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991.
T Mester HJ Swarts S Romero i Sole JA de Bont JA Field 《Canadian Metallurgical Quarterly》1997,63(5):1987-1994
Aryl metabolites are known to have an important role in the ligninolytic system of white rot fungi. The addition of known precursors and aromatic acids representing lignin degradation products stimulated the production of aryl metabolites (veratryl alcohol, veratraldehyde, p-anisaldehyde, and 3-chloro-p-anisaldehyde) in the white rot fungus Bjerkandera sp. strain BOS55. The presence of manganese (Mn) is known to inhibit the biosynthesis of veratryl alcohol (T. Mester, E. de Jong, and J.A. Field, Appl. Environ. Microbiol. 61:1881-1887, 1995). A new finding of this study was that the production of the other aryl metabolites, p-anisaldehyde and 3-chloro-p-anisaldehyde, was also inhibited by Mn. We attempted to bypass the Mn-inhibited step in the biosynthesis of aryl metabolites by the addition of known and suspected precursors. Most of these compounds were not able to bypass the inhibiting effect of Mn. Only the fully methylated precursors (veratrate, p-anisate, and 3-chloro-p-anisate) provided similar concentrations of aryl metabolites in the presence and absence of Mn, indicating that Mn does not influence the reduction of the benzylic acid group. The addition of deuterated benzoate and 4-hydroxybenzoate resulted in the formation of deuterated aryl metabolites, indicating that these aromatic acids entered into the biosynthetic pathway and were common intermediates to all aryl metabolites. Only deuterated chlorinated anisyl metabolites were produced when the cultures were supplemented with deuterated 3-chloro-4-hydroxybenzoate. This observation combined with the fact that 3-chloro-4-hydroxybenzoate is a natural product of Bjerkandera spp. (H. J. Swarts, F. J. M. Verhagen, J. A. Field, and J. B. P. A. Wijnberg, Phytochemistry 42:1699-1701, 1996) suggest that it is a possible intermediate in chlorinated anisyl metabolite biosynthesis. 相似文献
992.
993.
I-Hsing Tan Dudley J.J. Babic D.I. Cohen D.A. Young B.D. Hu E.L. Bowers J.E. Miller B.I. Koren U. Young M.G. 《Photonics Technology Letters, IEEE》1994,6(7):811-813
We demonstrate greater than 90% quantum efficiency in an In0.53Ga0.47As photodetector with a thin (900 Å) absorbing layer. This was achieved by inserting the In0.53 Ga0.47As/InP epitaxial layer into a microcavity composed of a GaAs/AlAs quarter-wavelength stack (QWS) and a Si/SiO2 dielectric mirror. The 900-Å-thick In0.53 Ga0.47As layer was wafer fused to a GaAs/AlAs mirror, having nearly 100% power reflectivity. A Si/SiO2 dielectric mirror was subsequently deposited onto the wafer-fused photodiode to form an asymmetric Fabry-Perot cavity. The external quantum efficiency and absorption bandwidth for the wafer-fused RCE photodiodes were measured to be 94±3% and 14 nm, respectively. To our knowledge, these wafer-fused RCE photodetectors have the highest external quantum efficiency and narrowest absorption bandwidth ever reported on the long-wavelength resonant-cavity-enhanced photodetectors 相似文献
994.
995.
A new non-iterative method for a parametric study of a particular distillation column is devised. The technique takes use of the similarity between difference and differential equations. For solution of nonlinear boundary value problems for difference equations the GPM technique is used. The method is illustrated by calculated examples. 相似文献
996.
Examination of magnesium concentrations in the blood serum was carried out on a population of 246 patients 17-39 years old in pathologic/imminent abortion, imminent immature and premature labour and normal pregnancies as well as in first periods of parturition. In spite of considerable oscillations of magnesium concentrations in respective periods of normal and imminent pregnancies, the differences were statistically insignificant. A significant decrease of magnesium concentrations was found in the first period of parturition as compared with the imminent and normal pregnancies of the first and second trimester. 相似文献
997.
998.
999.
Summary Two soluble photochromic polymers containing 1-(ß-hydroxyethyl)-3,3-dimethyl-6-nitrospiro[2H-1-benzopyran-2,2-indoline] bound on a variously long side chain were prepared. It was found that the discolouration process depends on the length of the side chain to which the photochromic centre is bound. 相似文献
1000.
Vladivoj Valković Ivica Orlić Jagoda Makjanić Dubravko Rendić Uroš Miklavžič Miloš Budnar 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》1984,4(1):127-131
Three different modes of sample excitation in X-ray emission spectroscopy were used in trace element analysis of coal and coal ash: proton beam, Mo X-ray tube and radioactive sources 57Co and 109Cd. The results of analysis are presented and methods and their possibilities are compared in order to indicate the most appropriate technique for the particular purpose. 相似文献