Sugarcane bagasse cellulose/HDPE composites obtained by extrusion

Natural fibers used in this study were both pre-treated and modified residues from sugarcane bagasse. Polymer of high density polyethylene (HDPE) was employed as matrix in to composites, which were produced by mixing high density polyethylene with cellulose (10%) and Cell/ZrO₂·nH₂O (10%), using an extruder and hydraulic press. Tensile tests showed that the Cell/ZrO₂·nH₂O (10%)/HDPE composites present better tensile strength than cellulose (10%)/HDPE composites. Cellulose agglomerations were responsible for poor adhesion between fiber and matrix in cellulose (10%)/HDPE composites. HDPE/natural fibers composites showed also lower tensile strength in comparison to the polymer. The increase in Young’s modulus is associated to fibers reinforcement. SEM analysis showed that the cellulose fibers insertion in the matrix caused an increase of defects, which were reduced when modified cellulose fibers were used.     

Survival analysis methodology to predict the shelf-life of probiotic flavored yogurt

The feasibility of survival analysis methodology was used to determine the shelf-life of probiotic strawberry flavored yogurt supplemented with Bifidobacteirum animalis DN 173010 W was investigated. The quality parameters of probiotic yogurts were related to storage conditions which they are submitted. The consumers were shown sensitive to changes towards sensory characteristics introduced into the products. Using the survival analysis and considering 25% and 50% probability of consumer rejection, the shelf-life of the probiotic yogurt was estimated at 38 and 53 days, respectively. The findings of this research highlighted the feasibility this technique to determine the shelf-life of foods, in particular, functional foods, as probiotic yogurts.     

Lipid Damage Inhibition in Hake by Active Packaging Film with Natural Antioxidants

The capacity of the natural antioxidant to retard oxidation of polyunsaturated fatty acids in hake (Merluccius merluccius) muscle was investigated. Hake fillets were packaged in low‐density polyethylene with the natural antioxidant (sample C1 = 7 mg/dm² film and sample C2 = 24 mg/dm² film) or without the antioxidant (control sample) and frozen for 12 months at ?20°C. The results confirm the efficacy of an active packaging with a natural antioxidant derived from barley husks to slow the progress of lipid hydrolysis and increase oxidative stability in hake muscle. Determination of peroxide value, conjugated dienes, free fatty acids, thiobarbituric acid reactive substances (TBARS) and anisidine value (AV) proved suitable for studying lipid hydrolysis and primary and secondary lipid oxidation over time. After 6 months of frozen storage, the TBARS levels were lower in hake packed with low‐density polyethylene with the natural antioxidant (C1 and C2) than in the control sample; at month 12, the TBARS values of C1 and C2 were lower (16 and 21%, respectively) than the control samples. AVs observed in samples C1 and C2 at month 9 were lower than those observed in the control sample at month 12. Copyright © 2011 John Wiley & Sons, Ltd.     

Caffeine selectivity of divinylbenzene crosslinked polymers in aqueous media

The selective binding of caffeine to polymers is of interest in developing caffeine-specific sensors. The influence of the nature and quantity of crosslinking agents and functional monomers on the selectivity and binding affinity of a polymer to caffeine is reported. A high binding affinity and selectivity of divinylbenzene (DVB) crosslinked polymers toward caffeine was exhibited by the binding competition of caffeine with several dimethylated and chlorinated xanthines and N-methylated uric acids in aqueous media. To understand the nature of the caffeine–polymer interaction, we performed binding studies with solvents of different polarities and ionic strengths. The binding properties of DVB-based polymers containing different functional monomers were compared with Amberlite^® XAD resins. Analytes with hydrophilic and electron-withdrawing groups lowered their binding affinity with the polymer in comparison with caffeine and its dimethylated derivatives. The caffeine–polymer interaction appeared to be predominantly a hydrophobic π–π interaction but partly due to the presence of caffeine-specific sites. The reversibility of the caffeine–polymer binding was investigated, and the dissociation constants were approximated to be 27 and 6 mM. Dipole moments of caffeine and related molecules were estimated theoretically and were correlated with their corresponding B/T ratio, which is defined as the fraction of caffeine bound to the polymer. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 195–205, 2001     

Finite element simulation to design constructive elements: An application to light gypsum plaster for partitions

In the past decade finite element simulation has become a very useful methodological tool in the different science fields. This article offers a specific application of this powerful mechanism used for analyzing the mechanical behaviour of constructive elements in the design phase, prior to the laboratory tests’ stage. The aim of applying this simulation is to minimize the high cost the real scale fabrication of these elements entails.This research focuses on the analysis by finite element simulations (FES) of several construction elements used as interior partitions and made of plaster lightened with cork. The results of the study will allow us to determine the most suitable thickness values and proportions to ensure that the requirements stated by the standards and norms for light partitions are fulfilled. These parameters will later be useful for the final laboratory tests.Two simulation groups have been developed using the ANSYS application: firstly, a partition leaf of 200 × 260 cm is studied exposing it to a superficial load and to an eccentric load following the EUAtc common directives for the technical appreciation of light panels, 1973). Second, the behaviour of a panel with a through opening is tested with the simulation regarding the different hypothesis of the structure deformation supporting and surrounding it.Finally, it is proved that the element of thickness 7 cm and proportions stated at the beginning ensure a good performance regarding strain without producing any visible fissures, and therefore are suitable for a further laboratory test on real models.     

