Preparation and properties of CuInS2 thin film prepared from electroplated precursor

Thin CuInS₂ films were prepared by sulfurization of Cu/In bi-layers. First, the precursor layer was electroplated onto the treated surface of Mo-coated glass. Observation of the cross-section prepared by focused ion beam (FIB) etching revealed that the void-free film was initially formed on the top surface of the precursor layer and continued to grow until the advancing front of the film reached the Mo layer. The nucleation of voids near the bottom of the CuInS₂ film followed. To determine whether the condition of the Cu/In alloy influences the CuInS₂ quality we investigated the Cu/In alloy state using FIB. We found that the annealed precursor of low Cu/In ratio (1.2) has several voids in the mid position in the layer compared with Cu-rich precursor (1.6). The cross-sectional view of the Cu-rich absorber layer is uniform compared with the low copper absorber layer. Thin film solar cells were fabricated using the CuInS₂ film (Cu/In ratio: 1.2) as an optical absorber layer. It was found that the optimization of a sulfurization period is important in order to improve the cell efficiency. We have not yet obtained good results with high Cu-rich absorber because of a blister problem. This blister was found before sulfurization. So, we are going to solve this blister problem before sulfurization.     

A numerical method for natural convection and heat conduction around and in a horizontal circular pipe

Natural convection around a horizontal circular pipe coupled with heat conduction in the solid structure is numerically investigated using a preconditioning method for solving incompressible and compressible Navier–Stokes equations. In this method, fundamental equations are completely reduced to an equation of heat conduction when the flow field is static (zero velocity). Therefore, not only compressible flows but also very slow flows such as natural convection in a flow field and heat conduction in a static field can be simultaneously calculated using the same computational algorithm. In this study, we first calculated the compressible flow around a NACA0012 airfoil with conduction in the airfoil and then simulated natural convections around a horizontal circular pipe with a different heat conductivity. Finally, we numerically investigated the effect of heat conductivity of the pipe on natural convection.     

Feasibility study on 1.6 μm continuous-wave modulation laser absorption spectrometer system for measurement of global CO2 concentration from a satellite

A feasibility study is carried out on a 1.6 μm continuous-wave modulation laser absorption spectrometer system for measurement of global CO(2)concentration from a satellite. The studies are performed for wavelength selection and both systematic and random error analyses. The systematic error in the differential absorption optical depth (DAOD) is mainly caused by the temperature estimation error, surface pressure estimation error, altitude estimation error, and ON wavelength instability. The systematic errors caused by unwanted backscattering from background aerosols and dust aerosols can be reduced to less than 0.26% by using a modulation frequency of around 200 kHz, when backscatter coefficients of these unwanted backscattering have a simple profile on altitude. The influence of backscattering from cirrus clouds is much larger than that of dust aerosols. The transmission power required to reduce the random error in the DAOD to 0.26% is determined by the signal-to-noise ratio and the carrier-to-noise ratio calculations. For a satellite altitude of 400 km and receiving aperture diameter of 1 m, the required transmission power is approximately 18 W and 70 W when albedo is 0.31 and 0.08, respectively; the total measurement time in this case is 4 s, which corresponds to a horizontal resolution of 28 km.     

Fabrication of dense β-calcium orthophosphate with submicrometer-sized grains and its high-temperature superplastic deformation

High-density β-calcium orthophosphate (β-Ca₃(PO₄)₂, also called β-tricalcium phosphate: β-TCP) ceramics with submicrometer-sized grains were fabricated using a pulse-current pressure firing route. The maximum relative density of the β-TCP compacts was 98.7% at 1050 °C and this was accompanied by a translucent appearance. The mean grain size of the β-TCP compacts increased slightly with temperature to reach 0.78 μm at 1000 °C. However, upon further increasing the firing temperature to 1050 °C the mean grain size increased significantly to 1.6 μm. The extent of plastic deformation during tensile testing was examined at temperatures between 900 and 1100 °C using a strain rate in the range 9.26 × 10⁻⁵ to 4.44 × 10⁻⁴ s⁻¹. The maximum tensile strain achieved was 145% for a test temperature of 1000 °C and strain rate of 1.48 × 10⁻⁴ s⁻¹ and this was attributed to the relatively high density and small grain size.     

Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion

The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying (MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between Ag and Ni on atomic scale even after 100 rotations of HPT. On the other hand, the β-Zr phase started to appear after HPT 2 rotations in the Nb–Zr system, even though β-Zr is a high temperature phase. Further, Nb and Zr were completely mixed to form a bcc structured single phase after HPT 100 rotations. The sequence of alloying in the Nb–Zr system during HPT was discussed. These results clearly suggest that non-equilibrium phases can form in the Nb–Zr system by bulk MA by the use of HPT.     

