全文获取类型
收费全文 | 191191篇 |
免费 | 26495篇 |
国内免费 | 7669篇 |
专业分类
电工技术 | 11831篇 |
技术理论 | 10篇 |
综合类 | 10803篇 |
化学工业 | 39292篇 |
金属工艺 | 9187篇 |
机械仪表 | 10059篇 |
建筑科学 | 13753篇 |
矿业工程 | 4158篇 |
能源动力 | 5384篇 |
轻工业 | 17899篇 |
水利工程 | 3660篇 |
石油天然气 | 7153篇 |
武器工业 | 1454篇 |
无线电 | 25814篇 |
一般工业技术 | 28737篇 |
冶金工业 | 7854篇 |
原子能技术 | 1902篇 |
自动化技术 | 26405篇 |
出版年
2024年 | 732篇 |
2023年 | 2619篇 |
2022年 | 5239篇 |
2021年 | 7236篇 |
2020年 | 6417篇 |
2019年 | 6917篇 |
2018年 | 7418篇 |
2017年 | 8394篇 |
2016年 | 8265篇 |
2015年 | 10233篇 |
2014年 | 11861篇 |
2013年 | 14694篇 |
2012年 | 13570篇 |
2011年 | 14217篇 |
2010年 | 12834篇 |
2009年 | 12230篇 |
2008年 | 11578篇 |
2007年 | 10868篇 |
2006年 | 10173篇 |
2005年 | 8354篇 |
2004年 | 6039篇 |
2003年 | 4997篇 |
2002年 | 4851篇 |
2001年 | 4088篇 |
2000年 | 3879篇 |
1999年 | 3247篇 |
1998年 | 2513篇 |
1997年 | 2136篇 |
1996年 | 1966篇 |
1995年 | 1579篇 |
1994年 | 1265篇 |
1993年 | 1010篇 |
1992年 | 817篇 |
1991年 | 590篇 |
1990年 | 495篇 |
1989年 | 378篇 |
1988年 | 328篇 |
1987年 | 228篇 |
1986年 | 189篇 |
1985年 | 170篇 |
1984年 | 115篇 |
1983年 | 89篇 |
1982年 | 82篇 |
1981年 | 70篇 |
1980年 | 62篇 |
1979年 | 43篇 |
1978年 | 33篇 |
1977年 | 37篇 |
1976年 | 62篇 |
1973年 | 23篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
81.
Shaofeng Wang Jianwei Xu Yuejin Tong Lin Wang Chaobin He 《Polymer International》2005,54(9):1268-1274
A novel cholesterol‐imprinted polymer (CMIP‐H) was prepared by a hybrid method of covalent imprinting and non‐covalent imprinting. This approach involves the copolymerization of a template‐containing monomer, cholesteryl 2‐hydroxyethyl methacrylate carbonate, and a cross‐linker, followed by hydrolysis to afford a flexible guest‐binding site accompanied with the easy and efficient removal of a ‘sacrificial spacer’. The effect of solvent on the binding capacity of CMIP‐H towards cholesterol was studied, indicating that a good binding capacity towards cholesterol could be achieved in a less‐polar solvent. The binding experiments of CMIP‐H towards a series of structural analogues of cholesterol, including cholesterol acetate, progesterone and stigmasterol, were carried out in hexane. The results showed that CMIP‐H almost did not bind cholesterol acetate at all because the hydrogen‐bonding site is blocked. It exhibited a similar binding towards both cholesterol and stigmasterol, but much higher binding towards progesterone. Copyright © 2005 Society of Chemical Industry 相似文献
82.
Antonio Sanchez‐Solis Andres Garcia‐Rejon Mirna Estrada Antonio Martinez‐Richa Guadalupe Sanchez Octavio Manero 《Polymer International》2005,54(12):1669-1672
The production and properties of blends of poly(ethylene terephthalate) (PET) and poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) with three modified clays are reported. Octadecylammonium chloride and maleic anhydride (MAH) are used to modify the surface of the montmorillonite–Na+ clay particles (clay–Na+) to produce clay–C18 and clay–MAH, respectively, before they are mixed with the PET/PEN system. The transesterification degree, hydrophobicity and the effect of the clays on the mechanical, rheological and thermal properties are analysed. The PET–PEN/clay–C18 system does not show any improvements in the mechanical properties, which is attributed to poor exfoliation. On the other hand, in the PET–PEN/clay–MAH blends, the modified clay restricts crystallization of the matrix, as evidenced in the low value of the crystallization enthalpy. The process‐induced PET–PEN transesterification reaction is affected by the clay particles. Clay–C18 induces the largest proportion of naphthalate–ethylene–terephthalate (NET) blocks, as opposed to clay–Na+ which renders the lowest proportion. The clay readily incorporates in the bulk polymer, but receding contact‐angle measurements reveal a small influence of the particles on the surface properties of the sample. The clay–Na+ blend shows a predominant solid‐like behaviour, as evidenced by the magnitude of the storage modulus in the low‐frequency range, which reflects a high entanglement density and a substantial degree of polymer–particle interactions. Copyright © 2005 Society of Chemical Industry 相似文献
83.
Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry 相似文献
84.
