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排序方式: 共有8865条查询结果,搜索用时 15 毫秒
31.
Marta Valkov Pavel Letinský Lenka Matjov Kateina Klemencov Michal Ritz Christian Schimpf Mykhailo Motylenko David Rafaja Jakub Blík 《International journal of molecular sciences》2022,23(15)
Hematite (α-Fe2O3) catalysts prepared using the precipitation methods was found to be highly effective, and therefore, it was studied with methane (CH4), showing an excellent stable performance below 500 °C. This study investigates hematite nanoparticles (NPs) obtained by precipitation in water from the precursor of ferric chloride hexahydrate using precipitating agents NaOH or NH4OH at maintained pH 11 and calcined up to 500 °C for the catalytic oxidation of low concentrations of CH4 (5% by volume in air) at 500 °C to compare their structural state in a CH4 reducing environment. The conversion (%) of CH4 values decreasing with time was discussed according to the course of different transformation of goethite and hydrohematites NPs precursors to magnetite and the structural state of the calcined hydrohematites. The phase composition, the size and morphology of nanocrystallites, thermal transformation of precipitates and the specific surface area of the NPs were characterized in detail by X-ray powder diffraction, transmission electron microscopy, infrared spectroscopy, thermal TG/DTA analysis and nitrogen physisorption measurements. The results support the finding that after goethite dehydration, transformation to hydrohematite due to structurally incorporated water and vacancies is different from hydrohematite α-Fe2O3. The surface area SBET of Fe2O3_NH-70 precipitate composed of protohematite was larger by about 53 m2/g in comparison with Fe2O3_Na-70 precipitate composed of goethite. The oxidation of methane was positively influenced by the hydrohematites of the smaller particle size and the largest lattice volume containing structurally incorporated water and vacancies. 相似文献
32.
Marina Paiva Abuafy Regina Celia Galvao Frem Giulia Polinario Fernando Rogerio Pavan Heng Zhao Angelika Mielcarek Cedric Boissiere Christian Serre Leila Aparecida Chiavacci 《International journal of molecular sciences》2022,23(14)
Nanoparticles of metal–organic frameworks (MOF NPs) are crystalline hybrid micro- or mesoporous nanomaterials that show great promise in biomedicine due to their significant drug loading ability and controlled release. Herein, we develop porous capsules from aggregate of nanoparticles of the iron carboxylate MIL-100(Fe) through a low-temperature spray-drying route. This enables the concomitant one-pot encapsulation of high loading of an antitumor drug, methotrexate, within the pores of the MOF NPs, and the collagenase enzyme (COL), inside the inter-particular mesoporous cavities, upon the formation of the capsule, enhancing tumor treatment. This association provides better control of the release of the active moieties, MTX and collagenase, in simulated body fluid conditions in comparison with the bare MOF NPs. In addition, the loaded MIL-100 capsules present, against the A-375 cancer cell line, selective toxicity nine times higher than for the normal HaCaT cells, suggesting that MTX@COL@MIL-100 capsules may have potential application in the selective treatment of cancer cells. We highlight that an appropriate level of collagenase activity remained after encapsulation using the spray dryer equipment. Therefore, this work describes a novel application of MOF-based capsules as a dual drug delivery system for cancer treatment. 相似文献
33.
Generation of Inducible BCL11B Knockout in TAL1/LMO1 Transgenic Mouse T Cell Leukemia/Lymphoma Model
Grzegorz K. Przybylski Dorota Korsak Katarzyna Iykowska Karina Nowicka Tomasz Zalewski Magorzata Tubacka Maria Mosor Danuta Januszkiewicz-Lewandowska Magdalena Frydrychowicz Maciej Boruczkowski Grzegorz Dworacki Jens van den Brandt Piotr Grabarczyk Christian A. Schmidt Chengwu Zeng Yangqiu Li 《International journal of molecular sciences》2022,23(9)
34.
Jonas Baumann Christian Krnig Theresa Staufer Christopher Schlesiger Oliver Schmutzler Florian Grüner Wolfgang Malzer Birgit Kanngießer 《International journal of molecular sciences》2022,23(9)
Trace elements, functionalized nanoparticles and labeled entities can be localized with sub-mm spatial resolution by X-ray fluorescence imaging (XFI). Here, small animals are raster scanned with a pencil-like synchrotron beam of high energy and low divergence and the X-ray fluorescence is recorded with an energy-dispersive detector. The ability to first perform coarse scans to identify regions of interest, followed by a close-up with a sub-mm X-ray beam is desirable, because overall measurement time and X-ray dose absorbed by the (biological) specimen can thus be minimized. However, the size of X-ray beams at synchrotron beamlines is usually strongly dependent on the actual beamline setup and can only be adapted within specific pre-defined limits. Especially, large synchrotron beams are non-trivial to generate. Here, we present the concept of graphite-based, convex reflection optics for the one-dimensional enlargement of a 1 mm wide synchrotron beam by a factor of 5 to 10 within a 1 m distance. Four different optics are tested and characterized and their reflection properties compared to ray tracing simulations. The general shape and size of the measured reflection profiles agree with expectations. Enhancements with respect to homogeneity and efficiency can be expected with improved optics manufacturing. A mouse phantom is used for a proof-of-principle XFI experiment demonstrating the applicability of coarse and fine scans with the suggested optics design. 相似文献
35.
