The electrochemical behaviour of the Nickel(II) ion at the dropping mercury electrode in the presence of some complexing agents—part I

The polarographic reduction wave for the Ni²⁺ ion is almost invariably shifted to more positive potentials on addition of very low concentrations of complexing agent. After reaching a limiting positive potential, shifts occur in the more negative direction as the ligand concentration is further increased. In some cases the positively shifted waves are catalytically controlled while in others the waves are controlled solely by diffusion. Analysis of the variation of half-wave potential with ligand concentration has been used to verify the mechanism of the reduction processes of the Nickel(II) ion in the presence of ammonia, pyridine and pyrazole.     

A GaAs MESFET IC for optical multiprocessor networks

A GaAs, enhanced/depletion mode, self-aligned, refractory-gate, MESFET chip process and circuit family have been developed for the integration of fiber-optic data link functions (e.g. photodetection, amplification, clock recovery, and deserialization) on a single chip. These authors describe the process and present results on integrating a complete optical receiver, including the photodiode and clock recovery circuits, on one chip. The chip functions use over 2000 devices, and perform at 1-GB/s, while dissipating less than 300 mW of heat. This chip is the most complex high-performance optoelectronic integrated circuit reported to date     

Effects of monensin and stage of lactation on variation of blood metabolites within twenty-four hours in dairy cows

Effects of prepartum administration of a monensin controlled release capsule (CRC) and stage of lactation on variation of blood metabolites within 24 h were determined in 16 dairy cows. Cows were fed a total mixed ration ad libitum twice daily at 0700 and 1300 h. At calving, cows were switched from a close-up dry cow diet to a lactating cow diet. Cows were blood sampled every 3 h for 24 h at 3 stages of lactation, including 1 wk before calving (wk −1), 1 wk after calving (wk 1), and 6 wk after calving (wk 6). Serum concentrations of glucose, β-hydroxybutyrate (BHBA), nonesterified fatty acids (NEFA), and urea exhibited significant variation within 24 h. Glucose and NEFA were, respectively, 0.09 and 0.08 mM lower between 1030 and 2230 h than between 2230 and 1030 h. β-Hydroxybutyrate and urea were, respectively, 95.1 and 0.49 mM higher between 1030 and 2230 h than between 2230 and 1030 h. Monensin did not significantly affect glucose, NEFA, and urea in this study. Monensin reduced BHBA at wk 1, but not at wk −1 or wk 6. Glucose was lower and BHBA and NEFA were higher at wk 1 compared with wk −1 and wk 6. Urea was higher at wk 6 compared with wk −1. The variation within 24 h of glucose, BHBA, and NEFA were not affected by monensin and stage of lactation. Diurnal variation of urea was affected by stage of lactation, but not by monensin.     

The effect of violent and non-violent computer games on cognitive performance

Two studies were conducted in order to determine the impact computer games had on the cognitive performance. Study 1 evaluated a measure of cognition, which incorporates aspects of short-term working memory, visual attention, mathematical decision making, and auditory perception. Study 2 measured the cognitive performance between those who did not play video games versus those who played either a violent or non-violent video game. Results from Study 1 indicate participants needed approximately four trials to reach asymptotic performance on the cognitive measure. Results of Study 2 showed that participants who did not play any video game did not have a change in their cognitive performance, while those who played either a violent or non-violent video game had an increase in their cognitive performance.     

Access to water in a Nairobi slum: women's work and institutional learning

This paper describes the ways that households, and particularly women, experience water scarcity in a large informal settlement in Nairobi, Kenya, through heavy expenditures of time and money, considerable investments in water storage and routinized sequences of deferred household tasks. It then delineates three phases of adaptive water and social engineering undertaken in several informal settlements by the Nairobi Water Company in an ongoing attempt to construct effective municipal institutions and infrastructure to improve residential access to water and loosen the grip that informal vendors may have on the market for water in these localities.     

Upper critical and irreversibility fields in selectively doped YBa2Cu3O7

The electrical resistivity of (Y_1–xPr_x)Ba₂Cu₃O_7–gd and YBa₂(Cu_1–xZn_x)₃O_7– thin films and (Y_1–x. Tb_x)Ba₂Cu₃O_7– thin films and single crystals has been measured as a function of 0xx_crit, 2KT300K and OTH20T. The samples were oriented withc-axis parallel to applied fields. Upper critical field H_c2 and irreversibility field H_irr values have been determined from these measurements. Increased Tb doping appears to shift H_irr to higher temperatures. This coupled with observed twin peaks in magnetization measurements reflects an enhancement of flux pinning. Unlike Tb which does not appear to alterT _c , Pr and Zn doping of this system tends to depress bothT _c and the slope of the mean field normal phase-mixed phase boundary line (dH _c2/dT).     

