A semiautomated procedure for the determination of phosphorus in water, waste waters and particulates

Improved procedures for the determination of total dissolved phosphorus (TDP), particulate phosphorus (PP) and dissolved inorganic orthophosphate (DP) are described. Organic particulate material is solubilized in 5 n NaOH, and phosphorus compounds are oxidized and mineralized to orthophosphate by persulfate digestion. DP is determined by an improved automated molybdenum blue procedure that does not require sample pH adjustment or a correction for silicate interference in the 0–50 mg Si 1^?1 range. The use of 36-position digestion racks allows 32 TDP or PP samples to be digested in ca. 1 and 4 h respectively. Detection limits in μg of phosphorus 1^?1 are DP, 2; TDP, 5; and PP. 1. Waste water samples were analyzed for TDP and PP by the nitric acid-sulfuric acid procedure and by the proposed method. There was no significant difference between the two sets of data (P > 0.45).     

A Microcomputer Model for Flood Prediction with Applications

Abstract: A generally applicable mathematical model, tailored for use on a Personal Computer, as the design tool to simulate unsteady flood flow in a network of interconnected rivers has been developed and applied to the Sham Chun River along the border between Hong Kong and the People's Republic of China. The effect on the improved Sham Chun River due to the proposed river training in the River Indus, one of its tributaries, is evaluated. The one-dimensional unsteady flow model itself is broadly applicable to a wide range of hydrologic conditions and varying field situations. It incorporates real hydraulic features including branched channels and 'tidal flats' flooding and drying. The time history of water stages and discharges are computed at any desired location throughout the connected essentially one-dimensional channel network subject to initial and boundary conditions. Details are given of techniques adapted in using the computational scheme to quantify the unsteady flow condition and the means to assure an efficient numerical solution as well as to verify the accuracy of the computed outputs by subjection to carefully selected schematic simplified test cases and real prototype cases with numerical solution method is a useful predictive engineering tool in river design.     

Interaction effects of multiple pool fires

What are the effects of flame behavior of a number of fires burning in close proximity to one another? The results of measurements of burning rates, heat feedback, flame height, and flame trailing are reported for fires involving liquid pools.     

Fire Safety Engineering Research and Technology Centre (FireSERT) University of Ulster: Recent Developments

The Institute of Fire Safety Engineering Research and Technology Centre (FireSERT) at the University of Ulster in Northern Ireland has been a major provider of higher technical fire safety education, fire related research and services to industry for over 20 years. Its internationally recognised research spans the fields of fire dynamics, structural fire engineering, human behaviour in fire and more recently fire (CFD) modelling. Since 1991, it has offered the only PG Dip/MSc Fire Safety Engineering programme in the United Kingdom. In September 2000 FireSERT was the recipient of a £5.7 m Joint Infrastructure Fund (JIF) Award to build new fire safety engineering laboratories on the University's Jordanstown campus. These new facilities unparallel in the University sector in the UK offer greater scope and depth to the FireSERT's research portfolios. The new facilities will be extensively used in support of FireSERT's suite of MSc Fire Safety Engineering and DPhil programmes. This paper presents a brief history of FireSERT and its achievements, together with an update on the new facility, current research themes, taught programmes, research opportunities and visions for the future.     

A digital wind gust recorder

The instrument was a byproduct of an undergraduate final year project on wind power which was carried out by the Department of Mechanical Engineering of the University of Liverpool.The windmill test site was on an exposed, rocky island where there was no history of weather recording but a long tradition of violent winds.Field experience during the winter months suggested that corrosion fatigue arising from wind buffeting and salt spray would rank equally with maximum wind pressure as criteria of failure and if modern materials, so convenient for forming aerodynamic surfaces, were to be used then limited life concepts would need to be considered. This called for more knowledge of wind variations at the test site. A complete wind spectrum taken on chart recording instruments would have been ideal but since such such refined devices were not available the instrument to be described was designed.The only wind measuring instrument which was available was a rotating cup anemometer. This supplied an alternating voltage proportional to its rotational speed. It also operated a gear driven microswitch which could give an integrated “miles of wind” reading on an electromagnetic counter.Briefly the e.m.f. generated by the anemometer (Fig. 1) was matched against a pre-set voltage corresponding to the required gust velocity. When this was exceeded an appropriate counter was operated. Only the rising e.m.f. was significant. The subsequent fall was ignored. Initially three stages were incorporated which reported the gusts rising through forty, fifty and sixty knots, respectively. These recorded on separate counters. All basic settings were based on pitot-static speed determinations in a wind tunnel.     

Enhancement of bond strength for epoxy-coated rebar using river sand

In this paper, improvement of bond strength for epoxy-coated rebars is studied. Although the epoxy-coated rebar is well accepted as an alternative corrosion prevention method in engineering practice, it still suffers from its poor bond performance, which requires modification of design parameters such as development length and splice length. Following our previous study [Proceedings of the Third Structure Engineering Conference (1996) 651–659], it is proposed to mix the river sand in the epoxy to improve the bond strength of epoxy-coated rebar. Specimens of several sizes of river sand and sand/epoxy weight ratios were studied. The single-rebar pullout test was performed to examine the bond strength. The open circuit potential method and the linear DC polarization method were conducted for corrosion rate measurements to ensure for keeping the merit of epoxy-coated rebar, i.e. the ability of corrosion. Experimental results show that the proposed method is very promising.     

Toxic metals in the atmosphere in Lahore, Pakistan

Aerosol mass (PM₁₀ and PM_2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m^− 3), Zn (12 μg m^− 3), Cd (0.077 μg m^− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM_2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM₁₀ mass concentration was 340 μg m^− 3, which is well above the WHO guideline of 20 μg m^− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM₁₀ mass and 14% (29%) of PM_2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM₁₀. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment.     

Measurement of the intrinsic process zone in rock using acoustic emission

Laboratory specimens with a smooth boundary (no notch) were fabricated from four different rock types (grain sizes from 0.1–10 mm) and were tested in three-point bending. The locations of acoustic emission that occurred around peak load were used to characterize the dimensions of the region of localized microcracking, the so-called intrinsic process zone. The size of this zone was found to vary significantly between the rock types, but was not found to vary significantly for different size beams of the same material. An approximately linear relation was found between the width of the intrinsic process zone and the logarithm of the grain size. An explanation of size effect evolves naturally by considering the intrinsic process zone as a material characteristic. Two different models were used to analyze stress at failure. The first treated the intrinsic process zone as a mathematical crack, an infinite stress raiser, from which a K_IC value was calculated. The second model assumed the intrinsic process zone was a cohesive notch, a finite stress raiser, from which the theoretical tensile strength was defined. The second method seemed somewhat better at predicting size effect on nominal peak stress.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...