个人剂量无线监测装置的研制

本文提出了一种基于无线功能的个人剂量核辐射监测.旨在对辐射工作区域的工作人员提供辐射剂量的实时监测.该系统采用射频通信传输技术,将工二人所受的辐射剂量、剂量率和受照时间等数据发送至监控中心,以方便自动数据存储和分析.同时及时有效的预警,可避免工作人员超剂量受照的风险,对辐射环境卫生领域的深入研究也有重要的参考价值.     

高速铁路3G及TD-LTE移动通信关键问题研究综述

对现有及未来移动通信系统在高速铁路中应用出现的主要问题进行了分析,主要包括如车体损耗、小区切换、多普勒频移等。归纳总结了目前国内第三代移动通信(3G)三大主流技术的现有解决方案。在此基础上分析了未来分时长期演进(TD-LTE)移动通信在高铁场景下应用的先进性及其面临的技术难题。重点对解决该问题的国内外相关现有研究成果进行了分析评述,并针对现有研究存在的问题提出了下一步的研究方向。     

Simultaneous Synthesis of Dimethyl Carbonate and Poly（ethylene terephthalate） Using Alkali Metals as Catalysts

Dimethyl carbonate （DMC） and poly（ethylene terephthalate） was simultaneously synthesized by the transesterification of ethylene carbonate （EC） with dimethyl terephthalate （DMT） in this paper. This reaction is an excellent green chemical process without poisonous substance. Various alkali metals were used as the catalysts. The results showed alkali metals had catalytic activity in a certain extent. The effect of reaction condition was also studied. When the reaction was carded out under the following conditions： the reaction temperature 250℃, molar ratio of EC to DMT 3 ： 1, reaction time 3h, and catalyst amount 0.004 （molar ratio to DMT）, the yield of DMC was 68.9%.     

The Effects of Experience and Strategy on Visual Attention Allocation in an Automated Multiple-Task Environment

Operators and users interacting with computer environments often have to deal with multiple tasks at once, responding to each in series. Diagnostic automation, that is, automation that alerts users when and where to look, has been suggested to support the unique challenges of multiple task environments: activating tasks, switching between tasks, and tasks interfering with each other. Automation is not always reliable, however. Because of the common interaction with novel systems and the importance of training, the Simultaneous Task Environment Platform program—a multiple-task environment—was developed to understand the effects of experience on interaction with these automation-supported systems, as well as what strategies were developed. It was found that participants became more efficient with experience only when they interacted with higher reliability automation. Furthermore, the strategies participants developed focused on the differences between tasks and patterns across those tasks. Automated systems training should be sure to employ these findings.     

基于单片机的简易电子琴的设计与实现

电子琴是现代电子科技与音乐结合的产物,是一种新型的键盘乐器。它在现代音乐扮演重要的角色,单片机具有强大的控制功能和灵活的编程实现特性,它已经溶入现代人们的生活中,成为不可替代的一部分。该文的主要内容是用8253芯片为核心控制元件,设计一个简易电子琴。通过按动STAR ES598PCI单板机的G6区的1~7号键,使用单板机上的8255A芯片进行音调的选择,由8253芯片控制产生不同频率的方波,输出到单板机上D1区的蜂鸣器,使其对应于G6区的1~7号键由低到高发出1~7的音阶,并由8255A芯片控制8253芯片的工作状态,使其能够控制蜂鸣器的发声与否,从而实现简易电子琴的演奏功能。同时,也可以通过事先设置好的“乐谱”回放一段音乐,实现简易电子琴的回放功能以及对用户演奏过的一段音乐进行重放功能。用户可以通过DOS界面下的菜单对电子琴的回放和重放或是演奏功能进行选择。     

环己烷在Au-Co/SBA-15上选择性氧化的研究

以沉积-沉淀法制备了Au-Co/SBA-15催化剂,在没有任何有机溶剂或助剂的条件下,研究了以空气为氧化剂的环己烷选择性氧化。当Au-Co/SBA-15催化剂中金的质量百分含量为1.0%,催化反应在423 K 3.0 MPa下进行120 m in时,催化效果最好,此时环己烷的转化率为22.7%,环己酮和环己醇的总选择性为95.2%,酮醇比为2.9,且催化剂重复使用五次后活性基本不变。     

Solvent-free oxidation of benzyl alcohol using titania-supported gold–palladium catalysts: Effect of Au–Pd ratio on catalytic performance

The oxidation of benzyl alcohol with molecular oxygen under solvent-free conditions has been investigated using a range of titania-supported Au–Pd alloy catalysts to examine the effect of the Au–Pd ratio on the conversion and selectivity. The catalysts have been compared at high reaction temperature (160 °C) as well as at 100 °C, to determine the effect on selectivity since at lower reaction temperature the range of by-products that are formed are limited. Under these conditions the 2.5 wt.% Au–2.5 wt.% Pd/TiO₂ was found to be the most active catalyst, whereas the Au/TiO₂ catalyst demonstrated the highest selectivity to benzaldehyde. Toluene, formed via either a hydrogen transfer process or an oxygen transfer process, was observed as a major by-product under these forcing conditions.     

PVC微孔塑料的研究进展

阐述化学发泡剂、物理发泡剂和添加剂对PVC微孔发泡的影响,综述了PVC微孔发泡成型方法的研究进展,包括间歇成型法、连续挤出成型法和电磁动态挤出成型法。将振动力场引入到微孔发泡过程为PVC微孔塑料连续挤出成型提供了新的思路和研究方向。     

Isomerization Dynamics of Dicyanine A in n-Alcoholic Solution

The radiationless relaxation of dicyanine A molecules in n-alcohols methanol to butanol has been studied by picosecond fluorescence spectroscopy and time-resolved nonlinear spectroscopy. The fluorescence decay rates have been measured as a function of viscosity, temperature, and fluorescence wavelength. It is shown that the wavelength dependence can be explained by coexistence of two ground-state conformers. The intrinsic activation barrier for the nonradiative decay from the excited surface is very small, much less than 1 kcal/mol. In a particular solvent the time constants of the nonradiative relaxation show a linear dependence on the variation of viscosity. The experimental data are discussed in relation to the BFO theory (Bagchi, B.; Fleming, G.R.; Oxtoby, D.W. J. Chem. Phys. 1983, 78: 7375).     

Uniqueness and multiplicity criteria for an nth order chemical reaction

New and very strong criteria are presented for a priori prediction of the conditions for which the steady-state lumped parameter model of an nth order chemical reaction (n ≥ 0) in an adiabatic CSTR has either a unique or multiple solutions. The criteria show that the higher the order of the reaction the smaller is the region in the parameters space for which multiplicity can occur.New uniqueness and multiplicity criteria are developed also for an nth order reaction in a porous catalyst using a model, which accounts for intraparticle concentration gradients, while assuming a uniform intraparticle temperature different from the ambient one. The region in the parameters space for which steady state multiplicity can occur for this model is smaller than that for a corresponding lumped model, which ignores the intraparticle concentration gradients.