Broadband Light Absorption and Efficient Charge Separation Using a Light Scattering Layer with Mixed Cavities for High‐Performance Perovskite Photovoltaic Cells with Stability

CH₃NH₃PbI₃ is one of the promising light sensitizers for perovskite photovoltaic cells, but a thick layer is required to enhance light absorption in the long‐wavelength regime ranging from PbI₂ absorption edge (500 nm) to its optical band‐gap edge (780 nm) in visible light. Meanwhile, the thick perovskite layer suppresses visible‐light absorption in the short wavelengths below 500 nm and charge extraction capability of electron–hole pairs produced upon light absorption. Herein, we find that a new light scattering layer with the mixed cavities of sizes in 100 and 200 nm between transparent fluorine‐doped tin oxide and mesoporous titanium dioxide electron transport layer enables full absorption of short‐wavelength photons (λ < 500 nm) to the perovskite along with enhanced absorption of long‐wavelength photons (500 nm < λ < 780 nm). Moreover, the light‐driven electric field is proven to allow efficient charge extraction upon light absorption, thereby leading to the increased photocurrent density as well as the fill factor prompted by the slow recombination rate. Additionally, the photocurrent density of the cell with a light scattering layer of mixed cavities is stabilized due to suppressed charge accumulation. Consequently, this work provides a new route to realize broadband light harvesting of visible light for high‐performance perovskite photovoltaic cells.     

An adaptive method based on the improved LPA-ICI algorithm for MRI enhancement

Various diseases are diagnosed using medical imaging used for analysing internal anatomical structures. However, medical images are susceptible to noise introduced in both acquisition and transmission processes. We propose an adaptive data-driven image denoising algorithm based on an improvement of the intersection of confidence intervals (ICI), called relative ICI (RICI) algorithm. The 2D mask of the adaptive size and shape is calculated for each image pixel independently, and utilized in the design of the 2D local polynomial approximation (LPA) filters. Denoising performances, in terms of the PSNR, are compared to the original ICI-based method, as well as to the fixed sized filtering. The proposed adaptive RICI-based denoising outperformed the original ICI-based method by up to 1.32 dB, and the fixed size filtering by up to 6.48 dB. Furthermore, since the denoising of each image pixel is done locally and independently, the method is easy to parallelize.     

Effects of surface sterilisation with green synthesised silver nanoparticles on Lamiaceae seeds

Nanoparticles have been used in many areas of biotechnology. In this study, an alternative surface sterilisation method was established for plant tissue cultures. Silver nanoparticles synthesised via green synthesis were used for the surface sterilisation of Lamiaceae seeds (Salvia farinecae, Ocimum basilicum – Large Leaf Italian, Thymus vulgaris, Ocimum basilicum var. purpurascens). Water extracts of dried Alkanna tinctorum rhizomes and Syzygium aromaticum flowers were utilised in the bioreduction of silver ions. The seeds were exposed to 0, 1, 7, 14 and 28 day‐old colloidal solutions of silver nanoparticles and their effects on germination and surface sterilisation were determined. Fresh (0 and 1 day‐old) colloidal solutions of silver nanoparticles were found very effective on surface sterilisation (100%). Moreover, they showed no negative effect on both germination and morphology of plantlets. It was shown that silver nanoparticles can be used as a surface sterilisation agent and they have no adverse effects on seed germination and in vitro plantlet growth.Inspec keywords: nanoparticles, microorganisms, sterilisation (microbiological), silver, nanofabrication, antibacterial activity, colloids, nanobiotechnology, agricultureOther keywords: green synthesised silver nanoparticles, Lamiaceae seeds, silver ions, surface sterilisation agent, seed germination, colloidal solutions, surface sterilisation method, Ag     

