Effectiveness of nitrogen incorporation to enhance the photoelectrochemical activity of nanostructured TiO2:NH3 versus H2-N2 annealing

Highly ordered TiO(2) nanohole layers were synthesized by anodic oxidation of titanium foils using ethylene glycol and ammonium fluoride as the electrolyte. The effectiveness of different methods, namely annealing at 500?°C in NH(3) and in H(2) diluted in N(2), to incorporate nitrogen into TiO(2) and thus extend its photoelectrochemical (PEC) activity to the visible range was studied. The intra-gap levels introduced by both processes were identified by means of XPS and PL measurements. Water splitting experiments demonstrated that annealing in H(2) improved the photocatalytic activity of pure TiO(2), while annealing in ammonia led to a decrease in the PEC performance.     

Angiotensin-I converting enzyme inhibitory and antioxidant activity of bioactive peptides produced by enzymatic hydrolysis of skin from grass carp (Ctenopharyngodon idella)

Grass carp skin pieces were homogenized in water and hydrolyzed by Alcalase®, collagenase, proteinase K, and/or trypsin at their optimum conditions. Samples were taken at various degrees of hydrolysis and were evaluated for antioxidant, antimicrobial, and angiotensin-converting enzyme inhibitory activities. Alcalase and collagenase completely hydrolyzed the skin with different rates, and released peptides with antioxidant and angiotensin-converting enzyme-inhibitory activity. These activities increased linearly with increasing degrees of hydrolysis. Subsequent incubation of the collagenase hydrolysates with trypsin slightly increased the antioxidant activity. Proteinase K, although only partially hydrolyzing the skin, also catalyzed the release of peptides with antioxidant and angiotensin-converting enzyme-inhibitory activities. These results show that skin by-products from grass carp can be a source of bioactive peptides produced by a one-step reaction. Such hydrolysates may be applied in food products to prolong shelf life and provide beneficial effects on blood pressure.     

The structure of shock and interphase layers for a heat conducting Maxwellian rate-type approach to solid–solid phase transitions

One continues the qualitative analysis started in Part I (F?ciu and Molinari in Acta Mech) concerning the thermomechanical characteristics of a steady, structured moving phase boundary in a shape memory alloy (SMA) by a quantitative investigation. The internal structure of these interphase layers is governed by a Maxwellian rate-type constitutive equation coupled or not with the Fourier heat conduction law. We consider as equilibrium stress–strain–temperature response function for the Maxwellian model an explicit piecewise linear thermoelastic relation for an SMA bar which can exist in the austenite phase A and in two variants of martensite M ^±. Its thermal properties are built in agreement with experimental results on NiTi. This equilibrium relation has the atypical property that not only the derivative of the stress response function with respect to the strain changes its sign, but also the derivative with respect to the temperature. Considerable temperature variation is generated by impact-induced phase transformations due to the large amount of latent heat released (absorbed) inside the transition layer. One gets strong heating (cooling) across a compressive A→ M ^? (expansive M ^? → A) propagating interphase layer. A significant lower (larger) temperature than that at the front and Hugoniot back state is obtained inside an impact-induced M ⁺→ M ^? (M ^?→ M ⁺) interphase layer. The experimental finding of this phenomenon of temperature undershoot (overshoot) could be a valuable indication for the existence of an interphase layer.     

Toward multimodal notation for mathematics: Why and how

Notation is a tool of thought, recording and communicating concepts and activities related to a domain of knowledge. In the history of mathematical notation, written notation is usually considered. However, to be an effective thinking tool, notation must be properly perceived. Blind and partially sighted people run into difficulty in making, exploring and understanding mathematical concepts conceived for being represented in multi-dimensional space. In this paper, we capitalize on the multifaceted nature of digital symbols to define multimodal digital notation for graph structures that allows blind and partially sighted people to represent graph structures, reason about them and communicate their reasoning with sighted people as well as each other. As support tool for notation proposed we have designed a multimodal interactive system, in which haptic signals play a crucial role. An evolutionary prototype of the system has been developed and evaluated according to the star life cycle model.     

In situ monitoring of pH level with fiber optic evanescent field spectroscopy

Fiber optic evanescent field spectroscopy for in situ monitoring of pH levels is presented. Cladding of plastic clad silica fiber is replaced with polymethyl methacrylate doped with pH sensitive chromoionophores. The chromoionophores include methyl red, thymol blue, and thymolphtalein for pH in acidic, neutral and basic environments, respectively. The evanescent wave is used to selectively excite the indicator molecules within the fiber cladding for sampling aqueous media surrounding the fiber.     

Synchronous atomic broadcast for redundant broadcast channels

We propose a synchronous atomic broadcast protocol for distributed real-time systems based on redundant broadcast channels. The protocol can tolerate a finite number f of concurrent processor crash failures, channel adapter performance failures and channel omission failures. Its message cost is optimal: when no failures occur only f+1 messages are sent per broadcast. The cost implications of providing tolerance to other failure classes are also investigated.