Preparation and properties of PET/PA6 copolymer/montmorillonite hybrid nanocomposite

From in situ polycondensation, a poly(ethylene terephthalate)/Polyamide 6 copolymer/montmorillonite nanocomposite was prepared, after the treatment of montmorillonite (MMT) with a water soluble polymer. The resulting nanocomposites were characterized by X‐ray diffraction (XRD), differential scanning calorimeter (DSC), nuclear magnetic resonance (NMR), dynamic mechanical analysis (DMA), and transmission electron microscopy (TEM). The results of DSC, ¹H NMR, and DMA proved that the nanocomposite synthesized was PET/PA6 copolymer/MMT nanocomposite, not the PET/PA6 blend/MMT nanocomposite. The results of XRD and TEM proved that the dispersion of MMT was improved observably after the introduction of PA6 molecular chain into PET. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2512–2517, 2006     

Novel method for preparation of quaternary ammonium ionomer from epoxidized styrene–butadiene–styrene triblock copolymer and its use as compatibilizer for blending of styrene–butadiene–styrene and chlorosulfonated polyethylene

A novel method for the preparation of a quaternary ammonium ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed by a ring‐opening reaction of epoxidized SBS with triethylamine hydrochloride in the presence of a phase transfer catalyst. The optimum conditions were studied. The ionomer was characterized by quantitative analysis, IR spectroscopy, and ¹H‐NMR spectroscopy. Its water absorbency, oil absorbency, dilute solution viscosity, and use as a compatibilizer for the blending of SBS and chlorosulfonated polyethylene (CSPE) were investigated. The results showed that, under optimum conditions, the epoxy groups can be completely converted to the quaternary ammonium groups. The IR spectrum did not exhibit the absorption peak for quaternary ammonium groups, whereas the ¹H‐NMR spectrum and titration method demonstrated it. With increasing ionic group content, the water absorbency of the ionomer increased whereas its oil absorbency decreased. These indicated the amphiphilic character of the SBS ionomer. The dilute solution viscosity of the ionomer in toluene/methanol (9/1) solvent increased with increasing quaternary ammonium group content. The ionomer was used as a compatibilizer for the blends of SBS and CSPE. The addition of a small amount of the ionomer to the blend enhanced the mechanical properties of the blends: 2 wt % ionomer based on the blend increased the tensile strength and ultimate elongation of the blend nearly 2 times. The blends of equal parts SBS and CSPE behaved as oil‐resistant thermoplastic elastomers. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1975–1980, 2006     

高层级轮胎各层帘布裁断角度的计算方法

提出一种新的确定高层级轮胎内外各层帘布裁断角度的方法。根据各层帘布在成品胎内部的材料分布图和在成型机头上的材料分布图，计算该层所在的机头宽度，比较计算的机头宽度和实际的机头宽度，通过调整帘布裁断角度使两者近似相等。以此确定各层帘布的裁断角度，达到内外层帘线均匀伸张的目的。     

7.50-16 12PR轻型载重轮胎的优化设计

介绍轻型载重轮胎的优化设计。采取的主要措施是：减小轮胎外缘尺寸，外直径由８０８ｍｍ减至７９８ｍｍ，断面宽由１９８ｍｍ减至１９５ｍｍ；胎面花纹以纵向花纹为主，肩部为纵横结合花纹并加深肩部通挖花纹沟的深度，改善肩部生热；胎体帘布采用加粗减层的方法，用６层１８７０ｄｔｅｘ／２尼龙帘布代替８层１４００ｄｔｅｘ／２帘布。优化轮胎重量减轻４ｋｇ，轮胎性能符合国家标准。     

Direct synthesis of electrorheological suspension containing salt of poly(methacrylic acid) and its electrorheological effect

Colloidal suspensions containing salts of poly(methacrylic acid) which exhibit high electrorheological (ER) activity were synthesized by inverse emulsion polymerization. Factors influencing the ER effect were studied. The results showed that maximum yield stress occurred at optimum amounts of both polymeric stabilizer and crosslinking agent used in the inverse emulsion polymerization as well as a certain water content of the particles, while yield stress increased with electric field strength, average diameter of the particles below 0.9 μm, or the molar ratio of the salt to the acid. The ER activity for the suspensions containing different monovalent counter ions decreased in the following order: Li⁺ > Na⁺ > K⁺ > NH₄⁺. The phenomena were discussed with the ionic polarization mechanism. © 1995 John Wiley & Sons, Inc.     

