obtained. Finally, the obtained normal form and numerical simulations show some interesting phenomena such as the existence of a stable fixed point, a pair of stable non‐trivial equilibria, a stable limit cycles, heteroclinic orbits, homoclinic orbits, coexistence of two stable non‐trivial equilibria and a stable limit cycles in the neighbourhood of the Bogdanov–Takens bifurcation critical point.Inspec keywords: neurophysiology, neural nets, bifurcation, delays, critical pointsOther keywords: Bogdanov‐Takens bifurcation critical point, neutral BAM neural networks, bidirectional associative memory, delays, triple zero singularity, neurons, centre manifold reduction, bifurcation parameters, second‐order normal forms, third‐order normal forms, numerical simulations, stable fixed point, stable nontrivial equilibria, stable limit cycles, heteroclinic orbits, homoclinic orbits     

Transformation of monolayer MoS<Subscript>2</Subscript> into multiphasic MoTe<Subscript>2</Subscript>: Chalcogen atom-exchange synthesis route

Molybdenum ditelluride (MoTe2),which is an important transition-metal dichalcogenide,has attracted considerable interest owing to its unique properties,such as its small bandgap and large Seebeck coefficient.However,the batch production of monolayer MoTe2 has been rarely reported.In this study,we demonstrate the synthesis of large-domain (edge length exceeding 30 μm),monolayer MoTe2 from chemical vapor deposition-grown monolayer MoS2 using a chalcogen atom-exchange synthesis route.An in-depth investigation of the tellurization process reveals that the substitution of S atoms by Te is prevalently initiated at the edges and grain boundaries of the monolayer MoS2,which differs from the homogeneous selenization of MoS2 flakes with the formation of alloyed Mo-S-Se hybrids.Moreover,we detect a large compressive strain (approximately-10％) in the transformed MoTe2 lattice,which possibly drives the phase transition from 2H to 1T'at the reaction temperature of 500 ℃.This phase change is substantiated by experimental facts and first-principles calculations.This work introduces a novel route for the templated synthesis of two-dimensional layered materials through atom substitutional chemistry and provides a new pathway for engineering the strain and thus the intriguing physics and chemistry.     

Numerical simulation of prestrain history effect on ductile crack growth in mismatched welded joints

Pipe reeling may lead to plastic pre‐deformation (prestrain) around existing cracks in components; therefore, investigating whether this process accelerates or counteracts ductile crack growth, especially for strength mismatched welded joints, is warranted. This study focused on the effect of prestrain history on ductile crack growth in mismatched welded joints. A single‐edge‐notched tension specimen was selected for numerical study, and the crack was assumed to have existed before a prestrain history was applied. Crack growth resistance curves for plane strain and mode I crack growth under large‐scale yielding conditions have been computed using the complete Gurson model. Meanwhile, symmetrical and non‐symmetrical prestrain cycle modes with different loading levels were applied to the overmatched specimens. The outcome demonstrated that the mismatch ratio (the ratio between the yield stress of the weld metal and base metal) showed a significant effect on fracture resistance regardless of the stage at which the prestrain cycle loading was located. By contrast, the processing of the crack growth was weakened by the increase of prestrain values, and the symmetrical prestrain cycle resulted in greater plastic damage than the non‐symmetrical prestrain cycle did. However, the initial crack length had a non‐significant effect on the ductile fracture considering the prestrain and mismatch effects.