Atmospheric Chemistry of 2-Ethyl Acrolein

The atmospheric oxidation of the unsaturated aldehyde 2-ethyl acrolein, CH₂=C(C₂H₅)CHO, has been studied in laboratory experiments involving the reaction of ozone with 2-ethyl acrolein in the dark (with cyclohexane added to scavenge the hydroxyl radical), and the sunlight irradiation of 2-ethyl acrolein with NO in air. The major carbonyl products of the 2-ethyl acrolein reaction with ozone are formaldehyde, acetaldehyde, and the dicarbonyl ethylglyoxal, CH₃CH₂COCHO. Sunlight irradiation of 2-ethyl acrolein and NO led to the formation of three carbonyls (formaldehyde, acetaldehyde, and ethylglyoxal) and three peroxyacyl nitrates, (RC(O)OONO₂), including PAN (R = CH₃), PPN (R = C₂H₅), and the unsaturated compound EPAN (R = CH₂=C(C₂H₅)). Mechanisms are outlined for the reactions of ozone and of the hydroxyl radical with 2-ethyl acrolein. These mechanisms are consistent with the observed carbonyl and peroxyacyl nitrate products. Thermal decomposition, a major atmospheric removal process for peroxyacyl nitrates, has been studied for EPAN. The decomposition rate of EPAN relative to that of PAN is 0.59–0.73 at 292–294 K and 1 atm of air. Atmospheric implications of these results are discussed.     

Differential effects of aging on directional and absolute errors in visuospatial memory.

Studied memory for visuospatial arrays in 28 male and 34 female healthy dextral adults (aged 20–90 yrs). 10 abstract figures were presented in each hemispace over a series of learning trials, and then delayed free recall of figure placement was obtained. Figures were misplaced significantly downward and leftward in both hemispaces. Both vertical and horizontal absolute error increased significanty with age, but no age effects on directional errors were observed. The increase in absolute error over age is consistent with decreased anterograde memory and visuospatial skills in the elderly. The directional errors are believed to result from an attentional shift toward proximal peripersonal space, in combination with attentional shifts from differential left vs right cerebral activation. Gender effects were also observed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Trajectories leading to school-age conduct problems.

The present study applied a semiparametric mixture model to a sample of 284 low-income boys to model developmental trajectories of overt conduct problems from ages 2 to 8. As in research on older children, 4 developmental trajectories were identified: a persistent problem trajectory, a high-level desister trajectory, a moderate-level desister trajectory, and a persistent low trajectory. Follow-up analyses indicated that initially high and low groups were differentiated in early childhood by high child fearlessness and elevated maternal depressive symptomatology. Persistent problem and high desister trajectories were differentiated by high child fearlessness and maternal rejecting parenting. The implications of the results for early intervention research are discussed, with an emphasis on the identification of at-risk parent-child dyads. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Speakers gaze at objects while preparing intentionally inaccurate labels for them.

When describing scenes, speakers gaze at objects while preparing their names (Z. M. Griffin & K. Bock, 2000). In this study, the authors investigated whether gazes to referents occurred in the absence of a correspondence between visual features and word meaning. Speakers gazed significantly longer at objects before intentionally labeling them inaccurately with the names of similar things (e.g., calling a horse a dog) than when labeling them accurately. This held for grammatical subjects and objects as well as agents and patients. Moreover, the time spent gazing at a referent before labeling it with a novel word or accurate name was similar and decreased as speakers gained experience using the novel word. These results suggest that visual attention in speaking may be directed toward referents in the absence of any association between their visual forms and the words used to talk about them. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Performance evaluation of dynamically linearized and kinematically redundant planar manipulators

The objective of this research is to investigate the feasibility of a theoretical development which could lead to advanced manipulator concepts offering fast dynamic and control features. Specifically, the application of “dynamic linearization” to a kinematically redundant planar manipulator is studied. In comparing such a manipulator with a standard non-linear, non-redundant design it is shown that in addition to the expected merits in linearity, dexterity, and computational simplicity, savings in actuator energy consumption can also be realized using a relative simple trajectory optimization scheme.     

The nuclear fuel cycle

In the first half of the 21st century, a redistribution of the energy data should occur, where nuclear will play a more important role, particularly as coal will become more and more costly to extract.On a worldwide basis, the unability of oil to be replaced in some areas like transportation, and the difficulty of developing countries to find substitutes for this energy source, could also lead developed countries to keep the energy resources for a better utilization, and give the countries which have no access to other resources, a possibility to develop.Thus, France has extensively enhanced nuclear energy for its electricity production, and, consequently, makes the necessary efforts for the knowledge of the whole fuel cycle.     

Order–disorder phase transition induced by swift ions in MgAl2O4 and ZnAl2O4 spinels

Grazing X-ray diffraction was used to study in details the behaviour of two spinels, ZnAl₂O₄ and MgAl₂O₄ irradiated by swift ions. Such an irradiation allows to have an important irradiated depth and then accurate diffraction diagrams. Rietveld refinement done on these diagrams clearly show an order–disorder transition due to a melting of cations under irradiation in these two spinels. More especially, these results clearly exhibit that no new phase is created under irradiation in MgAl₂O₄. Raman spectroscopy, sensitive to the crystallographic space group, seems to confirm this analysis.     

Learning and Revising User Profiles: The Identification of Interesting Web Sites

We discuss algorithms for learning and revising user profiles that can determine which World Wide Web sites on a given topic would be interesting to a user. We describe the use of a naive Bayesian classifier for this task, and demonstrate that it can incrementally learn profiles from user feedback on the interestingness of Web sites. Furthermore, the Bayesian classifier may easily be extended to revise user provided profiles. In an experimental evaluation we compare the Bayesian classifier to computationally more intensive alternatives, and show that it performs at least as well as these approaches throughout a range of different domains. In addition, we empirically analyze the effects of providing the classifier with background knowledge in form of user defined profiles and examine the use of lexical knowledge for feature selection. We find that both approaches can substantially increase the prediction accuracy.     

Initial Stages in the Metal-dusting Process on Alloy 800

The initial stages of the metal-dusting process on Alloy 800 at 620 °C were investigated by light optical microscopy, RAMAN spectroscopy, atomic-force microscopy, Auger electron spectroscopy, transmission-electron microscopy and electron back-scatter diffraction. As it turned out the incubation period for metal-dusting is characterized by simultaneous formation of a heterogeneously growing oxide scale and deposition of carbon. The material surface shows different tarnish colors depending on the substrate-grain orientation with different susceptibility to the beginning of metal-dusting attack. “Low-index” grains were not attacked within the times investigated while the other grain orientations showed pitting. Carbon is evidently incorporated into the oxide scale from the very beginning of exposure with different intensities depending on the underlying substrate-grain orientation leading to differences in the tarnish colors. As a consequence carbides are formed even underneath “dense” oxide layers. Evidently metal-dusting attack starts at positions of the oxide scale where “higher carbon concentrations” are present.