Activity and excitability to electrical current of cortical auditory receptive neurons of awake cats as affected by stimulus association

1. Unit activity and excitability were studied at the midlateral and suprasylvian cortex of naive, blink-conditioned and "randomization" cats. The latter received the same CS and US as did the conditioned animals, but in random temporal order and with random intertrial intervals with mean comparable to that used for conditioning. The randomization group failed to develop a blink CR. 2. With conditioning, spontaneous and evoked unit discharges were increased above levels found in naive animals. Correspondingly, levels of extracellularly injected current required to elicit a spike discharge were lower in conditioned than in naive animals. In addition, in the conditioned animals, the degree of enhancement of evoked activity and excitability was found to be greatest in the units that responded to the CS, as opposed to units that responded to another auditory stimulus of equal intensity but of no special behavioral significance vis-a-vis the conditioned reflex. 3...     

Monitoring root-zone soil moisture through the assimilation of a thermal remote sensing-based soil moisture proxy into a water balance model

Two types of Soil Vegetation Atmosphere Transfer (SVAT) modeling approaches can be applied to monitor root-zone soil moisture in agricultural landscapes. Water and Energy Balance (WEB) SVAT modeling is based on forcing a prognostic root-zone water balance model with observed rainfall and predicted evapotranspiration. In contrast, thermal Remote Sensing (RS) observations of surface radiometric temperature (T_R) are integrated into purely diagnostic RS-SVAT models to predict the onset of vegetation water stress. While RS-SVAT models do not explicitly monitor soil moisture, they can be used in the calculation of thermal-based proxy variables for the availability of soil water in the root zone. Using four growing seasons (2001 to 2004) of profile soil moisture, micro-meteorology, and surface radiometric temperature measurements at the United States Department of Agriculture (USDA) Optimizing Production Inputs for Economic and Environmental Enhancements (OPE³) study site in Beltsville, MD, prospects for improving WEB-SVAT root-zone soil water predictions via the assimilation of diagnostic RS-SVAT soil moisture proxy information are examined. Results illustrate the potential advantages of such an assimilation approach relative to the competing approach of directly assimilating T_R measurements. Since T_R measurements used in the analysis are tower-based (and not obtained from a remote platform), a sensitivity analysis demonstrates the potential impact of remote sensing limitations on the value of the RS-SVAT proxy. Overall, results support a potential role for RS-SVAT modeling strategies in improving WEB-SVAT model characterization of root-zone soil moisture.     

A method for retrieving high-resolution surface soil moisture from hydros L-band radiometer and Radar observations

NASA's Earth System Science Pathfinder Hydrospheric States (Hydros) mission will provide the first global scale space-borne observations of Earth's soil moisture using both L-band microwave radiometer and radar technologies. In preparation for the Hydros mission, an observation system simulation experiment (OSSE) has been conducted. As a part of this OSSE, the potential for retrieving useful surface soil moisture at spatial resolutions of 9 and 3 km was explored. The approach involved optimally merging relatively accurate 36-km radiometer brightness temperature and relatively noisy 3-km radar backscatter cross section observations using a Bayesian method. Based on the Hydros OSSE data sets with low and high noises added to the simulated observations or model parameters, the Bayesian method performed better than direct inversion of either the brightness temperature or radar backscatter observations alone. The root-mean-square errors of 9-km soil moisture retrievals from the Bayesian merging method were reduced by 0.5 %vol/vol and 1.4 %vol/vol from the errors of direct radar inversions for the entire OSSE domain of all 34 consecutive days for the low and high noise data sets, respectively. Improvement in soil moisture estimates using the Bayesian merging method over the direct inversions of radar or radiometer data were even more significant for soil moisture retrieval at 3-km resolution. However, to address the representativeness of these results at the global and multiyear scales, further performance comparison studies are needed, particularly with actual field data.     

Onset of binge eating and dieting in overweight women: implications for etiology, associated features and treatment

This study investigated differences between overweight binge eating women who reported the onset of binge eating prior to or following the onset of dieting (binged first [BF], or dieted first [DF]). Of overweight binge eating subjects enrolled in a treatment study, 38.7% indicated binge eating first, and 48.1% dieting first. The mean age of onset of binge eating differed significantly between the two groups (11.8 years vs. 25.7 years). More of the BF group (82.5%) satisfied proposed binge eating disorder (BED) criteria than did the DF group (52.0%), although short of significantly. The results suggest that: (a) the leading hypothesis concerning dieting as a cause of binge eating does not apply to a substantial number of individuals who binge eat; (b) there may be an early pattern and a late pattern in the development of binge eating among overweight individuals; and (c) the early or binge first pattern may be more likely to result in BED.