Dielectric and morphological investigations of phase separation and cure in rubber-modified epoxy resins: Comparison between teta- and DDM-based systems

Real-time and equilibrium dielectric measurements, covering the frequency range 10^?1–10⁵ Hz, are reported on a series of rubber-modified epoxy resins, based on reaction of the diglycidyl ether of bisphenol A (DGEBA) with either triethylenetetramine (TETA) or diaminodiphenylmethylene (DDM). The rubber modifier used was a carboxyl-terminated butadiene acrylonitrile (CTBN) reactive oligomer and the phase-separated structure, the results of which was examined using both dielectric and electron microscopic techniques. The mixture was initially homogeneous, but after a short period of time, it underwent phase separation and this process was marked by the appearance of a dielectric peak associated with ion-charge migration within the occluded rubbery phase. Analysis of the peak provided information on the morphology of the system and these data were compared with information obtained from scanning electron microscopy. A phase-separated morphology was observed consisting of spherical rubber particles dispersed in an epoxy matrix. For high concentrations of rubber ≥ 10 wt %, precipitation of epoxy domains within the rubbery phase was observed. Detailed dielectric studies of the peak associated with phase separation revealed that in the case of the TETA system the peak continued to shift after vitrification, whereas in the case of DDM, it was invariant with time. The point at which the peak appears was used to determine the time at which phase separation occurred. Differences observed in the lower temperature dielectric spectra were associated with variations in the form of the phase structure and possibly reflect different degrees of densification of the matrix. Good agreement was observed between the predictions of the Maxwell—Wagner—Sillers (MWS) theory and experimental observation for these systems. © 1993 John Wiley & Sons, Inc.     

Effect of the complexation with copper(II) on the hydrodynamic behaviour of some polyelectrolytes

Summary The complex formation between copper and a number of polyelectrolytes derived from amino-acids was studied by viscosimetry. It was concluded that the complexes involving two side chains of the polymer form between two neighbouring side chains of the same polymeric chain. The effect of copper on the viscosity of the polymer solutions was thus accounted for mainly by changes in the net charge of the polymer and changes in the electrostatic interactions.     

Synthesis of Mixed Refrigerant Cascade Cycles

This paper considers the synthesis of refrigeration systems with refrigerant mixtures as working fluids. The employed refrigeration topology encompasses features from industrial liquefaction of natural gas (LNG) systems. This configuration consists of a combination of horizontal and vertical cascades generalizing the vertical cascade of pure refrigerant systems. The key features of mixtures exploited here are their ability to evaporate/condense over a temperature range and their potential to generate streams with different compositions through partial condensation. The synthesis problem is formulated and solved as a nonlinear program. The proposed methodology is illustrated using an example of cooling a methane-rich stream.     

Price dynamics in European petroleum markets

This paper analyses horizontal and vertical price dynamics in the EU petroleum markets. The results indicate that the cross-country price differentials have significant impact on the local price adjustments. We investigate the cross-national price spill-overs and find that the extent of the welfare transfer due to asymmetric price transmission, when analysed in a cross-country setting, is less pronounced than claimed in previous contributions in this area. We also find empirical evidence, although indirect, for the politically charged concept of “fuel tourism”, using a pan-European cross-product time series dataset.     

Shape Connectivity: Multiscale Analysis and Application to Generalized Granulometries

This paper develops a multiscale connectivity theory for shapes based on the axiomatic definition of new generalized connectivity measures, which are obtained using morphology-based nonlinear scale-space operators. The concept of connectivity-tree for hierarchical image representation is introduced and used to define generalized connected morphological operators. This theoretical framework is then applied to establish a class of generalized granulometries, implemented at a particular problem concerning soilsection image analysis and evaluation of morphological properties such as size distributions. Comparative results demonstrate the power and versatility of the proposed methodology with respect to the application of typical connected operators (such as reconstruction openings). This multiscale connectivity analysis framework aims at a more reliable evaluation of shape/size information within complex images, with particular applications to generalized granulometries, connected operators, and segmentation.     

Õ(Congestion + Dilation) Hot-Potato Routing on Leveled Networks

We study packet routing problems, in which we are given a set of N packets which will be sent on preselected paths with congestion C and dilation D. For store-and-forward routing, in which nodes have buffers for packets in transit, there are routing algorithms with a performance that matches the lower bound Ω(C+D). Motivated from optical networks, we study hot-potato routing in which the nodes are bufferless. Due to the lack of buffers, in hot-potato routing the packets may be delayed more than in store-and-forward routing. An interesting question is how much is the performance of routing algorithms affected by the absence of buffers. Here, we answer this question for the class of leveled networks, in which the nodes are partitioned into L+1 distinct levels. We present a randomized hot-potato routing algorithm for leveled networks, which routes the packets in O((C + L) ln⁹ (LN)) time with high probability. For routing problems with dilation Ω(L), and where N is a polynonial in L, this bound is within polylogarithmic factors of the lower bound Ω(C+L). Our algorithm demonstrates that for such routing problems the benefit from using buffers is no more than polylogarithmic; thus, hot-potato routing is an efficient way to route packets in leveled networks. In hot-potato routing, due to the lack of buffers, the packets may not be able to remain on their preselected paths during the course of routing (while in store-and-forward routing the packets remain on their preselected paths). However, in our algorithm the actual path that each packet follows contains its original preselected path; thus the lower bound Ω(C+L) is also a lower bound for the new paths. Our algorithm is distributed, that is, routing decisions are taken locally at each node while packets are routed in the network. To our knowledge, this is the first hot-potato algorithm designed and analyzed, in terms of congestion and dilation, for leveled networks.