Study of viscosity of mono-, di-, and trialkylamines

Viscosities of several mono-, di-, and trialkylamines have been measured in the temperature range 298 to 333 K. It is observed that viscosities are highly dependent on shape, size, and association through H-bond or through dipole. Following the transition state theory, energy, Gibbs free energy, and entropy of activation of viscous flow have been calculated. The values of expansion energy for these liquids have also been calculated using free volume theory, and subsequently amines have been classified as volume-restrained or energy-restrained liquids. The group contribution method of Van Velzen, Cardozo, and Langenkamp for estimating viscosity has been examined with the present and literature data, and the new group contribution increments N _i and B _i for amines have been evaluated.     

From ethnographic record to system design

This paper explores the issues involved in moving from ethnographic explorations of work in context to a practical contribution to system design. It does so using the example of an interdisciplinary research project involving sociologists and computer scientists in the domain of air traffic control systems. It forms a pair with another paper (Sommerville et al., 1992) exploring these questions from the perspective of our computer science partners. We characterise ethnography as a research method, and consider the differences between undertaking it for strictly sociological or anthropological purposes by contrast with interdisciplinary and design purposes. We summarise some of our results in ethnographic explications of the work of air traffic controllers, and the sociality which it manifests. We describe the dialogues involved in rendering these observations informative for systems design, and the mutual translations implied in attempting to reconcile sociological with software engineering questions about supporting the work. We conclude by specifying some features of cooperative work which an engineering approach is in danger of overlooking; the ways, and limits, in which ethnographers can form a bridge between users and designers; and some of the conflicts of interest entrained in generating technical change.The research is funded by the UK MRC/SERC/ESRC Cognitive Science/HCI Initiative with the title Social Analysis of Control Systems for HCI Design, grant number SPG 8931598. The computer science partners are Professor Ian Sommerville, Dr Tom Rodden, Dr Pete Sawyer and Mr Richard Bentley. Thanks are due to Val King, Kjeldt Schmidt, Ian Sommerville and Tom Rodden for very helpful comments on earlier drafts of this paper.     

Efficient Implementation of the Fuzzy c-Means Clustering Algorithms

This paper reports the results of a numerical comparison of two versions of the fuzzy c-means (FCM) clustering algorithms. In particular, we propose and exemplify an approximate fuzzy c-means (AFCM) implementation based upon replacing the necessary ``exact' variates in the FCM equation with integer-valued or real-valued estimates. This approximation enables AFCM to exploit a lookup table approach for computing Euclidean distances and for exponentiation. The net effect of the proposed implementation is that CPU time during each iteration is reduced to approximately one sixth of the time required for a literal implementation of the algorithm, while apparently preserving the overall quality of terminal clusters produced. The two implementations are tested numerically on a nine-band digital image, and a pseudocode subroutine is given for the convenience of applications-oriented readers. Our results suggest that AFCM may be used to accelerate FCM processing whenever the feature space is comprised of tuples having a finite number of integer-valued coordinates.     

Virtual reality in Africa – for Africa

The paper describes a number of virtual reality projects taking place in Africa. The availability of VR on PCs, it is argued, has made access possible for a large number of users. Applications for education and training and applications that preserve and promote African culture are particularly highlighted.     

Numerical simulation of 2D granular flow entrainment using DEM

To understand the entrainment process in granular flow, numerical experiments have been conducted using a Discrete Element Method model. A flow channel of 8 m long with \(15^\circ \) slope is setup with monitoring points located in an erodible bed. Particles, ranging from 3 to 4 mm in diameters, are used in the simulations. In the simulations, translational, rotational and average velocities, total volume, shear stresses are calculated in the measurement circles. The sizes of the measurement circles have been varied to see their effects on the results. It is found the minimum size of the measurement circles should include 20–30 particles. An new analytical model has been developed to calculate entrainment in granular flow. Results of the numerical experiment are compared with analytical model. Shear stresses at the interface between flowing particles in motion and the immobile particles in the channel bed, change of depth of erosion and entrainment rate are used to verify the analytical model. It is found that the calculated shear stresses in the PFC model agree well with the shear stresses calculated using Mohr–Coulomb frictional relationship in the analytical model. The calculated depth of erosion using the new analytical model is also compared with that from dynamic and static entrainment model. The results indicates that the analytical model is able to capture the mechanism of erosion and it can be used in granular flow analysis.     

