降低汽油烯烃含量裂化催化剂LBO-12的研制与开发

探讨了催化裂化过程降低汽油烯烃的反应原理，研究了催化剂各组分对裂化汽油性质影响的规律性，围绕提高氢转移活性，提出制备降烯烃裂化催化剂的技术路线，并研制开发了新型LBO-12降烯烃催化剂，固定流化床反应器对中试样品的评价和工业应用结果表明，该催化剂在不损失汽油辛烷值的前提下，降低催化裂化汽油烯烃能力较强，并具有较高的水热活性稳定性和良好的抗重金属污染特性。     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry     

Material removal and surface damage in EDM of Ti3SiC2 ceramic

Material removal and surface damage of Ti₃SiC₂ ceramic during electrical discharge machining (EDM) were investigated. Melting and decomposition were found to be the main material removal mechanisms during the machining process. Material removal rate was enhanced acceleratively with increasing discharge current, i_e, working voltage, u_i, but increased deceleratively with pulse duration, t_e. Microcracks in the surface and loose grains in the subsurface resulted from thermal shock were confirmed, and the surface damage in Ti₃SiC₂ ceramic led to a degradation of both strength and reliability.     

昆2井优快钻井及油气层保护技术

昆2井是一口位于柴北缘西段的昆特依凹陷潜伏Ⅰ号圈闭上的风险探井,设计井深为5950m。针对柴北缘深探井存在的主要技术难题,制定了昆2井的技术对策。通过对钻井设备的优选、井身结构的优化、钻头及钻具组合的优选、钻井参数及钻井液性能的优化、油气层保护技术的研究与应用,形成了一套适合于柴北缘的优快钻井技术,使昆2井的完钻井深达到5950m。与邻区的深探井平均水平相比,在井深增加888m、大尺寸井眼段更长的前提下,昆2井的钻井、完井周期分别缩短了98.75d、124.2d,钻机月速度增加了317m/台,平均机械钻速增加了0.82m/h。根据“理想充填新理论”,确定了保护油气层的最优复配暂堵方案,利用该方案所配制的钻井液其渗透率恢复值达到了87.5%以上,流变性能良好,滤失量低,对改善泥饼质量、增强井壁稳定性有明显的效果。     

小红楼

小红楼建于1921年，是一座三层的法式小洋楼。三十年代，它被英国百代唱片公司收购，抗日战争期间，一度被日本人占有，解放后，它成为中国唱片公司的所在地，伟大的中国国歌就诞生在这里。     

Synthesis,characterization, and redox and electrochromic behaviors of poly(3-n-octyloxythiophene)

Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

扫描近场光学显微镜及其在生物微结构探测上的应用

扫描近场光学显微镜（ＳＮＯＭ）可探测生物体亚波长水平的光学特性，以接近分子水平的分辨率在生物微结构成象、探测和修饰等多方面有巨大的潜力。本文对ＳＮＯＭ的技术方法及其近期的的生物学应用进行了介绍。     

双机同轴拖动系统扭转振动分析

介绍了两台柴油机同轴拖动一台发电机轴系扭转振动的特点，以6000kW柴油发电机组为实例，计算分析了两台柴油机的列间发火间隔角，联接相位角、功率不平衡对轴系扭转振动的影响。     

Optically tuned superconductive-dielectric resonators with whispering-gallery modes

An analytical method is presented for calculating the resonant frequency andQ-factor of a superconducting dielectric disk resonator operating in millimeter-wave regime with whispering-gallery mode. Resonant frequency shift due to the optical generation of quasi-particles in superconducting film is investigated as a function of photon flux. An optically tunable resonant frequency of about 500 MHz is estimated, and good agreement is found between numerical results and experimental ones.     

Cr/SiO_2界面还原反应研究

利用俄歇电子能谱研究了Cr／SiO2薄膜在热处理过程中的界面扩散反应机理、界面反应动力学过程及界面反应产物。研究结果表明，Cr／SiO2体系的界面还原反应主要是Cr与SiO2的反应，其还原反应产物是CrSix和Cr2O3物种。界面还原反应的速度与反应时间的平方根成正比，其界面还原反应过程受Cr向SiO2层的扩散过程所控制，界面还原反应的表观活化能为72．5kJ／mol（约0．75eV）。