Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

Analysis of performance of fuel elements of the BOR-60 reactor with vibrocompacted uranium-plutonium oxide fuel

Translated from Atomnaya Énergiya, Vol. 66, No. 5, pp. 299–302, May 1989.     

Long-term recovery of pressurized water reactors following a large break loss-of-coolant accident

The U.S. Nuclear Regulatory Commission recently identified a possible safety concern for pressurized water reactors. Following the reflood phase of a large break loss-of-coolant accident, long-term cooling of the reactor core may not be ensured. Specifically, the concern is that, for a pump discharge cold leg break, the loop seals in the reactor coolant pump suction piping will refill with liquid and the post-reflood steam production may depress the liquid levels in the downflow sides of the loop seals. A loop seal depression would cause a corresponding depression of the core liquid levels and possibly a fuel rod heatup in the upper core region. This paper is intended as an introduction of the safety issue that: (1) describes the important aspects of the problem, (2) provides an initial analysis of the consequences, and (3) discusses ongoing work in this area. Because the elevation of the loop seals is near the mid-core elevation in plants of Westinghouse design, the concern is greatest for those plants. There is less concern for most plants of Combustion Engineering design, and likely no concern for plants of Babcock and Wilcox design. This issue was addressed by employing both steady-state and transient systems analysis approaches. Two approaches were used because of uncertainties regarding actual reactor coolant system behavior during the post-reflood period. The steady-state approach involved the development and application of a simple computer program to investigate reactor coolant system behavior assuming quiescent post-reflood conditions. The transient systems approach involved investigating this behavior using the RELAP5/MOD2 computer code and a comprehensive RELAP5 model of a Westinghouse pressurized water reactor. The steady-state analysis indicated only a moderate fuel rod heatup is possible. The transient systems analysis indicated boiling and condensation-induced flow oscillations are sufficient to prevent fuel rod heatup. Analysis uncertainties are discussed.     

A Device for Measurements of Dielectric Characteristics of Liquid Crystalline Materials, Solid Substances, and Their Melts

The device developed allows one to measure the dielectric characteristics of solid substances and their melts at frequencies of 20–20000 Hz and in a wide temperature range of 20–250°C. The measured temperature dependencies of the dielectric permittivities of several molecular and liquid crystals (stilbene, diphenyl, naphthalene, cholesterylpelargonate, and 8OCB) are presented.     

Surface structure of spherical gamma-alumina

Smoke produced by arcing of two aluminium rods in air is found to be composed of gamma-alumina spheres with a size range of 6 to 500 nm. While most particles are solid, single crystals with many exhibiting complicated stacking faulting and twinning, some are hollow. In appropriately clean conditions the surface is observed to be complicated, with the steps in some areas being directly related to the alumina lattice. Heating in air at 1150° C for 48 h transforms the sphere morphology of gamma to plate-and-block type alpha-alumina. Direct evidence of surface diffusion during this transformation is observed.