Research on hydrophobicity of electrospun Fe3O4/PVDF nanofiber membranes under different preparation conditions

Abstract

Preparation condition can affect the structure and the properties of nanofiber membrane. In order to explore suitable conditions to prepare the Fe₃O₄/PVDF nanofiber membrane with good hydrophobicity, the hydrophobicity of Fe₃O₄/PVDF nanofiber membranes obtained by electrospinning was investigated by changing preparation conditions like weight percentage of Fe₃O₄ nanoparticles, blending quality concentration of poly (vinylidene fluoride) (PVDF) and Fe₃O₄ nanoparticles, and positive voltage. And the variations of hydrophobicity of Fe₃O₄/PVDF nanofiber membranes modified by 1H, 1H, 2H, 2H-perfluorodecyl trimethoxysilane were studied. The results show that the hydrophobicity of Fe₃O₄/PVDF nanofiber membranes has changed under different preparation conditions. The contact angles of samples increased after a modification by 1H, 1H, 2H, 2H-perfluorodecyl trimethoxysilane, which indicates that the hydrophobicity of Fe₃O₄/PVDF nanofiber membranes has been enhanced.     

Compressive properties of pristine and SiC-Te-added MgB2 powders,green compacts and spark-plasma-sintered bulks

Pristine and (SiC+Te)-added MgB₂ powders, green and spark plasma sintered (SPS) compacts were investigated from the viewpoint of quasi-static and dynamic (Split-Hopkinson Pressure Bar, SHPB) compressive mechanical properties The amount of the additive (SiC+Te) was selected to be the optimum one for maximization of the superconducting functional parameters. Pristine and added MgB₂ show very similar compressive parameters (tan δ, fracture strength, Vickers hardness, others) and fragment size in the SHPB test. However, for the bulk SPSed samples the ratio of intergranular to transgranular fracturing changes, the first one being stronger in the added sample. This is reflected in the quasi-static K_IC that is higher for the added sample. Despite this result, sintered samples are brittle and have roughly similar fragmentation behavior as for brittle engineering ceramics. In the fragmentation process, the composite nature of our samples should be considered with a special focus on MgB₂ blocks (colonies) that show the major contribution to fracturing. The Glenn-Chudnovsky model of fracturing under dynamic load provides the closest values to our experimental fragment size data.     

从数据库到数据仓库——广电未来的制胜武器

在目前数据爆炸、信息匮乏的情况下，需要利用数据仓库系统集成1个或多个独立传统数据库数据，通过分析海量数据发现市场潜在规律，获取商业信息以支持商业决策，这将是广电未来的制胜武器。     

质量控制图系统的实现及在SMT中的应用

本文将控制图理论与计算机技术相结合,开发了质量控制图系统.介绍了该系统的设计方案和关键技术问题,并以电子产品制造中监控SMT机的焊膏厚度为例说明了系统的应用.     

天然水资源价值评估的能值方法及应用

本文从水资源的自然属性出发，提出了采用能值(Emergy)理论与方法研究天然水资源价值的新思路。论述了环境与自然资源定价的能值价值理论；根据水文循环与天然水资源基本特性，给出了水资源生成与能量转换的概念模型；从水的化学能角度提出了天然水资源价值的能值评估方法，包括理论方法与简化方法；并以我国南方某沿海县域为例进行了实际应用。实例表明，基于能值价值理论的天然水资源价值定量评估方法具有可行性。     

PKI在网络接入控制中的应用

一、前言网络,无论是企业、机构内部网还是公共服务网,都是受保护的资源,只有获得许可、授权的人员或设备才能接入网络接入控制是网络安全的一个重要环节而,接入控制的关键是身份鉴别。目前常用的身份鉴别技术有口令动、态口令生物特征(如指纹)和PKI(PublicKeyInfrastructure),其中PKI具有安全性高、安全功能多样等特点。恰当的网络身份鉴别协议同PKI的结合能够实现安全的网络接入控制。二、EAP-ExtensibleAuthenticationProtocolE A P是为点对点协议(Point-to-PointProtocol,PPP)[1]设计的身份鉴别协议,它采用Request/Response…     

基于水印的图像认证和完整性保护技术

数字水印技术的发展为解决图像认证和完整性保护问题提供了新的思路。对用于篡改检测和图像认证的水印技术做了综述。数字水印技术根据其识别差错的能力分为四种类型:易损水印、半易损水印、混合水印和自嵌入水印。最后还对水印认证技术的安全性问题进行了讨论。     

Noise-Assisted Signal Reception in Threshold Neuron

1IntroductionSometi mes,noise can i mprove signal transmission orsignal processing in a nonlinear system.This phe-nomenonis the so-called Stochastic Resonance(SR)[1].Most studies of SRinvolve asubthresholdsignal througha single nonlinear systemand the non…     

分析矩形光波导损耗的简易方法

利用有效折射率和修正的有效折射率方法对矩形光波导的损耗作了简单有效的分析，并且计算出了纵向传播系数和衰减系数的大小。     

Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry