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111.
Polypropylene/silica micro‐ and nanocomposites modified with poly(styrene‐b‐ethylene‐co‐butylene‐b‐styrene) 下载免费PDF全文
The effects of different silica loadings and elastomeric content on interfacial properties, morphology and mechanical properties of polypropylene/silica 96/4 composites modified with 5, 10, 15, and 20 vol % of poly(styrene‐b‐ethylene‐co‐butylene‐b‐styrene) SEBS added to total composite volume were investigated. Four silica fillers differing in size (nano‐ vs. micro‐) and in surface properties (untreated vs. treated) were chosen as fillers. Elastomer SEBS was added as impact modifier and compatibilizer at the same time. The morphology of ternary polymer composites revealed by light and scanning electron microscopies was compared with morphology predicted models based on interfacial properties. The results indicated that general morphology of composite systems was determined primarily by interfacial properties, whereas the spherulitic morphology of polypropylene matrix was a result of two competitive effects: nucleation effect of filler and solidification effect of elastomer. Tensile and impact strength properties were mainly influenced by combined competetive effects of stiff filler and tough SEBS elastomer. Spherulitic morphology of polypropylene matrix might affect some mechanical properties additionally. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41486. 相似文献
112.
基于模型分析,研究了镀金可伐引线在各种缺陷组合方式下的偶合系统在静、动态3%NaCl溶液中的腐蚀行为。应用OCC理论阐述了蚀孔的形成和形貌特征。大气环境下镀金可伐引线的腐蚀是以偶合腐蚀为起因,具有闭塞小孔腐蚀特征的局部腐蚀。中性介质的实验结果与实际断腿样品在形貌等各方面均十分相符,这支持了上述观点。 相似文献
113.
Prof. Dr. Zhiqing Zhang Dr. Mark A. Eckert Dr. M. Monsur Ali Linan Liu Dr. Dong‐Ku Kang Elizabeth Chang Dr. Egest J. Pone Prof. Dr. Leonard S. Sender Prof. Dr. David A. Fruman Prof. Dr. Weian Zhao 《Chembiochem : a European journal of chemical biology》2014,15(9):1268-1273
We report a simple, versatile, multivalent ligand system that is capable of specifically and efficiently modulating cell‐surface receptor clustering and function. The multivalent ligand is made of a polymeric DNA scaffold decorated with biorecognition ligands (i.e., antibodies) to interrogate and modulate cell receptor signaling and function. Using CD20 clustering‐mediated apoptosis in B‐cell cancer cells as a model system, we demonstrated that our multivalent ligand is significantly more effective at inducing apoptosis of target cancer cells than its monovalent counterpart. This multivalent DNA material approach represents a new chemical biology tool to interrogate cell receptor signaling and functions and to potentially manipulate such functions for the development of therapeutics. 相似文献
114.
A general and complete methodology is presented to facilitate systematic modeling and design of polymer processes during the early development period. To capture and handle the subjective type of uncertainty, embedded in the preliminary process development, fuzzy theories are used as a basis to model and design the process in the presence of ambiguity and vagueness. Physical membership functions are developed for mapping the relation between process variables and the associated fuzzy uncertainties. Based on the qualitative results generated using our previously proposed “linguistic based preliminary design method,” the process modeling can be followed even in the absence of any process governing equations. The modeling is carried out by establishing an appropriate fuzzy reasoning system which provides a specific functional mapping that relates input process variables to one (or more than one) output performance parameter(s). A reduced yet feasible domain is generated by our qualitative design scheme to constrain the process variables. Now, any optimization routine can then be employed to search for a proper process design. We demonstrate the effectiveness of the proposed methodology by its application to a typical compression molding process. 相似文献
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The extraction of high-quality DNA from processed dairy products is often the crucial step in an authentication process by PCR-based methods. In this study, we optimized a novel DNA extraction method for milk powder and used the extracted DNA for identification of milk powder based on PCR analysis. The DNA quality was assessed by amplifying target sequences from mitochondrial genes, as well as by monitoring the yield, purity, and integrity of the extracted DNA. In addition, a laboratory adulteration model of milk powder was detected by PCR-based methods (PCR and real-time PCR) using primers targeting the mitochondrial 12S rRNA gene. Results showed that a sufficient amount and quality of DNA could be isolated from milk powder with this method. Both PCR and real-time PCR detection of cow milk compositions in goat milk powder further confirmed the DNA extracted with this extraction method could be widely used in addressing milk powder adulterant by a PCR-based method. 相似文献
117.
The aim of this study was to determine the levels of essential, trace and toxic elements, such as K, Ca, Fe, Cu, Al, Ni, Sn, Pb and Cd in citrus honeys from different regions (industrialized and nonindustrialized) of Hatay, Turkey. K, Ca, Na and Mg were the most abundant elements, with mean contents of 363.5, 256.6, 88.1 and 37.7 mg/kg, respectively. The trace element mean contents ranged between 0.032 and 15.58 mg/kg. Significant differences in Fe, Cu, Al, Ni, Sn, Pb, Cd, Co and Sr levels were observed between two different regions. The findings that Fe, Cu, Al, Ni, Sn, Pb, Cd, Co and Sr contents in citrus honeys from industrialized regions were higher than citrus honeys from non-industrialized regions indicate that the honeys were affected by industrial pollution. Chemometric methods were applied to classify honey according to mineral content. Cluster analysis showed three clusters corresponding to the three different regions. 相似文献
118.
Maoxiong Zhao Mu Ku Chen Ze-Peng Zhuang Yiwen Zhang Ang Chen Qinmiao Chen Wenzhe Liu Jiajun Wang Ze-Ming Chen Bo Wang Xiaohan Liu Haiwei Yin Shumin Xiao Lei Shi Jian-Wen Dong Jian Zi Din Ping Tsai 《光:科学与应用(英文版)》2021,10(4):551-561
Metalenses have emerged as a new optical element or system in recent years, showing superior performance and abundant applications. However, the phase distribut... 相似文献
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120.
The rates of intrasubband and intersubband scattering of electrons by polar optical and intervalley phonons are determined
in relation to the electron energy and width of a deep rectangular quantum well in GaAs. The Monte Carlo method was used to
calculate the field dependences of the electron’s drift velocity in quantum wells with the width of 10, 20, and 30 nm. It
is shown that the drift velocity in high electric fields in a quantum well vastly exceeds the maximum drift’s saturation velocity
in the bulk material. 相似文献