Technical new feature

A continuous process for the commercial production of isopropenyl stearate (IPS) from triple pressed stearic acid and a stabilized form of propyne has been developed. Cost estimates, including capital costs, operating costs, and profitability, for commercial scale plant production which show the process to be economically feasible are presented. This potentially profitable process offers the advantages of reliable raw material sources, minimal external thermal requirements, and usable process waste streams. For a plant producing 5 million pounds of IPS per year, the selling price range is 80 to 107 cents/lb IPS, corresponding to a raw material cost range of 27 to 54 cents/lb of IPS. For a 20 million pound per year plant, the selling price range is 58 to 85 cents/lb IPS. The selling prices include a 20% annual return on fixed capital investment. Fixed capital requirement ranges from 2.7 to 10.9 million dollars (3rd quarter, 1975) for plants ranging in size from 5 to 50 million pounds of IPS per year, respectively.     

Quantitative fatty acid analysis of vegetable oils by gas-liquid chromatography

Summary The fatty acid composition of a number of vegetable oils and of two synthetic mixtures of methyl esters are compared by gas-liquid chromatography and by standard methods. The calculated iodine values from G.L.P.C. results are in good agreement with measured iodine values and are indicative of the reliability of the G.L.P.C. values. Standard methods gave lower values for linoleic acid and higher values for linolenic acid than did G.L.P.C. This deviation was particularly evident in oils with a high proportion of linolenic acid,e.g., linseed oil. The results of G.L.P.C. are considered to be accurate to within one unit percentage. Thermal stability of the polyester polymers can be improved by using 1,4-butanediol or ethylene glycol as the polyols instead of diethylene glycol. Issued as N.R.C. No. 5373. Presented at 32nd annual fall meeting, American Oil Chemists' Society, October 20–22, 1958, Chicago, Ill. National Research Council of Canada Postdoctorate Fellow, 1957     

Influence of genetics,environment and admixtures on low erucic acid rapeseed in Canada

Single plant isolates in theBrassica napus andBrassica campestris species of rapeseed yielded glyceride oil containing small amounts of erucic acid. Agronomically suitable varieties were grown commercially in 1971 as the first phase in a changeover of Canadian rapeseed production from varieties with erucic contents of 20–45% to low erucic acid varieties. A program to monitor the erucic content by gas chromatographic analysis in the stages of production, handling and transportation from seed to export shipment was undertaken to evaluate the effects of genetics, environment and admixture. The individual increase in erucic content ranged from 0.5 to 1.0, resulting in total increases of 1–2%. NRCC No. 13471. One of six papers presented in the symposium “Rapeseed Marketing and Breeding,” AOCS Meeting, Ottawa, September 1972.     

Preparation of long-chain fatty acid chlorides

Summary A rapid method has been found for preparing the long-chain fatty acid chlorides, which eliminates purification by distillation. It gave a quantitative yield of product containing less than 1.5% free acid. The method involves treating the free acid with phosphorus pentachloride or trichloride in an inert organic solvent and removing the excess chlorinating agent by washing the solvent phase with water. Phosphorus pentachloride and Skellysolve “F” were preferred for laboratory preparations. For commercial purposes however either chlorinating agent could be used in a variety of inert organic solvents. Infrared analysis was found to give a rapid measure of the free acid content of the prepared acid chlorides. Presented at the fall meeting, American Oil Chemists' Society, Philadelphia, Pa., Oct. 10–12, 1955. Issued as N. R. C. No. 4240.     

Beyond Market Baskets: Generalizing Association Rules to Dependence Rules

One of the more well-studied problems in data mining is the search for association rules in market basket data. Association rules are intended to identify patterns of the type: A customer purchasing item A often also purchases item B. Motivated partly by the goal of generalizing beyond market basket data and partly by the goal of ironing out some problems in the definition of association rules, we develop the notion of dependence rules that identify statistical dependence in both the presence and absence of items in itemsets. We propose measuring significance of dependence via the chi-squared test for independence from classical statistics. This leads to a measure that is upward-closed in the itemset lattice, enabling us to reduce the mining problem to the search for a border between dependent and independent itemsets in the lattice. We develop pruning strategies based on the closure property and thereby devise an efficient algorithm for discovering dependence rules. We demonstrate our algorithm's effectiveness by testing it on census data, text data (wherein we seek term dependence), and synthetic data.     

