无机高分子絮凝剂聚硫酸铁合成条件的研究

实验研究了以工业硫酸亚铁及废硫酸为原料,分别采用NaClo_3、KClO_3、H_2O_2及(o_2+NaNO_2)为氧化剂成聚硫酸铁的条件。在以(O_2+NaNO_2)为氧化剂的合成过程中,发现添加微量助催化剂(型号为HG-1、HG-2和HG-3),对提高合成速度及反应过程的稳定性具有重大作用。     

Variations in Spectral Slope in Lake Taihu,a Large Subtropical Shallow Lake in China

Spectral slope (S), describing the exponential decrease of the absorption spectrum over a given wavelength range, is an important parameter in the study of of chromophoric dissolved organic matter (CDOM) dynamics, and also an essential input parameter in remote sensing models. Furthermore, S is often used as a proxy for CDOM composition, including the ratio of fulvic to humic acids and molecular weight. The relative broad range in S values reported in the literature can be explained by the different spectral ranges and fitting methods used. A single exponential model is used to fit the S values for 17 investigations involving 458 samples in Lake Taihu from January to October in 2004. The average S value was 15.18 ± 1.39 μm⁻¹ for the range of 280–500 nm, which fell within the range reported in the literature. The frequency distribution of S value basically obeyed a normal distribution. Significant differences in S values between summer and other seasons showed that phytoplankton degradation was one of the important sources of CDOM in summer, whereas CDOM mainly came from the river input in other seasons. Furthermore, the estimated S value decreased with increasing wavelength range used in regression. The maximum and minimum values derived from the regression were 17.89 ± 1.25 μm⁻¹ and 13.62 ± 2.11 μm⁻¹ for the wavelength ranges of 280–380 nm and 400–500 nm, respectively, a decrease of 23.9%. S values significantly decreased with the increase of CDOM absorption coefficients. CDOM absorption coefficients could be more appropriately estimated from exponential model introducing the variation of S with absorption coefficients, making them useful for a remote sensing bio-optical model of Lake Taihu. DOC-specific absorption coefficient a*(λ) and the parameter M describing molecular size of the humic molecules could also be used as a proxy for the sources and types of CDOM. A general relationship was found between S and a*(λ), and M values. S increased with the decrease of DOC-specific absorption coefficient and the increase of M corresponding to the decrease of molecular weight.     

Adaptive predictive control algorithm based on Laguerre Functional Model

Laguerre Functional Model has many advantages such as good approximation capability for the variances of system time‐delay, order and other structural parameters, low computational complexity, and the facility of online parameter identification, etc., so this model is suitable for complex industrial process control. A series of successful applications have been gained in linear and non‐linear predictive control fields by the control algorithm based on Laguerre Functional Model, however, former researchers have not systemically brought forward the theoretical analyses of the stability, robustness, and steady‐state performance of this algorithm, which are the keys to guarantee the feasibility of the control algorithm fundamentally. Aimed at this problem, we introduce the principles of the Incremental Mode Linear Laguerre Predictive Control (IMLLPC) algorithm, and then systemically propose the theoretical analyses and proofs of the stability and robustness of the algorithm, in addition, we also put forward the steady‐state performance analysis. At last, the control performances of this algorithm on two different physical industrial plants are presented in detail, and a number of experimental results validate the feasibility and superiority of IMLLPC algorithm. Copyright © 2005 John Wiley & Sons, Ltd.     

Method of selecting the regularisation parameter for microwaveimaging

The Tikhonov regularisation technique is widely used in the solution of inverse scattering problems. One of the difficulties in applying this technique is the proper selection of the associated regularisation parameter. Based on a stochastic model of the reconstruction process, a simple method is presented for selecting this parameter for an efficient implementation of various microwave imaging methods     

An investigation of bulk recycling planning for an electronics recycling facility receiving industrial returns versus residential returns

Since most end-of-life electronics equipment contain hazardous materials such as lead solder alloys or lead-impregnated glass, it is important to divert them from landfills. For end-of-life products that are not repairable and do not contain reusable parts, bulk recycling is an alternative to recover base materials. In this paper, we contrast production and recycling planning and distribution decisions, activities, and costs. We reveal that while a traditional production facility connects suppliers and customers, a recycling facility connects both "input" and "output" customers. As a result, decisions in short-term bulk recycling planning include what products to accept, what products to process and reprocess, and what products to carry in inventory. Many recyclers set prices to receive "input" based on experience. For various prices to receive "input", we use a new analytical model to investigate the sensitivity of the short-term bulk recycling planning decisions in products from two different sources: industrial returns versus residential returns. The results of the case study show that different decisions are recommended for the industrial returns versus the residential returns when the total quantity of the incoming products is equal.     

双能X射线骨密度仪测定技术研究

以Ｌｕｎａｒ公司ＤＰＸ－Ｌ型双能Ｘ射线骨密度仪为例，研究引起测量误差的主要因素并提出质控措施。用自检模块、腰椎体膜评定仪器的体外测量精度好于１％。对１０位志愿者重复２次测量，体内精度对腰椎，ＭＰＤ（平均百分差）为０．４６，ＣＶ（变异系数）为０．７５；对股骨颈，ＭＰＤ为１．２６、ＣＶ为０．４７；Ｗａｒｄ’ｓ三角区ＭＰＤ为２．０１、ＣＶ为１．１４；大转子ＭＰＤ为１．６６、ＣＶ为０．７２。扫描图像由２位     

Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

聚氨酯防水涂料及其市场发展概况

聚氨酯防水涂料是当今最有效的柔性防水材料之一，介绍了聚氨酯防水涂料的发展状况，并对其市场前景进行了展望。     

我国烧碱市场分析与展望

回顾了2005年我国烧碱的生产与市场消费情况,分析了2006年国内烧碱市场形势,对“十一五”期间我国烧碱市场总体趋势进行了展望。