Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41

Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d_1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce⁴⁺ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity.     

市区微蜂窝传播路径损耗模式的比较检验

讨论了几种微蜂窝路径损耗模式,并用我国某城市测量的微蜂窝传播数据对COST231WI,修正COST231WI和Xia模式进行了检验,结果表明修正COST231模式的误差最小,Xia模式次之,COST231WI模式最差。从而得到修正COST231模式比较符合我国实际的微蜂窝传播预测模式。     

我国先进制造技术的现状和发展途径

介绍了现在制造业中面临的问题，通过对问题的分析，提出了发展先进制造前沿技术的见解和在我国发展先进制造技术的途径，同时展望了先进制造技术的发展前景。     

一种考虑分布电容的模糊故障测距算法

提出了一种考虑分布电容的故障测距新算法。该算法基于微分方程描述的线路数学模型，利用单端信息对高压输电线路进行故障测距，保留了解微分方程算法的简单可靠、现实可行、不必考虑衰减直流分量和谐波及电网频率波动影响的特点，同时考虑过渡电阻和分布电容的影响，克服了传统解微分方程法中在经高阻接地故障时测距误差过大和忽略分布电容引起的故障定位不准确的缺点。为了检验算法的精度，进行了大量的动模实验。结果表明，算法原理正确并具有较高的测距精度。     

延迟破胶及强制裂缝闭合技术的研究及应用

采用延迟破胶技术,在压裂施工过程中加入不同浓度的胶囊破胶剂,利用它的延缓释放特性,使植物胶压裂液耐温、耐剪切稳定性增强,并且可以在不造成压裂液的流变性、滤失性和携砂性等过早丧失的前提下高浓度使用胶囊破胶剂。该技术与常规破胶技术相比,延缓释放率达50%,能更有效地清除液体残渣,减少压裂液对储层的伤害。同时由于有延缓破胶的特性,放喷采用相应的措施,可以降低支撑剂沉降速度,形成较好的沉砂剖面,提供高的裂缝导流能力,并且可以降低滤饼和压裂液残渣的伤害。     

18臂机械井径与磁法井径组合测井仪原理及应用

文章主要介绍了18臂机械井径与磁法井径组合测井仪的仪器结构、主要技术特性、测量原理及测井资料在油田中的应用。通过对测井资料的分析，阐述了该仪器在套损检测、补贴效果检查、射孔工程作业效果评价等方面的应用，为油田套管分析提供了可靠的保证。     

An Agent Interaction Based Method for Nonlinear Process Plan Scheduling

This article puts forward a scheduling method for nonlinear process plan shop floor.Task allocation and load bal- ance are realized by bidding mechanism.Though the agent interaction process,the execution of tasks is determined and the coherence of manufacturing decision is verified.The employment of heuristic index can help to optimize the system performance.     

浅谈南水北调中线S13标渠道机械化衬砌施工技术

南水北调渠道混凝土衬砌,由于其工程等级属于Ⅰ等,总干渠渠道为Ⅰ级建筑物,且渠底宽度较大,边坡坡度较缓,衬砌分缝较多,无论从资源投入、工效还是工程质量达到设计要求都有相当大的难度,渠道衬砌机施工技术正好解决这个难题,实现了机械化作业,值得在南水北调中线工程渠道施工中推广和应用.     

浅谈GPS在矿山测量中的应用

根据GPS的使用现状,结合测绘工作的一些感悟和经验,简单介绍GPS RTK(Real Time Kine-matic)工作原理及其在矿山测量、道路测量等实际工作的作业方法和注意的问题,及GPS在应用过程中的一些体会。     

中兴宽带线路测试技术及功能介绍

宽带线路测试是中兴通讯ZXDSL综合宽带运维系统的核心功能，在DSL业务提供过程中主要应用在开通前的预测试、线路测试、开通后的例测试以及故障时的在线测试。对其测试技术和功能作了介绍。