聚氨酯基pH/温度敏感性水凝胶的结构形态

通过阴离子型端丙烯酸酯基聚氨酯(UAA)与N-异丙基丙烯酰胺(NIPAAm)的共聚交联反应,制备了pH/温度敏感性水凝胶,分析了水凝胶的结构形态及溶胀水的状态.结果表明,凝胶相结构均匀,随聚氨酯含量的降低,凝胶的骨架变得松散,并且孔道结构增大,导致溶胀凝胶中不可冻结水含量及凝胶强度的降低.     

基于STEP标准的机械零件应用协议的设计方法

根据扩展应用协议的要求,提出一种基于STEP标准的汽车后桥主传动器中圆锥齿轮类零件的几何模型描述(ZCAP203、ZCAP42).通过对应用协议AP214、ZCAP203及ZCAP42进行互操作,制定出它的应用协议(ZCAP),为各类机械零件应用协议的制定提供了新方法.     

~(99)Tc~m-MVNE-膦混配配合物的制备及其在小鼠体内分布研究

为探索锝膦混配配合物的制备方法,寻找新的心肌显像剂,合成了一个新的N3S配体(MVNE)和3个膦配体。通过交换反应在室温下制备了放化纯>95%的99Tcm-MVNE, 然后分别与3种膦配体混配得到放化纯>90%的99Tcm-MVNE-膦混配配合物。小鼠体内的生物分布研究表明,该类混配配合物有较高的的心肌摄取,血液清除也较快。     

SSRF直线加速器聚束器的研制

在SSRF(上海同步辐射装置)注入器的预制研究中，等梯度行波聚束器是一个重点。本文描述了SSRF直线加速器聚束器的设计、加工以及测试结果。     

基于可编程逻辑器件的串行外设接口设计及实现

论述了串行外设接口(SPI)的原理,扩展了多从/多主模式、线与等新功能.用VHDL语言设计了全部源代码,在Max plusⅡ集成开发环境下对VHDL源代码进行编译、综合,并由可编程逻辑器件(CPLD)实现.使SPI接口应用的灵活性得到提高.     

一个几何概率问题的推广

本文利用初等方法将概率论中著名的几何概率问题-Buffon问题进行了较深入的探讨与推广。     

Isotope and hydrochemical study of seawater intrusion in Laizhou Bay, Shandong Province

Seawater intrusion on the northern coast of Laizhou City is featured by "three sources and three dimensions". Modern sea water, ancient saline water and brine contained both in the Quaternary aquifer and in the bedrock fissures or crevice have been identified as possible sources. The ratio of γSO4/γCI is used to distinguish the origin of the different types of saline water. The correlation between 3H and y SO4/γ Cl provides a quantitative differentiation on the origin of the saline water, which makes it possible to take counter protection measures in different areas affected by sea water intrusion.     

Rapid and Sensitive Liquid Chromatography-Tandem Mass Spectrometry for Quantification of Glycyrrhetic Acid in Human Plasma

A simple, rapid and sensitive liquid chromatography-tandem mass spectrometry(LC-MS/MS) for the determination of glycyrrhetic acid in human plasma with ginsenoside Rh2 as internal standard was developed and validated. The plasma samples were prepared via liquid-liquid extraction with ethyl acetate. Chromatographic separation was accomplished on a Venusil MP-C18(50 mm×2.1 mm, 5μm i.d.) column at 25℃. The mobile phase consisted of acetonitrile/5 mmol·L-1 ammonium acetate(10:90, volume ratio) at a flow rate of 0.4 mL/min. Negative electrospray ionization was utilized as the ionization source. Glycyrrhetic acid and internal standard were determined via the mutiple reaction monitoring of precursor→production ion transitions at m/z 469→425, 409 and m/z 621→161,respectively. Each sample was chromatographed within 2.5 min. The lower limit of uantification was 0.50 ng/mL for 200 μL of plasma sample and the linear range was from 0.50 ng/mL to 800 ng/mL. The intra-and inter-day precisions were less than 8.76% in terms of relative standard deviation(RSD), and the accuracy was within a range of -3.25%-1.32% in terms of relative error(RE). The method was successfully applied to the pharmacokinetic studies of glycyrrhetic acid in healthy male Chinese volunteers after a single oral administration of 75 mg of glycyrrhizin.     

上海市生活垃圾废塑料回收再利用现状及优化策略

在生活垃圾分类背景下上海市可回收物回收体系逐步完善,生活源废塑料回收再利用量获得极大提升。通过现场调研与统计资料分析,对当前上海市生活垃圾废塑料分类回收现状、再利用技术进行分析梳理,结果显示当前生活垃圾废塑料回收类别以PET、PP为主,分别占总回收量的45.3%和30.7%;另有近30%具有回收价值的废塑料未被回收,主要以PP和PET为主。在此基础上,提出需进一步完善分类回收标准与补贴政策、推动PET同级利用等回收技术创新、强化宣传教育与主体监管等优化策略,以期促进废塑料回收与再利用行业进一步发展。     

D2、M2、S5模具扁钢脱碳特性实验研究

开展了在空气和氮气两种气氛下,采用Gleeble-1500热模拟机与普通电炉两种热方式、不同加热温度、加热时间对D2、M2、S5钢脱碳层深度影响的试验研究。依据试验结果,结合现场实际制定了较为合理的生产工艺并在现场成功应用,使上述模具扁钢脱碳层指标达到了美国ASTM－A681技术标准。