Low dielectric poly[methylsilsesquioxane‐ran‐trifluoropropylsilsesquioxane‐ran‐(2,4,6,8‐tetramethyl‐2,4,6,8‐tetraethylenecyclotetrasiloxane)silsesquioxane]s {P[M‐ran‐TFP‐ran‐(TCS)]SSQs} having various compositions were synthesized using trifluoropropyl trimethoxysilane, methyl trimethoxysilane and 2,4,6,8‐tetramethyl‐2,4,6,8‐tetra(trimethoxysilylethyl)cyclotetrasiloxane. The chemical composition of the polymers and the content of SiOH end‐groups were controlled by adjusting the reaction conditions, and they were characterized by 1H‐NMR. The thermally decomposable trifluoropropyl groups on the P[M‐ran‐TFP‐ran‐(TCS)]SSQ backbone and heptakis(2,3,6‐tri‐O‐methyl)‐β‐cyclodextrin (CD) were employed as pore generators. The dielectric constants of the porous CD/P[M‐ran‐TFP‐ran‐(TCS)]SSQ films were in the range 2.0–2.7 (at 100 kHz) depending on the concentration of the porogens, and showed no change over 4 days under aqueous conditions. The pore size of the films showed a bimodal distribution, with diameters of ca 0.5–1.0 nm for those originating from the trifluoropropyl groups and 1.7 nm from the CD. The elastic modulus and hardness of the 30 vol% CD‐blended film with a dielectric constant of 2.26 were 2.40 and 0.38 GPa, respectively, as determined by a nanoindenter. Copyright © 2005 Society of Chemical Industry 相似文献
85.
86.
在互联网服务中,即时通讯已成为了最流行的服务模式之一,人们对即时通讯的依赖程度也与日俱增。但是, 频频出现的病毒和黑客攻击使广大用户深受其害,即时通讯的安全问题也日益严峻。为了从根本上解决问题,本文对即时通讯软件的架构和协议进行了深入分析,目的是找出漏洞根源,给开发者和使用者提供防止漏洞的依据。 相似文献
87.
Dongming Peng Mi Lu 《Very Large Scale Integration (VLSI) Systems, IEEE Transactions on》2005,13(1):106-125
Although the notion of the parallelism in multidimensional applications has existed for a long time, it is so far unknown what the bound (if any) of inter-iteration parallelism in multirate multidimensional digital signal processing (DSP) algorithms is, and whether the maximum inter-iteration parallelism can be achieved for arbitrary multirate data flow algorithms. This paper explores the bound of inter-iteration parallelism within rate-balanced multirate multidimensional DSP algorithms and proves that this parallelism can always be achieved in hardware system given the availability of a large number of processors and the interconnections between them. 相似文献
88.
Ming-Da Tsai Chin-Shen Lin Chun-Hsien Lien Huei Wang 《Microwave Theory and Techniques》2005,53(2):496-505
Using the concept of loss compensation, novel broad-band monolithic microwave integrated circuits (MMICs), including an amplifier and an analog multiplier/mixer, with LC ladder matching networks in a commercial 0.35-mum SiGe BiCMOS technology are demonstrated for the first time. An HBT two-stage cascade single-stage distributed amplifier (2-CSSDA) using the modified loss-compensation technique is presented. It demonstrates a small-signal gain of better than 15 dB from dc to 28 GHz (gain-bandwidth product=157 GHz) with a low power consumption of 48 mW and a miniature chip size of 0.63 mm2 including testing pads. The gain-bandwidth product of the modified loss-compensated CSSDA is improved approximately 68% compared with the conventional attenuation-compensation technique. The wide-band amplifier achieves a high gain-bandwidth product with the lowest power consumption and smallest chip size. The broad-band mixer designed using a Gilbert cell with the modified loss-compensation technique achieves a measured power conversion gain of 19 dB with a 3-dB bandwidth from 0.1 to 23 GHz, which is the highest gain-bandwidth product of operation among previously reported MMIC mixers. As an analog multiplier, the measured sensitivity is better than 3000 V/W from 0.1 to 25 GHz, and the measured low-frequency noise floor and corner frequency can be estimated to be 20 nV/sqrt(Hz) and 1.2 kHz, respectively. The mixer performance represents state-of-the-art result of the MMIC broad-band mixers using commercial silicon-based technologies 相似文献
89.
3D characterization and analysis of particle shape using X-ray microtomography (XMT) 总被引:2,自引:0,他引:2
C.L. Lin 《Powder Technology》2005,154(1):61-69
90.
从上个世纪九十年代中期开始,无定型的造型在设计中占据了主导。十年之后,人们的审美和设计标准发生了变化。几何原理的广泛应用使得生活物品的设计出现了“硬边”(产品的棱线和轮廓)与“精确”之风的回潮。也许是人们渴望在这个不稳定的世界中寻求稳定的元素,也许是为了用简单直白的设计来掩饰以往设计中复杂计算的造型。总之,设计师对成熟稳重的几何形式表现得情有独钟。这种席卷而来的感觉体现了一种设计的成熟,而Viable工作室的设计就是其中的代表;不仅如此,他们的设计还反映出了每个人对生活的不同理解。[编者按] 相似文献