Chloroaromatic formation in incineration processes

The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.     

Procedure for predicting settlements of thawing bases for engineering calculations

It was shown that in order to compute the settlement of thawing cohesive soil under a load in time it is necessary to experimentally determine the consolidation coefficient. A procedure is suggested for determining this coefficient, as well as use of the classical solution of a differential equation for seepage consolidation to describe the settlement of soil, thawing of which can occur according to any law.State All-Union Scientific Research Institute of Roads. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 5–7, July–August, 1993.     

A steady-state model for the rotating biological disc reactor

A steady-state model for substrate removal in a rotating biological disc reactor is presented. The model considers the consumption of substrate by micro-organisms in the biofilm attached to the rotating disc, and mass transfer from the attached liquid film to the biofilm. A mass balance on substrate over the liquid in the trough provides an expression for effluent substrate in terms of the microbial kinetic constants, the geometry of the system and the operating conditions. In order to simplify the solution of the equations in the model, first order kinetics are assumed for the rate of microbial growth and substrate utilization. This simplified model can be solved, for example, by using a programmable calculator. The model predicts that the fractional removal of substrate per stage is strongly dependent on the hydraulic loading rate per unit disc area but independent of feed substrate concentration. It predicts constant removal independent of disc size provided the hydraulic loading per unit area is kept constant. The rotational speed has only a slight predicted effect on the rate of substrate removal. The predictions of the model are compared with published data from the literature for both domestic wastewater and some industrial wastes. Trends observed in the field are predicted qualitatively by the model.     

Continuous monitoring of short term dissolved oxygen and algal dynamics

Dissolved oxygen (DO) in coastal bays with frequent algal blooms can undergo significant diurnal changes. Short-term DO and algal dynamics in a sub-tropical, nitrogen-limited, marine ecosystem are studied by means of a specially designed telemetry system. The high resolution data show clearly the importance of the vertical DO structure, and its relationship with environmental variables (solar radiation, water temperature, wind, tidal current) and phytoplankton dynamics. The design, instrumentation and calibration, and operational experience of the system are described. The simple and robust system has proved useful in (i) providing continuous data for full testing of water quality models, and (ii) the planning of field experiments to study algal dynamics.     

Indirect check of aggregate pore effects on concrete

It is very difficult to quantify aggregate pores directly in a way that allows pore/water interaction to be accurately related to hardened concrete properties. This work examines, a number of aggregates through water absorption checks and gives results of tests on some concretes made with them. Three especially relevant concrete properties are examined, initial surface absorption, freeze/thaw behaviour and drying shrinkage; it is shown that aggregate absorption is reflected in these properties.     

Effect of chlorination practice on soluble organics

As the practice of chlorination for the disinfection of waste effluents is apparently to be extended, this study was initiated to examine the possibility that chlorinated organics could be formed in the disinfection process. A group of pure compounds that had been demonstrated to be susceptible to chlorination were examined under conditions likely to apply under normal disinfection practice.From the results obtained, it appears only organics with ring structures and electron activating substituents, or amino groupings are capable of chlorination. The frequent presence of ammonia or amino groups means that chloramine formation with its asociated toxicity is likely. However, the presence of ammonia or amino groups will retard the reaction with other compounds making chlorination of these unlikely.     

Book reviews

Edge of Empire: Postcolonialism and the City. Jane M. Jacobs. London and New York, Routledge, 1996, 193 pp., £12.99 pb, ISBN 0–415–12007–1

Land for Industrial Development. David Adams, Lynne Russell & Clare Taylor‐Russell. London, E.&F.N. Spon, 1994, 289 pp., £37.50 hb, ISBN 0–419–19180–1

Urban Policy in Practice. Tim Blackman. London, Routledge, 1994, 320 pp., £14.99 pb, ISBN 0–415–09300–7

Planning, the Market and Private House‐building. G. Bramley, W. Bartlett & C. Lambert London, UCL Press, 1995, 192 pp., £11.95 pb, ISBN 1–85728–163–2

Retail Planning Policies in Western Europe. Ross Davies. London, Routledge, 1995, 304 pp., £45.00 hb, ISBN 0–415–10997–3

Transport Concepts in European Cities. Tim Pharoah & Dieter Apel. Aldershot, Avebury, 1995, 291 pp., £42.50 hb, ISBN 1–859–72094–3

Building a New Heritage: Tourism, Culture and Identity in the New Europe. G.J. Ashworth & P.J. Larkham (Eds). London, Routledge, 1994, 278 pp., hb (out of print), ISBN 0–415–07931–4

Fractal Cities: A Geometry of Form and Function. Michael Batty & Paul Longley. London, Academic Press, 1994, 394 pp., £38.00 hb, ISBN 0–124–55570–5     

Conceptual aspects of water re-use

A simplified model of a municipal water recycle system is presented and gives a clear picture of the relationship between process variables such as the intensity of the treatment, the accumulation of pollutants and the number of times the water is re-used. The model can be used to determine the necessary requirements for the treatment process in order to reach a certain desired drinking water quality. This model is extended to cover a variety of practical conditions. It is also shown that accumulation under practical conditions is limited, even if there is no treatment. The model predicts that the recycle system can utilise a low quality supplementary supply, e.g. brackish water. Although the model is derived for a recycle system for domestic water supply it can be used for any closed loop water system.