Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

Estimation of access failure probability in D2D underlaid cellular networks

Device-to-Device (D2D) communication can reduce the mobile devices' energy consumption and increase the spectral efficiency in D2D underlaid cellular networks. However, D2D users will interfere with co-channel cellular users, which can lead to cellular communication access failures. There are two reasons for cellular communication access failures: (1)D2D interference and (2)insufficient spectrum resources. To address the absence of research on the performance of cellular services' access in D2D underlaid cellular networks, this paper defines the new services' access failure probability and handoff services' access failure probability to evaluate the effect of both D2D interference and limited resources on cellular communication access. Based on the stochastic geometry and stochastic process, a random network model is presented to estimate the access failure probabilities, which can provide guidelines for network design to ensure cellular services' access. The accuracy of the estimated access failure probability is validated through extensive simulations.     

综合物探方法在地面塌陷勘察中的应用

地面塌陷引发的地质灾害对国民经济建设的危害重大。目前,探测塌陷区的物探方法种类繁多,但没有一种方法能全面解决各种问题,需综合运用多种方法。以安徽某地面塌陷研究对象,运用高密度电法和瞬变电磁法探测重点塌陷区域,简要介绍了高密度电法、瞬变电磁法的工作原理、方法特点、数据采集和数据处理,并对数据进行了解释,通过此次探测研究,取得了明显的成果。结果表明,两种方法相互验证,相互参照,相互补充,查明了塌陷区及其附近的覆盖层厚度、地质构造和地层岩性变化,为后期地面塌陷灾害治理提供了科学依据。     

液压夹具夹持力对金属材料室温拉伸曲线的影响及处理

针对日常检测中金属材料室温拉伸曲线出现的异常现象,分析材料试验机液压夹具夹持力大小对金属材料室温拉伸曲线的影响情况。结果表明:液压夹具夹持力对拉伸曲线的影响不可忽视,应注意观察试样最大拉力并适时调整夹具夹持力;在判明曲线异常为液压夹具夹持力所致时,应人为处理曲线得出正确测试结果。     

旅游法实施背景下网友对“导游员”工作的感知——基于新浪微博文本分析

以2013年国庆期间新浪微博网友关于“旅游法”和“导游”的原创微博为样本,采用数量分析方法,分析网友对旅游法实施后导游工作关注程度的变化以及对旅游法的支持程度,研究表明,国庆期间网友对旅游法实施后导游工作的关注日益增加,认为旅游法的实施对导游工作有正面影响的网友占大多数.使用词频统计法和共现分析法进行内容分析,网友对导游工作的感知主要包括：导游工作需要旅行社和游客的支持和理解;支持旅游法对无证导游的惩罚,但是惩罚力度不足;旅游法对强制消费的约束已初见成效,但部分网友表现出对部分导游工作态度消极的不满;旅游法实施后导游收入下降明显.     

Degradability and biocompatibility of bioglass/poly(amino acid) composites with different surface bioactivity as bone repair materials

Bioglass (BG) possesses excellent bioactivity and has been widely used in the manufacture of biomaterials. In this study, a composite with different surface bioactivity was fabricated via in situ melting polymerization by incorporating BG and poly(amino acid) (PAA) at a suitable ratio. The structure of the composite was characterized by Fourier transform infrared spectroscopy and XRD. The compressive strength of the BG/PAA composites was 139 MPa (BG:PAA = 30:70). The BG/PAA composites were degradable, and higher BG in composite showed higher weight loss after 4 weeks of incubation in simulated body fluid. In addition, the BG/PAA composite maintained adequate residual compressive strength during the degradation period. The SEM results showed the differences in surface bioactivities of the composites directly, and 30BG/PAA composite showed thicker apatite layer and higher Ca/p than 15BG/PAA. in vitro MG-63 cell culture experiments showed that the composite was noncytotoxic and thus allows cells to adhere, proliferate, and differentiate. This indicates that the composite has good biocompatibility. The implantations in the bone defects of rabbits for 4 and 12 weeks were studied. The composites had good biocompatibility and were capable of guiding new bone formation without causing any inflammation. The composite may be successfully used in the development of bone implants.     

双回转送进二辊冷轧管机凸轮设计研究

本文提出了双回转送进二辊冷轧管机凸轮理论轮廓曲线的新设计方法 ,其轮廓曲线加速度与跃度呈梯形 ,且跃度边界连续 ,给出了针对双回转送进二辊冷轧管机的两个过渡段具有等加速度和跃度的设计准则     

车轮的热烈和磨损机理与抗热裂耐磨车轮的研制

本文研究了车轮踏面的热裂和磨损机理,结果表明,车轮热裂主要与其含碳量和硬度有关;在使用合成闸瓦时,车轮踏面的磨损率与新形成的“白层”(马氏体)的断裂韧性有关。研制的抗热裂耐磨车轮(55SiMn)取得了明显的运用效果。     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

Einfluß des totvolumens auf die Al2O3-CVD-Abscheidung

The influence of the free gas volume around the substrate on the chemical vapor deposition of Al₂O₃ layers in the AlCl₃/H₂/CO₂ system at different pressures and temperatures has been studied. Through the water gas reaction which occurs homogeneously in the gas phase, the Al₂O₃ growth rate increases with increasing free gas volume until a certain volume is reached, after which it remains constant. For this ‘critical free gas volume’ a theoretical characteristic dimension L_max is introduced. It is defined as the normal distance from a substrate surface, at which the water molecules formed from the CO₂ + H₂ in the gas phase can no longer reach the substrate surface in the time available. The dependencies of L_max on pressure, temperature and gas flow rate deduced through this theoretical consideration show agreement with the experimental results.

Zusammenfassung

Der Einfluß des die Substrate umgebenden Totvolumens auf die Al₂O₃-CVD-Abscheidung im System AlCl₃/H₂/CO₂ wurde systematisch bei verschiedenen Drücken und Temperaturen untersucht. Durch die homogen in der Gasphase ablaufende Wassergasreaktion nimmt in allen Fällen die Abscheidungs-geschwindigkeit mit vergrößerten Totvolumen zuerst zu, bleibt aber ab einer bestimmten Totvolumensgröße konstant. Für diese “kritische Totvolumensgröße” wird die theoretische Kenngröße L_max eingeführt. Diese Größe ist als Normalabstand zur Substratoberfläche definiert, bei dem das in der Gasphase aus CO₂ + H₂ gebildeten Wasser in der zur Verfügung stehenden Zeit die mit AlCl₃ belegte Oberfläche der Substrate nicht mehr erreichen kann. Die aus dieser theoretischen Überlegung abgeleiteten Voraussagen über die Abhängigkeit des L_max von Druck, Temperatur und Gasströmungsgeschwindigkeit zeigten Übereinstimmung mit den Versuchsergebnissen.