以齐聚副产物制备耐高温泡沫剂

以齐聚副产物为原料在实验室分别以AlCl3、AlCl3络合物和杂多酸为催化剂合成并经磺化制备了用于提高石油采收率的耐高温泡沫剂，试验结果说明烷基碳数为16的异构烷基苯磺酸盐常温发泡性能最佳，烷基碳数大于20的正构烷基苯磺酸盐高温发泡性能最佳，后者特别适合高温蒸汽驱油。加入适当的非离子助剂及无机盐能够提高磺酸盐的水溶性，改善发泡剂溶液的稳定性。     

无油润滑压缩机活塞环和支承环设计

通过对填充聚四氟乙烯材料活塞环及带卸荷槽结构支承环的研究 ,确定了活塞及活塞环结构 ,建立了带卸荷槽支承环的力学分析模型 ,并将其结果用于结构尺寸的确定。在压缩机工艺指标不变的情况下 ,用该方法设计的活塞环和支承环性能优良。     

基于MPLS骨干网络的VPN解决方案

现有的虚拟专用网(VPN)方案大多基于IP协议,这种结构的VPN在数据包转发速度、扩展性、服务质量等方面都存在欠缺,所以本文提出了基于多协议标记交换(MPLS)骨干网络的VPN解决方案.由于MPLS和IPSec在身份认证方面都没有定义,所以我们在方案中把认证中心(CA)的证书管理引入进来.该方案的核心思想是:利用MPLS在传输效率上的优势,通过CA进行身份认证、IKE协议^[1]进行密钥协商以及IPSec协议^[2]进行数据包加密,从而在MPLS骨干网络上建立一个安全高效的VPN.本文对实现MPLS VPN的每个关键部件都做了进一步的描述.     

RSView32软件平台的应用及扩展

概述了RSView32工控软件的特点和使用方法 ,并通过贵溪冶炼厂的一个液位自动控制系统的人机界面设计说明了如何在控制系统中使用RSView32软件。文章特别介绍了如何用VBA程序设计来扩展其功能     

为促进我国核电事业的发展而努力

本文简介了国外压水堆核电站的发展趋向,展望了我国核电发展的前景,提出了我国发展核电的基本方针和应采取的对策.     

后压浆技术在杨凌国际会展中心基桩工程中应用效果的分析

本文叙述了杨凌国际会展中心基桩静力载荷试验的试验过程 ;通过对三根灌注桩承载力的试验结果分析 ,认为后压浆技术对提高灌注桩单桩极限承载力有很大作用     

A STUDY ON ACIDITY AND CATALYTIC PROPERTY OF [B] ZSM-5 CATALYST MODIFIED WITH SILICON COMPOUND BY CHEMICAL SURFACE DEPOSITION OF LIQUID-PHASE TECHNIQUE

The boron heteroatom zeolite catalyst has been modified with silicon compound by Chemical Surface Deposition of Liquid-phase (CLD) technique and the catalytic property of the modified catalyst is studied. Meanwhile, the acidity of the modified zeolite catalysts is characterized through TPD and IR technique, and the fluid adsorption method is used to determine its pore structure. The relationship between the catalytic property of the zeolite catalyst and its pore structure, its acidity has been found. The results of toluene-ethylene alkylation reaction indicate that the selectivity of p-ethyltoluene on the modified zeolite catalyst is higher than that on the zeolite catalyst before silanizated, reaching 94.14%.     

In-situ composite Cu-Cr contact cables with high strength and high conductivity

In order to develop a new type of contact cable with high strength and high electrical conductivity, Cu-Cr alloy series were selected as materials and Cu-Cr alloy castings were produced by means of directional solidification continuous casting (DSCC) process. The results show that the fibrillar strengthening phase, 13-Cr, orderly arranges among the copper matrix phase along the wire direction; and a microstructure of in-situ composite forms, which retains the basic property of good conductivity of the copper matrix and meanwhile obtains the strengthening effect of [3-Cr phase. The production technology as well as the mechanical property, electrical property, and synthetic property of the in-situ composite contact cables was discussed.     

一种新的加权最小二乘测距定位方法

三站二维定位问题是最小定位问题，一般只利用几何关系就能获得定位估计，但由于未利用距离测量的统计信息，定位精度较差。该文先将点到点的距离测量转化为点到线的距离估计，再在此基础上推导出一种新的加权几休定位方法，其中加权的确定利用了距离测量的统计信息。仿真实验表明，在测距误差较小时新方法具有更高的定位精度。     

Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.