FCC原料加氢预处理催化剂FF-14的实验室研究

为适宜进口高硫原油的加工，抚顺石油化工研究院研制开发了在保持较高脱氮活性的同时，具有高脱硫活性的新型Fcc原料加氢预处理催化剂。该催化剂以Mo-Ni-Co为活性组分，具有孔体积、比表面积较大，堆密度较高的特点。小型活性评价试验结果表明：在反应氢压10．0MPa、氢油体积比1000：1、体积空速1．0h^-1的工艺条件下，FF-14催化剂的脱硫和脱氮活性高于在国内广泛应用的蜡油加氢处理参比催化剂。在1800h连续运转过程中，FF-14催化剂脱硫率始终保持在98％左右，催化剂的活性稳定性较好。     

用稳流试验台和等折射率技术进行内燃机气缸和燃烧室中紊流运动的研究

本文报导了利用等折射率技术和激光多普勒测速技术在稳态流动模拟试验装置上对直喷式柴油机气缸和燃烧室内的紊流运动所进行的研究。由于在这种情况下激光束在透明材料制成的燃烧室内表面上不再受到折射或反射，所以可以在复杂形状燃烧室内的任一部位进行测量，并可保持高的有效数据率（Ｄａｔａｒａｔｅ）。由于有足够高的数据率，所以有关紊流的一些详细信息，如紊流强度、尺度、高次矩、能谱密度等都可以得到，而这些参数对燃烧都有重要影响。在本研究中对圆柱形燃烧室和方形燃烧室内的流场进行了测量，并获得了令人满意的结果。     

Generalized nonlinear FET/HEMT modeling

A modeling procedure which provides an accurate large-signal response for variation in bias, input power level, and fundamental frequency for FET/HEMT transistors is designed. A procedure for measuring the large-signal input response on an easily implemented system is presented. The technique is illustrated by designing a nonlinear PHEMT model, which includes an accurate large-signal input response and works with variations in the aforementioned input conditions. © 2004 Wiley Periodicals, Inc. Int J RF and Microwave CAE 14, 122–133, 2004.     

Selective Oxidation of Isobutane to Methacrolein over Mo–V–Te–Sb Mixed Oxide Catalysts with Different Antimony Contents

A series of MoV_0.3Te_0.23Sb_x (x=0–0.6) mixed oxides were prepared and investigated for the selective oxidation of isobutane. Among them, MoV_0.3Te_0.23Sb_0.5 showed the best methacrolein selectivity (as high as 39%), and the yield to methacrolein reached 7.8% at 20.0% isobutane conversion at 470 °C.     

A method to predict triaxial residual stresses in plastic pipes

Significant hoop and longitudinal stresses are present in medium‐density polyethylene (MDPE) pipe, arising from differential cooling from the inner and the outer surfaces of a pipe during production. Owing to the difficulty of directly measuring deformations, these stresses have hitherto been almost exclusively estimated indirectly from deflection measurements on large samples cut from the pipe wall. Furthermore, because of procedural problems, only uniaxial hoop or longitudinal stresses are normally attempted, and these are known to be specimen size–dependent. Similar problems are experienced with other polymeric pipes. In this paper, based on direct biaxial strain measurements on small samples cut from the pipe wall, a method to predict triaxial residual stress distributions through the pipe wall is presented. Thermal effects that generate residual stresses in plastic pipe were considered in the theory. The analytical solutions satisfy the self‐equilibrating conditions for both the hoop and the longitudinal stresses. Also, the radial stress is shown to be insignificant through the wall thickness of a mildly thick pipe. Polym. Eng. Sci. 44:1828–1838, 2004. © 2004 Society of Plastics Engineers.     

Mode couplings in superstructure fiber Bragg gratings

The spectral characteristics of superstructure fiber Bragg gratings are analyzed numerically based on the coupled mode theory, simultaneously taking into account the counterdirectional guided mode coupling, codirectional and counterdirectional claddings mode coupling. The theoretical results were compared with experimental data and very good agreement was obtained     

隔热油管技术应用于海上稠油常规生产井数值模拟分析

提出了将隔热油管应用于海上稠油常规生产井实现保温降粘开采的观点,并通过数值模拟方法对各种工况下隔热油管的性能进行了分析,得到了隔热油管使用效果与产液量、含水率、气油比及下入深度的关系,为隔热油管技术在海上稠油油田开发中的应用奠定了基础。     

葡萄糖水溶液分散物系悬浮聚合法制备微米级单分散交联聚苯乙烯微球

采用葡萄糖水溶液为分散介质,加入稳定剂聚乙烯醇,经悬浮聚合法合成了微米级单分散交联聚苯乙烯微球,考察了葡萄糖含量、苯乙烯用量、引发剂用量、稳定剂用量和交联剂用量对微米级单分散交联聚苯乙烯微球粒径大小及其分布的影响。实验结果表明,最佳的悬浮聚合条件为:葡萄糖水溶液中葡萄糖的质量分数为7%~8%、苯乙烯占单体的质量分数为25%~28%、交联剂二乙烯苯占单体的质量分数为0.4%、引发剂偶氮二异丁腈占单体的质量分数为1.0%、稳定剂聚乙烯醇占单体的质量分数为4%、温度为79℃、时间为10h;在此条件下制备的微米级单分散交联聚苯乙烯微球平均直径为10~20μm,分散系数为0.020~0.046。光学显微镜观察结果表明,合成的微米级单分散交联聚苯乙烯微球的形状好。     

MP-01新型异丙苯催化剂中试研究

采用MP—01新型异丙苯催化剂，在中试装置上进行了苯与丙烯液相烷基化反应合成异丙苯试验，通过催化剂寿命试验及条件试验考察了MP—01新型异丙苯催化剂的性能。催化剂寿命试验表明，MP-01催化剂具有良好的反应稳定性和选择性。在苯烯比2．5，丙烯空速0．8h^-1，循环量2．0t/h，反应器人口温度145℃的条件下．丙烯转化率100％，烃化液中异丙苯含量36％～37％，异丙苯选择性85％～87％，丙基选择性100％，正丙苯质量分数为50～120μg／g。苯烯比、温度、空速等条件试验证明：MP—01催化剂可以在低温、低苯烯比、高空速的反应条件下使用。在人口温度135℃，循环量2．0t/h，苯烯比2．5、空速1．0h。的条件下，丙烯转化率100％，丙基选择性100％．异阿苯选择性85％～86％，正丙苯未检出。