Time and Space Optimal Data Parallel Volume Rendering Using Permutation Warping

In this paper we present a data parallel volume rendering algorithm that possesses numerous advantages over prior published solutions. Volume rendering is a three-dimensional graphics rendering algorithm that computes views of sampled medical and simulation data, but has been much slower than other graphics algorithms because of the data set sizes and the computational complexity. Our algorithm usespermutation warpingto achieve linear speedup (run time is O(S/P) forPprocessors whenP\= O(S/logS) forS\=n³samples), linear storage (O(S)) for large data sets, arbitrary view directions, and high-quality filters. We derived a new processor permutation assignment of five passes (our prior known solution was eight passes), and a new parallel compositing technique that is essential for scaling linearly on machines that have more processors than view rays to process (P>n²). We show a speedup of 15.7 for a 16k processor over a 1k processor MasPar MP-1 (16 is linear) and two frames/second with a 128³volume and trilinear view reconstruction. In addition, we demonstrate volume sizes of 256³, constant run time over angles 5 to 75°, filter quality comparisons, and communication congestion of just 19 to 29\%.     

Wear of filled and unfilled dental restorative resins

The influence of double-pass sliding on the surface failure of filled and unfilled dental restorative resins was evaluated. Damage was more severe for double-pass than for single-pass sliding. Wear of restorative resins and composites was influenced by the resistance to penetration and by the mode of deformation during sliding.     

Development of a Mortality Prediction Model in Hospitalised SARS-CoV-2 Positive Patients Based on Routine Kidney Biomarkers

Acute kidney injury (AKI) is a prevalent complication in severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) positive inpatients, which is linked to an increased mortality rate compared to patients without AKI. Here we analysed the difference in kidney blood biomarkers in SARS-CoV-2 positive patients with non-fatal or fatal outcome, in order to develop a mortality prediction model for hospitalised SARS-CoV-2 positive patients. A retrospective cohort study including data from suspected SARS-CoV-2 positive patients admitted to a large National Health Service (NHS) Foundation Trust hospital in the Yorkshire and Humber regions, United Kingdom, between 1 March 2020 and 30 August 2020. Hospitalised adult patients (aged ≥ 18 years) with at least one confirmed positive RT-PCR test for SARS-CoV-2 and blood tests of kidney biomarkers within 36 h of the RT-PCR test were included. The main outcome measure was 90-day in-hospital mortality in SARS-CoV-2 infected patients. The logistic regression and random forest (RF) models incorporated six predictors including three routine kidney function tests (sodium, urea; creatinine only in RF), along with age, sex, and ethnicity. The mortality prediction performance of the logistic regression model achieved an area under receiver operating characteristic (AUROC) curve of 0.772 in the test dataset (95% CI: 0.694–0.823), while the RF model attained the AUROC of 0.820 in the same test cohort (95% CI: 0.740–0.870). The resulting validated prediction model is the first to focus on kidney biomarkers specifically on in-hospital mortality over a 90-day period.     

Simulation of hole-mobility in doped relaxed and strained Ge

As silicon CMOS begins to reach the limits of its performance, alternative channel materials are being considered. Thus there is renewed interest in employing Germanium for p-MOSFETs, due to the significant improvement in hole mobility as compared to silicon for undoped materials. Of considerable interest from a device point of view is the transport in doped layers. We investigate hole transport at high carrier-densities in doped Germanium layers using a bulk 6-band k·p Monte Carlo simulator, and show that both dynamic and multi-ion screening play a significant role in describing the resulting transport.     

A practical, evidence-based approach for means-restriction counseling with suicidal patients.

Assessing a patient's access to potentially lethal means for suicide and taking steps to restrict access to means are common expectations for reasonable outpatient management of suicidal patients. Although scientific evidence supports means restriction as a suicide prevention strategy, means restriction continues to be infrequently utilized by clinicians, in large part because of the general lack of available training and guidance. The present article reviews the conceptual basis and empirical evidence for means restriction, discusses common barriers to means-restriction counseling, and provides practical procedures and tools (e.g., the means receipt, the crisis support plan) for accomplishing means-restriction counseling in routine clinical practice. (PsycINFO Database Record (c) 2011 APA, all rights reserved)