Learning material defect patterns by separating mixtures of independent component analyzers from NDT sonic signals

This paper introduces the application of independent component analysis mixture modelling (ICAMM) in non-destructive testing (NDT). The application consists of discriminating patterns for material quality control from homogeneous and defective materials inspected by impact-echo testing. This problem is modelled as a mixture of independent component analysis (ICA) models, representing a class of defective or homogeneous material by an ICA model whose parameters are learned from the impact-echo signal spectrum. These parameters define a kind of particular signature for the different defects. The proposed procedure is intended to exploit to the maximum the information obtained with the cost efficiency of only a single impact. To illustrate this capability, four levels of classification detail (material condition, kind of defect, defect orientation, and defect dimension) are defined, with the lowest level of detail having up to 12 classes. The results from several 3D finite element models and lab specimens of an aluminium alloy that contain defects of different shapes and sizes in different locations are included. The performance of the classification by ICA mixtures is compared with linear discriminant analysis (LDA) and with multi-layer perceptron (MLP) classification. We demonstrate that the mass spectra from impact-echo testing fit ICAMM, and we also show the feasibility of ICAMM to contribute in NDT applications.     

Calculation of jet’s inlet temperature for plate temperature control in an impinging jet cooling problem

In this study, a conjugate gradient method based inverse algorithm is applied to estimate the inlet jet temperature in an impinging jet cooling problem. Given the maximum allowable plate temperature and the extent of the area on plate where temperature needs to be controlled, the jet temperature required to meet the two demands can be determined. The tests in two scenarios show that very accurate inlet jet temperatures were returned, resulting in a maximum temperature less than 1% difference with the specified temperature within the specified area. The technique presented here can be a great assist to engineers to design adequate thermal management systems for devices or processes requiring jet impingement cooling.     

Mass transfer modeling and simulation at a rotating cylinder electrode (RCE) reactor under turbulent flow for copper recovery

This work presents the numerical simulation of a laboratory reactor with rotating cylinder electrode (RCE) and a six-plate counter electrode that is used in studies on heavy metal recovery. The rate of electrode rotation and the potential applied are of such magnitude that the electrochemical reactor works in conditions of mass transport control under turbulent flow to obtain high recovery rates and formation of dendritic metal deposits. For hydrodynamics, the Reynolds averaged Navier–Stokes (RANS) equations were solved using the standard k–ε turbulence model, as well as wall functions based on the universal velocity distribution in the near-wall region. Results of 3-D simulations of the velocity field show clearly the formation of the turbulence Taylor vortex flow. For mass transfer, convection–diffusion equation was solved using the Kays–Crawford model for turbulent Schmidt number and Launder–Spalding wall functions adapted for mass transfer. Kinetics of copper recovery from aqueous solutions containing 0.019 M CuSO₄ and 1 M H₂SO₄, in the range of rotation speed of 400–1100 rpm, was adequately fit (error <8%) during the electrolysis time to achieve a final recovery of 85% for potentiostatic and 60% for galvanostatic experiments. The fitting parameter of the concentration wall function used in all experiments was A=2.9.     

Fundamental Parameters for the Stiffness and Strength Control of Artificially Cemented Sand

The treatment of soils with cement is an attractive technique when the project requires improvement of the local soil for the construction of subgrades for rail tracks, as a support layer for shallow foundations and to prevent sand liquefaction. As reported by Consoli et al. in 2007, a unique dosage methodology has been established based on rational criteria where the voids/cement ratio plays a fundamental role in the assessment of the target unconfined compressive strength. The present study broadened the research carried out by Consoli et al. in 2007 through quantifying quantifies the influence of voids/cement ratio on the initial shear modulus (G0) and Mohr-Coulomb effective strength parameters (c′,?′) of an artificially cemented sand. A number of unconfined compression and triaxial compression tests with bender elements measurements were carried out. It was shown that the void/cement ratio defined as the ratio between the volume of voids of the compacted mixture and the volume of cement is an appropriate parameter to assess both initial stiffness and effective strength of the sand-cement mixture studied.