接受理论视角下的儿童文学翻译

接受理论的基本观点对儿童文学翻译研究也具有一定的启发和借鉴作用:译者在翻译的过程中不仅要尊重原文和原作者.也要尊重译文的目标语读者--儿童,充分考虑儿童读者的期待视野,从而实现原文与译者期待视野、译文与儿童读者期待视野之间的视野融合.     

Facile synthesis of uniform hollow hematite sub-micro spheres with controllable shell thickness

A simple method was developed to prepare the uniform hematite hollow submicro-spheres with controllable structure and different diameter based on monodisperse poly(styrene-co-acrylic acid) [P(St-co-AA)] particles. The structure and formation mechanism of the hollow spheres were investigated in detail. The control mechanism of shell thickness was also discussed. The results indicated that the shell thickness and coarseness of the synthesized core-shell hematite hollow spheres could be tuned simply by the surface carboxyl content of the P(St-co-AA) particles. This method provided a new approach for the structure control in the preparation of hollow spheres. A Brunauer-Emmett-Teller (BET) test shows that the prepared hollow spheres have large surface areas which were decreased along with the increase of the diameter. The magnetic properties of the as-obtained hematite hollow spheres were investigated. The result showed that the coercivity and saturated magnetization were increased along with the increase of the shell thickness, and the remanent magnetization was increased along with the decrease of the diameter.     

Development of a unified viscoplasticity constitutive model based on classical plasticity theory

The traditional unified viscoplasticity constitutive model can be only applied to metal materials. The study of the unified constitutive theory for metal materials has discovered the correlation between the classical plasticity theory and the unified viscoplasticity constitutive model, thus leading to the concepts of the classic plastic potential and yield surface in the unified constitutive model. Moreover, this research has given the continuous expression of the classical plastic multiplier and presented the corresponding constructive method, which extends its physical significance and lays down a good foundation for the application of the unified constitutive theory to the material analysis in more fields. This paper also introduces the unified constitutive model for metal materials and geo-materials. The numerical simulation indicates that the construction should be both reasonable and practical. Supported by the National Natural Science Foundation of China (Grant No. 90410012)     

基于流形学习的人体动作识别

目的 提出了一个基于流形学习的动作识别框架,用来识别深度图像序列中的人体行为。方法 从Kinect设备获得的深度信息中评估出人体的关节点信息,并用相对关节点位置差作为人体特征表达。在训练阶段,利用LE（Lalpacian eigenmaps）流形学习对高维空间下的训练集进行降维,得到低维隐空间下的运动模型。在识别阶段,用最近邻差值方法将测试序列映射到低维流形空间中去,然后进行匹配计算。在匹配过程中,通过使用改进的Hausdorff距离对低维空间下测试序列和训练运动集的吻合度和相似度进行度量。结果 用Kinect设备捕获的数据进行了实验,取得了良好的效果;同时也在MSR Action3D数据库上进行了测试,结果表明在训练样本较多情况下,本文方法识别效果优于以往方法。结论 实验结果表明本文方法适用于基于深度图像序列的人体动作识别。     

基于高精度流线生成的交互流场可视化

高效准确的流线绘制一直是流场可视化的重要研究内容,流线可以对流场的重要特征进行有效的稀疏表示,但流线需要长期的粒子追踪过程及大量的积分计算,在面向大规模流场可视化时时间效率较低,需要高性能计算设备进行辅助计算.本文通过设计一种基于深度学习的高精度流线生成算法,将初始的低精度流线快速映射为稠密的高精度流线,可以在较短的时间内快速生成可靠的流线可视化结果,并在此基础上设计了交互式实时流场可视化系统,涵盖了流场的特征检测,属性关联分析,信息论分析等,帮助用户快速了解流场数据,找到自己感兴趣的区域进行后续进一步深度分析,避免了获取过多冗余数据,同时优化了分析工作的效率,满足用户对于流场结构,特征属性等多维度进行关联分析的需求.