36.
A Simple Synthesis of Cyclohexanone-2-carboxamide and its Reactions By reaction of urea with cyclohexanone and subsequent acid hydrolysis cyclohexanone-2-carboxamide 2 is formed. 2 is C-alkylated by alkyl halides yielding compounds 6a—g . With amines, the enamines 10a and 10b , and with hydrazines the tetrahydroindazolones 8a and 8b are formed. 2 reacts with aqueous alkali to give pimelic acid. Cyclopentanone-2-carboxamide 3 and cycloheptanone-2-carboxamide 4 are formed in an analogous way. 相似文献
37.
Dipl.-Wirt.Inf. Christian Czarnecki Prof. Dr. Axel Winkelmann Prof. Dr. rer.nat./Griechenland habil. Myra Spiliopoulou 《WIRTSCHAFTSINFORMATIK》2013,55(2):83-97
The telecommunication market is experiencing substantial changes. New business models, innovative services, and technologies require reengineering, transformation, and process standardization. Enterprise Architecture Frameworks support the transformation by specifying methods, procedures, and reference models. With the Enhanced Telecom Operation Map (eTOM), the TM Forum offers an international de facto reference process framework, based on specific features and requirements of the telecommunication industry. However, this reference framework only offers a hierarchical collection of processes on different levels of abstraction; a control view in terms of a sequential ordering of tasks and hence a real process flow as well as an end-to-end view on the customer are missing. In this paper, we extend the eTOM reference model by reference process flows, in which we abstract and generalize the knowledge about processes in telecommunication companies. With reference process flows, we aim to assist companies in achieving a structured and transparent re-structuring and re-design of their processes. We demonstrate the applicability and usefulness of our reference process flows in two case studies, and evaluate them by means of criteria for reference model evaluation. Our reference process flows have been accepted as a standard by the TM Forum and published as part of eTOM version 9. We further elaborate on those components of our approach which can be applied outside the telecommunication industry. 相似文献
38.
Jean Berthier Sébastien Mermoz Kenneth Brakke Loic Sanchez Christian Frétigny Léa Di Cioccio 《Microfluidics and nanofluidics》2013,14(5):845-858
Capillary-driven self-alignment using droplets is currently extensively investigated for self-assembly and microassembly technology. In this technique, surface tension forces associated to capillary pinning create restoring forces and torques that tend to bring the moving part into the alignment. So far, most studies have addressed the problem of square chip alignment on a dedicated patch of a wafer, aiming to achieve 3D microelectronics. In this study, we investigate the shift-restoring forces for more complex moving parts such as regular—convex and non-convex—polygons and regular polygons with regular polygonal cavities. A closed-form approximate expression is derived for each of these polygonal geometries; this expression agrees with the numerical results obtained with the Surface Evolver software. For small shifts, it is found that the restoring force does not depend on the shift direction or on the polygonal shape. In order to tackle the problem of microsystem packaging, an extension of the theory is done for polygonal shapes pierced with connection vias (channels), and a closed form of the shift-restoring force is derived for these geometries and again checked against the numerical model. In this case, the restoring force depends on the shift direction. Finally, a non-dimensional number, the shift number, is proposed that indicates the isotropic or anisotropic behavior of the chip according to the shift direction. 相似文献
39.
40.
Stefan Linsinger Matthias Eul Christian Schwickert Rodolphe Decourt Bernard Chevalier Ute Ch. Rodewald Jean-Louis Bobet Rainer Pöttgen 《Intermetallics》2011,19(10):1579-1585
New ordered Laves phases RENi4Mg (RE = Sc, Sm, Tb–Lu) were synthesized from the elements in sealed tantalum ampoules in an induction furnace. Six of the structures were refined on the basis of X-ray single crystal data. The diffraction experiments gave hint for small homogeneity ranges RE1+xNi4Mg1?x. Magnetic susceptibility measurements show Curie–Weiss behavior for RE = Gd, Dy, Ho, Tm, Yb and the resulting effective magnetic moments suggest both stable trivalent states for all RE and a non-magnetic state for Ni. Gd1+xNi4Mg1?x (x ≈ 0.12) orders antiferromagnetically at a Néel temperature of TN = 4.6(5) K. Resistivity measurements reflect the metallic nature of these compounds. 相似文献