Thin reduced graphene oxide interlayer with a conjugated block copolymer for high performance non-volatile ferroelectric polymer memory

Polymer ferroelectric-gate field effect transistors (Fe-FETs) employing ferroelectric polymer thin films as gate insulators are highly attractive as a next-generation non-volatile memory. For minimizing gate leakage current of a device which arises from electrically defective ferroelectric polymer layer in particular at low operation voltage, the materials design of interlayers between the ferroelectric insulator and gate electrode is essential. Here, we introduce a new solution-processed interlayer of conductive reduced graphene oxides (rGOs) modified with a conjugated block copolymer, poly(styrene-block-paraphenylene) (PS-b-PPP). A FeFET with a solution-processed p-type oligomeric semiconducting channel and ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) insulator exhibited characteristic source–drain current hysteresis arising from ferroelectric polarization switching of a PVDF-TrFE insulator. Our PS-b-PPP modified rGOs (PMrGOs) with conductive moieties embedded in insulating polymer matrix not only significantly reduced the gate leakage current but also efficiently lowered operation voltage of the device. In consequence, the device showed large memory gate voltage window and high ON/OFF source–drain current ratio with excellent data retention and read/write cycle endurance. Furthermore, our PMrGOs interlayers were successfully employed to FeFETs fabricated on mechanically flexible substrates with promising non-volatile memory performance under repetitive bending deformation.     

Nano Molecular‐Platform: A Protocol to Write Energy Transmission Program Inside a Molecule for Bio‐Inspired Supramolecular Engineering

In a coded self‐assembly, a simple code is written in the molecule, which self‐assembles the molecules into a fractal like structure, which acts as a seed for the next step. As the molecule turns into a complex seed, the code transforms into another form and several seeds self‐assemble into another structure, which acts as a seed for the next step. Until now, this technology was considered as a prerogative of nature. Here, a dendritic network is used to write a basic code by synthetically attaching 32 molecular rotors and doping two controller molecules in its cavity. The code live, which is an energy transmission path in the molecule, is imaged. When the energy transmission path or code is triggered, a series of products generate one after another spontaneously. Two examples are: i) dendritic seed (5–6 nm)→paired nanowire (≈12 nm)→nanowire (≈200 nm)→microwire (500 nm)→wire like rod (1–2 μm)→jelly→rectangular sheet (5 μm). ii) dendritic seed→nano‐sphere (20 nm)→micro‐sphere (500 nm)→large balls(1 μm)→oval shape rod (5–10 μm)→Y, L or T shaped rod assembly. The energy level interactions are tracked using spectroscopy how exactly a directed energy transfer code generates multi‐step synthesis from nano to the visible scale.     

Research and development related to PFM for aged nuclear components

At the Japan Atomic Energy Research Institute (JAERI), research activities related to probabilistic fracture mechanics (PFM) have been conducted as a part of the research program on aging and structural integrity of LWR components. This paper describes the outline of two activities related to PFM, i.e. the development of a PFM code and a contract research on ‘Application of PFM Methodology to Reliability Assessment of Nuclear Components’ implemented by the Japan Welding Engineering Society (JWES). In the former research, a new PFM code PASCAL (PFM Analysis of Structural Components in Aging LWR) was developed. This code has some new functions in models of semi-elliptical crack extension, elastic–plastic fracture analysis based on R6 method and options for the evaluation of overlay cladding and warm pre-stress (WPS) effect. Besides, the code has the function to evaluate the effect of irradiation embrittlement recovery by thermal annealing of a reactor pressure vessel and re-irradiation embrittlement. Based on the analyses on benchmark problem conducted by USNRC/EPRI, performance and functions introduced in the code were examined. Some case studies were also carried out to investigate the influence of various parameters. On the other hand, JAERI has been sponsoring the PFM related activities in relation to the structural integrity of LWR components. These activities have been conducted at JSME and JWES. The objective of this activity has been to provide for the future need of PFM methodology.     

Improving the detection of requirements discordances among stakeholders

This paper introduces a technique to identify requirements discordances among stakeholders. This technique is validated in experiments. An extended version of the goal-oriented requirements elicitation method, named attributed goal-oriented analysis (AGORA), and its supporting tool are used. Two types of requirements discordances among stakeholders are defined: the first arises from the different interpretations by the stakeholders and the second is the result of different evaluations of preferences. Discordances are detected by the preference matrices in AGORA. Each preference matrix represents both preferences of each stakeholder and the estimated preferences of other stakeholders. A supporting tool for the AGORA method was developed. This tool is a groupware that seamlessly combines face-to-face meetings for goal elicitation and distributed individual sessions for scoring preference values. The experimental results showed that the proposed classification of discordances was sound and that the occurrences of the requirements discordances could be detected by preference matrices.     

Study of asynchronizing phenomena using generator model with field mutual leakage reactance

This paper describes the effect of mutual leakage reactance in the rotor circuit on the analysis of generator transient characteristics. The authors derive a detailed equivalent circuit model for a 48P‐15,750‐kVA generator, analyze sudden short circuits and asynchronization phenomena of the generator by simulations with an electromagnetic transients program (ATP‐EMTP), and compare the results with experimental data. © 2005 Wiley Periodicals, Inc. Electr Eng Jpn, 153(3): 31–40, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20147