A SLIT THROUGH PHOTOGRAPHY

Post-war experimental and conceptual photography in former Yugoslavia has only rarely been the subject of detailed study and interpretation. In considering this period, it is necessary to take into account several factors, including the absence of permanent exhibition spaces for photography, the lack of magazines in which photographic themes were presented and discussed, the impossibility of studying the field of photography and, finally, the inadequate knowledge and application of contemporary criticism and theories of photography. Nevertheless, from the mid-1950s onwards it is possible to note a variety of innovations in the field, in terms of both form and subject-matter. This article considers rare instances of institutional support for progressive photography-related events and unique, intellectual-poetic works. After the break-up of Yugoslavia, there is a dominant tendency to nationalize art created in the former state, thus ignoring the specific Yugoslav cultural field as well as the European context. Based on a methodology which surpasses the national (but still acknowledges it) and searches for meaning within the broader socio-political space to which art is referring, the research aims to change the paradigm of the peripheral position and general ignorance of the circumstances under which this innovative practice emerges.     

NMR study of quaternary superconductor RM2B2C (R = Y,La, Th,and M = Ni,Pd, Pt)

¹⁹⁵Pt-,¹³⁹La- and¹¹B-NMR have been investigated in quaternary RM₂B₂C (R=Y, La, Th and M=Ni, Pd, Pt). The electric quadrupole frequency of¹³⁹La changes more than 5 times in magnitude from M=Ni to Pt, indicating that the hybridization of La-5d and d-electrons of M-element changes largely. The analysis of¹¹B and¹³⁹La spectra shows also the large change of the magnetic anisotropy with R and M element, i.e., _{II c}>_{II ab} in LaNi₂B₂C, but _{II c}>_{II ab} YNi₂B₂C.The data of T₁T and K of¹⁹⁵Pt and¹¹B are consistent with the band effects and with no evidence of strong antiferromagnetic correlation effects.     

The crystal structure of the immunity protein of colicin E7 suggests a possible colicin-interacting surface

The immunity protein of colicin E7 (ImmE7) can bind specifically to the DNase-type colicin E7 and inhibit its bactericidal activity. Here we report the 1.8-angstrom crystal structure of the ImmE7 protein. This is the first x-ray structure determined in the superfamily of colicin immunity proteins. The ImmE7 protein consists of four antiparallel alpha-helices, folded in a topology similar to the architecture of a four-helix bundle structure. A region rich in acidic residues is identified. This negatively charged area has the greatest variability within the family of DNase-type immunity proteins; thus, it seems likely that this area is involved in specific binding to colicin. Based on structural, genetic, and kinetic data, we suggest that all the DNase-type immunity proteins, as well as colicins, share a "homologous-structural framework" and that specific interaction between a colicin and its cognate immunity protein relies upon how well these two proteins' charged residues match on the interaction surface, thus leading to specific immunity of the colicin.     

Passive fuzzy controller design via observer feedback for stochastic Takagi-Sugeno fuzzy models with multiplicative noises

This paper investigates the fuzzy control problem of a class of nonlinear continuous-time stochastic systems with achieving the passivity performance. A model-based observer feedback fuzzy control utilizing the concept of so-called parallel distributed compensation (PDC) is employed to stabilize the class of nonlinear stochastic systems that are represented by the Takagi-Sugeno (T-S) fuzzy models. Based on the Lyapunov criteria, the Linear Matrix Inequality (LMI) technique is used to synthesize the observer feedback fuzzy controller design such that the closed-loop system satisfies stability and passivity constraints, simultaneously. Finally, a numerical example is given to demonstrate the applicability and effectiveness of the proposed design method.     

Disjoint essential sets of implicates of a CQ Horn function

In this paper we study a class of CQ Horn functions introduced in Boros et al. (Ann Math Artif Intell 57(3–4):249–291, 2010). We prove that given a CQ Horn function f, the maximal number of pairwise disjoint essential sets of implicates of f equals the minimum number of clauses in a CNF representing f. In other words, we prove that the maximum number of pairwise disjoint essential sets of implicates of f constitutes a tight lower bound on the size (the number of clauses) of any CNF representation of f.