步进梁式炉的运动研究

对国内引进的、用于粉末冶金的步进梁式炉的运动,以图解法和解析法进行了分析,并对运动参数进行了理论推导和计算。本研究结果,对解决步进粱式炉的运动故障以及进行新型设计提供了有效的理论分析和计算依据。     

Investigation of Infrared Photonic Crystal Slab with Defect Waveguides

This paper deals with the two dimensional (2-D) infrared photonic crystal slab with an air-bridge structure featuring defect waveguides in which the optical propagation properties were obtained by measurements of transmission spectra. 3-D finite-difference time-domain (FDTD) simulations have revealed the appearance of four defect propagation modes for the band structure and transmission spectra in the air-bridge slab. These defect modes were experimentally identified in the measured transmission spectra.     

非水解溶胶-凝胶法低温合成硅酸锆

以工业纯ZrCl4、 Si(OC2H5)4为前驱体,通过非水解溶胶-凝胶法合成了硅酸锆.采用DTA-TG和XRD等测试手段研究了凝胶热处理过程中的物相变化.结果表明:当前驱体溶胶中未引入矿化剂时,硅酸锆的合成温度高达1450℃;相比之下,溶胶中引入矿化剂LiF后在600℃下便开始出现了ZrSiO4衍射峰,在700℃合成的硅酸锆不仅合成率高,而且晶体发育好,实现了低温合成硅酸锆的目标.     

N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究

用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0～10.0,反应温度15～20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3～6.5。     

Parametric Wavelength Conversion From Conventional Near-Infrared to Visible Band

The feasibility of distant wavelength conversion in photonic crystal fiber was explored. The one-pump parametric architecture was used to demonstrate translation from the conventional (1550 nm) to visible (500 nm) band. Experimental results are reported, which demonstrate the conventional-to-visible conversion of single- and multiple-channel signals encoded in the nonreturn-to-zero format     

高输入功率因数的三相无源AC-DC变换器

对于采用三相不控整流桥作为前级的变换器，自然条件下其输入电流波形系数不高，使得输入功率因数委低，降低了电源的利用率。为此需要采用功率因数提高技术，其中无源PFC是一类重要的功率因数校正技术，在某些场合非常具有应用价值。本文介绍了几种三相无源AC-DC变换器的高功率因数方案，如采用LC滤波器、移相电抗器，谐振电抗器，移相变压器，相间变压器，相间电抗器等，在进行简单的工作原理描述后，给出了部分方案的MATLAB/SIMULINK仿真结果。     

单井注水吞吐在塔河油田的应用

在塔河油田开发生产过程中，个别油井在修井作业中出现先漏后喷的现象。在修井完成后，产量较前期有大幅增加。针对这类油井进行单井注水吞吐采油试验，研究发现钻遇定容封闭性油藏的油井适合单井注水吞吐开采。一方面利用油水重力分异，抬升油水界面，增加采出量；另一方面注水补充地层能量，恢复地层压力。该方法在塔河油田实际应用中，取得了较好的效果和较高的经济效益，也为提高定容封闭性油藏油井的采收率提供了一个较好的方法。     

Inside Front Cover: Three‐Dimensionally Ordered Gold Nanocrystal/Silica Superlattice Thin Films Synthesized via Sol–Gel Self‐Assembly (Adv. Funct. Mater. 7/2006)

The synthesis of three‐dimensionally ordered, transparent gold‐nanocrystal (NC)/silica superlattice thin films using the self‐assembly (by spin‐coating) of water‐soluble gold nanocrystal micelles and soluble silica is reported by Fan and co‐workers on p. 891. The robust, 3D NC/silica superlattice films are of interest for the development of collective optical and electronic phenomena, and, importantly, for the integration of NC arrays into device architectures. Nanocrystals and their ordered arrays hold many important applications in fields such as catalysis, surface‐enhanced Raman spectroscopy based sensors, memory storage, and electronic and optical nanodevices. Herein, a simple and general method to synthesize ordered, three‐dimensional, transparent gold nanocrystal/silica superlattice thin films by self‐assembly of gold nanocrystal micelles with silica or organosilsesquioxane by spin‐coating is reported. The self‐assembly process is conducted under acidic sol–gel conditions (ca. pH 2), ensuring spin‐solution homogeneity and stability and facilitating the formation of ordered and transparent gold nanocrystal/silica films. The monodisperse nanocrystals are organized within inorganic host matrices as a face‐centered cubic mesostructure, and characterized by transmission electron spectroscopy and X‐ray diffraction.     

Effects of Process Conditions on Desalting and Demetalization of Crude Oil

The efficiency of desalting for six crude oils was studied with a SY-1 dynamic simulation experimental installation. The demulsifier DC2 was examined for 1#, 2#, and 4# crude oil and DC4 was used for 3#, 5#, and 6# crude oil. The effects of temperature, electric field gradient, dosage of demulsifier, and washing water on the desalting efficiency of six crude oils were investigated. The results showed that at the optimization process condition after desalting, the desalting efficiency and the salt content of 1# crude oil reached 89.17% and 1.92 mg/L; that of 2# crude oil reached 85.08% and 1.04 mg/L; that of 3# crude oil reached 91.06% and 1.35 mg/L; that of 4# crude oil reached 81.67% and 1.51 mg/L; that of 5# crude oil reached 81.03% and 2.32 mg/L; and that of 6# crude oil reached 86.64% and 2.67 mg/L. Different crude oils have different metal contents. Three assistants, ammonium nitrate (TJ1), nitric acid (TJ3), and polyamine carboxylate (TJ4), were used to improve the efficiencies of desalting and demetalization of six crude oils. TJ4 was more efficient in removing calcium and iron for 1# and 2# crude oil. TJ1 was more efficient in desalting and demetalizing 5# crude oil. The efficiencies for removal of calcium, iron, nickel, and vanadium respectively reached 99.89%, 98.33%, 20.58%, and 43.02%. TJ3 has better efficiency desalting and demetalizing for 6# crude oil. With the concentration of TJ3 increasing from 0 to 80 mg/L, the desalting efficiency increases from 31.22% to 73.54%, and the iron removal efficiency increases from 56.0% to 74.05%.