Single point incremental forming: state-of-the-art and prospects

Incremental sheet metal forming in general and Single Point Incremental Forming (SPIF) specifically have gone through a period of intensive development with growing attention from research institutes worldwide. The result of these efforts is significant progress in the understanding of the underlying forming mechanisms and opportunities as well as limitations associated with this category of flexible forming processes. Furthermore, creative process design efforts have enhanced the process capabilities and process planning methods. Also, simulation capabilities have evolved substantially. This review paper aims to provide an overview of the body of knowledge with respect to Single Point Incremental Forming. Without claiming to be exhaustive, each section aims for an up-to-date state-of-the-art review with corresponding conclusions on scientific progress and outlook on expected further developments.     

Acoustic modeling problem for automatic speech recognition system: conventional methods (Part I)

In automatic speech recognition (ASR) systems, the speech signal is captured and parameterized at front end and evaluated at back end using the statistical framework of hidden Markov model (HMM). The performance of these systems depend critically on both the type of models used and the methods adopted for signal analysis. Researchers have proposed a variety of modifications and extensions for HMM based acoustic models to overcome their limitations. In this review, we summarize most of the research work related to HMM-ASR which has been carried out during the last three decades. We present all these approaches under three categories, namely conventional methods, refinements and advancements of HMM. The review is presented in two parts (papers): (i) An overview of conventional methods for acoustic phonetic modeling, (ii) Refinements and advancements of acoustic models. Part I explores the architecture and working of the standard HMM with its limitations. It also covers different modeling units, language models and decoders. Part II presents a review on the advances and refinements of the conventional HMM techniques along with the current challenges and performance issues related to ASR.     

Free-living inferential modeling of blood glucose level using only noninvasive inputs

The goal of this work is to present a causation modeling methodology with the ability to accurately infer blood glucose levels using a large set of highly correlated noninvasive input variables over an extended period of time. These models can provide insight to improve glucose monitoring, and glucose regulation through advanced model-based control technologies. The efficacy of this approach is demonstrated using real data from a type 2 diabetic (T2D) subject collected under free-living conditions over a period of 25 consecutive days. The model was identified and tested using eleven variables that included three food variables as well as several activity and stress variables. The model was trained using 20 days of data and validated using 5 days of data. This gave a fitted correlation coefficient of 0.70 and an average absolute error (AAE) (i.e., the average of the absolute values for the measured glucose concentration minus modeled glucose concentration) of 13.3 mg/dL for the validation data. This AAE result was significantly better than the subject’s personal glucose meter AAE of 15.3 mg/dL for replicated measurements.     

Differential Fos Expression Following Aspiration, Electrolytic, or Excitotoxic Lesions of the Perirhinal Cortex in Rats.

The authors explored the possibility that there are different neural consequences, beyond the primary site of brain damage, following perirhinal cortex (PRh) lesions made in different ways. Fos expression was used as a marker for neuronal activation and compared across the forebrains of rats that underwent the different types of surgery. Electrolytic and excitotoxic PRh lesions produced dramatic increases in Fos expression in the cortex, and excitotoxic and aspiration PRh lesions increased Fos expression in the dentate gyrus. These data are consistent with the hypothesis that different lesion methods have separable effects on neural function in regions outside the lesion site that could account for inconsistencies in the literature regarding the behavioral effects of PRh lesions on tests of spatial memory. (PsycINFO Database Record (c) 2010 APA, all rights reserved)