Analysis of solvent extracts of bituminous coal macerals by chromatography, 1H n.m.r. and field-desorption mass spectrometry

Analysis of the carbon disulphide extracts of nine samples of UK coal-maceral concentrates by ¹H highresolution n.m.r. spectroscopy, gas-liquid chromatography and field-desorption mass spectrometry indicates the presence of components with a wide molecular weight range extending up to 1200 amu; these are attributed to n-alkanes up to ≈C₅₀ and highly condensed polynuclear aromatic compounds.     

Desalination and the commons: tragedy or triumph?

A policy is more likely to be economically efficient when its costs and benefits fall on the same group, but politicians can allocate costs and benefits to different groups within their jurisdictional commons. This article examines the distribution of costs and benefits from desalination projects using examples from San Diego, Almería and Riyadh. The examples illustrate how mismatches between costs and benefits can persist or change as politicians adjust the policy portfolio to balance inefficiency and political risk.     

The effect of axial pressure gradient on extruder mixing characteristics

Many twin screw extruders are operated in the starve-fed mode with the majority of the extruder having partially-filled channels. There will always be regions of totally filled channels due to the presence of the die or reverse elements. The authors experimentally show the effect of the change of percent drag flow on the rate of distributive mixing in the co-rotating and counter-rotating twin screw extruder. Optimum operating conditions for distributive mixing are identified experimentally and verified theoretically.     

Effect of eicosa-5,8,11,14-tetraynoic acid on fatty acid composition of selected organs in the rat

Eicosa-5,8,11,14-tetraynoic acid or arachidonic acid or no supplement (controls) was given orally to rats maintained on a fat free diet and the fatty acid composition of total lipids of several organs determined. No changes were noted in the total fatty acid concentrations of the organs examined in the various groups. A decrease in the amount of arachidonic acid, 22∶4ω6 and 22∶5ω6 (as percent of total fatty acids), and an increase in the amount of 20∶3ω6 and linoleate were observed in total lipids of several organs. In the group receiving the arachidonate supplement, there was less linoleate and 20∶3ω6 and more arachidonate than in the controls. Both eicosa-5,8,11,14-tetraynoic acid and arachidonate supplements resulted in a decrease in 20∶3ω9 in most organs studied. Generally, the most marked changes were seen in liver but, of the other organs examined (heart, kidney, testis, brain, and adrenals), only the adrenals failed to show any significant differences between the controls and each of the two supplemented groups. Although the experimental conditions preclude conclusive interpretation of the changes observed, it is suggested that eicosa-5,8,11,14-tetraynoic acid was effective in inhibiting the conversion of linoleate to arachidonate and the conversion of arachidonate to 22∶4 and 22∶5.     

Tensile Stress Relaxation of Alumina at High Temperature

The development of a tensile testing methodology for ceramics which enables a stress vs strain-rate response to be measured at high temperature is described. The test involves a carefully controled stress relaxation test at constant total strain using an experimental procedure and phenomenological analysis previously developed for metallic materials. It is demonstrated here with preliminary tests on alumina at 1050° and 1150°C. This offers, with further development, the possibility of establishing design stresses associated with low strain-rate behavior for structural applications. The results demonstrate that data covering four decades of strain rate may be generated in tests lasting a few hours. The inelastic strain consists of substantial anelastic recoverable strain in addition to a permanent creep strain.     

A review of attacks and security approaches in open multi-agent systems

Open multi-agent systems (MASs) have growing popularity in the Multi-agent Systems community and are predicted to have many applications in future, as large scale distributed systems become more widespread. A major practical limitation to open MASs is security because the openness of such systems negates many traditional security solutions. In this paper we introduce and classify main attacks on open MASs. We then survey and analyse various security techniques in the literature and categorise them under prevention and detection approaches. Finally, we suggest which security technique is an appropriate countermeasure for which classes of attack.     

Endogenous Movement and Equilibrium Selection in Spatial Coordination Games

We study the effects of agent movement on equilibrium selection in network based spatial coordination games with Pareto dominant and risk dominant Nash equilibria. Our primary interest is in understanding how endogenous partner selection on networks influences equilibrium selection in games with multiple equilibria. We use agent based models and best response behaviors of agents to study our questions of interest. In general, we find that allowing agents to move and choose new game play partners greatly increases the probability of attaining the Pareto dominant Nash equilibrium in coordination games. We also find that agent diversity increases the ability of agents to attain larger payoffs on average.     

Excess Gibbs free energy and excess enthalpy for mixtures of benzene and 1,1,2-trichlorotrifluoroethane

The rapid measurement of static vapour pressures of binary liquid mixtures as a function of composition by a new continuous-dilution apparatus is described. These measurements, together with the computed excess Gibbs free energies, are reported for mixtures of benzene and 1,1,2-trichlorotrifluoroethane at 283.30, 287.83, 293.21, 298.21, 303.06 and 308.15 K over the full composition range, and are compared with the results of Linford and Hildebrand. The excess enthalpies were measured directly at 303.15 K using a batch calorimeter. The equimolar excess enthalpy is + 754 J mol^?1, which is close to the value, + 727 J mol^?1, calculated from the temperature dependence of the computed equimolar excess Gibbs free energies.     

Thermal alteration of a cyclic fatty acid produced by a flaxseed extract

Methyl 8-[2-(cis-pent-2′-enyl)-3-oxo-cis-cyclopent-4-enyl] octanoate (I) is the methyl ester of a cyclic fatty acid synthesized enzymically from an incubation of linolenic acid with an extract of flaxseed (Linum usitatissimum L.). A proposed trivial name for I is methyl 12-oxo-cis-10, 15-phytodienoate (12-oxo-PDA). The evidence presented indicated that compound I has thecis configuration of the carbon chains with respect to the cyclopentenone ring. Treatment with acid, base, or heat isomerized I to a second product (II) that has thetrans configuration of the carbon chains. Prolonged heat treatment of II yielded a third cyclic product, methyl 12-oxo-9(13),cis-15-phytodienoate (III).     

Attractive and inhibitory pheromones produced in the bark beetle,Dendroctonus brevicomis,during host colonization: Regulation of inter- and intraspecific competition

Quantities of attractive (exo-brevicomin and frontalin) and inhibitory (trans-verbenol, verbenone, and ipsdienol) pheromones were monitored in both sexes ofDendroctonus brevicomis during their colonization of a ponderosa pine. Verbenone was found in males in the greatest amounts at the time of landing, and it declined more rapidly than the other pheromones in either sex. The amounts of frontalin andexo-brevicomin in males and females, respectively, increased after initial boring within the host but began to decline after mating. The quantity oftrans-verbenol in both sexes (females had significantly more) declined more gradually thanexo-brevicomin, frontalin, and verbenone. Ipsdienol was found only in males during the initial stages of attack when encountering the resin. It is suggested that along with a general decline in all pheromonal components, a sufficient change in the ratio of the attractive pheromones to an inhibitory pheromone,trans-verbenol, may play a role in termination of aggregation.trans-Verbenol may also function along with verbenone and ipsdienol in limiting the density of attack and thus intraspecific competition. These inhibitory pheromones also appear to cause several competing species of bark beetle to avoid landing in areas infested withD. brevicomis, even when their own pheromone is present.Coleoptera:Scolytidae. These studies were supported in part by the Rockefeller Foundation, USDA Forest Service, Regional research project W-110, SEA/ USDA, and the National Science Foundation and Environmental Protection Agency through a grant (NSF GB-34719/BMS 75-04223) to the University of California.