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31.
Production-integrated environmental protection – Utilization of residues . Chemical plants as well as coal-fired powerstations utilize chemical reactions in order to produce materials or energy. Most of these reactions additionally produce gaseous, liquid, or solid residues. It is the main objective of production-integrated environmental protection to use these residues as suitable feedstocks in order to reduce environmental pollution and lower the consumption of raw materials. Several examples from the BASF Group will show how, by crossing the borders of the respective plant, reasonable solutions for material, or at least energetic, utilization of residues can be achieved. As a result of permanent efforts in production-integrated environmental protection over many years and despite increasing outputs the emissions of the chemical industry have been continuously reduced. 相似文献
32.
Summary: This paper describes a step on the ambitious aim to “design” application properties of ldPE by first simulating the detailed molecular structure of a high‐pressure tubular reactor product. The reactor of a certain configuration produces under well‐defined operating conditions. The next step is to correlate the structure with the application properties. Finally, the sequence will be reversed in order to deduce the operating conditions, which lead to the desired product quality. Two‐dimensional distributions, in molecular weight and branching frequency, as well a two compartment models with a core and a shell stream were simulated and compared with experimental results. Therefore, CFD simulations were carried out to discretize the reaction medium. Samples were taken from both pilot and commercial plants. The TREF‐SEC analytical method was successfully applied in order to measure the microscopic structure of the material. The tremendous numerical problems were solved with the help of the software PREDICI .
33.
Helen E. Hermes Henrich Frielinghaus Wim Pyckhout-Hintzen Dieter Richter 《Polymer》2006,47(6):2147-2155
A new model is presented which can describe quantitatively the small angle neutron scattering from montmorillonite-type clay dispersions and polymer-clay nanocomposites. The model is shown to be able to describe well the data from a series of dilute montmorillonite in water dispersions in which the deuterium content of the water phase is varied. The fits combined with information from other techniques suggest strongly that H-D exchange occurs in the montmorillonite-water dispersions. Deviations from Q−2 behaviour often observed experimentally for clay dispersions are convincingly explained by the presence of a small proportion of tactoids. 相似文献
34.
Summary: Non‐Newtonian fluid behavior has significant influence on quantities in chemical engineering like power input, mixing time, heat transfer etc. In the laminar flow region, the concept of effective viscosity by Metzner and Otto is well established. In the transition region between laminar and turbulent flow, the existing concepts use three and even more empirical parameters to determine the specific power input. Here, a unified and general but simple approach is introduced to calculate the power input for shear thinning fluids over the whole flow region using just one empirical parameter. The Metzner‐Otto relation is obtained as a limiting case for the laminar region. The empirical parameter of the new approach is related to the Metzner‐Otto constant. The concept is validated for eight different stirrer systems. Mixing time and maximum shear rate and heat transfer can also be calculated using this approach. The new concept presented should also be applicable for other apparatuses, e.g., static mixers.
35.
Dieter Heymann 《Carbon》2005,43(11):2235-2242
The mean lifetimes of polyyne C8H2 in hexane were determined at 50, 60, 80, and 100 °C and in methanol at 60 °C. The reactions are second order at all temperatures: ln k2 = 20.5 ± 1.5-10303 ± 520T−1 and the corresponding activation energy is 85.7 ± 6.3 kJ mol−1 (7164 cm−1). Extrapolation suggests that solutions at 1 mM concentration are significantly unstable at room temperature. Quantum chemical calculations show that polyynes CmH2 + CnH2 (m + n = 16) could be products, but these were not detected. Alternatively, C16H2 isomers could form. IR spectra of the solid residues from hexane and methanol solutions were obtained. 相似文献
36.
Dieter Birnbacher 《Ethik in der Medizin》2016,28(4):283-294
Definition of the problem
Advance directives for later states of grave cognitive impairment that are typical for late stages of dementia meet with more far-reaching reservations than advance directives for other states of reduced competence. One of the reasons seems to lie in the ethical and psychological conflicts arising from advance directives demanding nontreatment of additional diseases or the abstention from artificial nutrition in situations in which patients show no signs of suffering from their condition.Arguments
In this article, it is argued that a “mixed” ethical strategy be used for these cases.Conclusion
Advance directives in the legally defined sense, especially if drawn up in a process of advance care planning, should be followed in order to avoid that advance directives as an instrument of patient autonomy are rendered futile to a degree incompatible with confidence that wishes for terminating medical treatment will be followed. In contrast, the authority of “care directives” without recognized legal status should be restricted to cases in which there is concordance between the patient’s will as expressed in the directive and the patient’s “natural” will in the relevant situation.37.
38.
Jonathan P. Caulkins Dieter Grass Gustav Feichtinger Gernot Tragler 《Computers & Operations Research》2008
This paper deals dynamically with the question of how recruitment to terror organizations is influenced by counter-terror operations. This is done within an optimal control model, where the key state is the (relative) number of terrorists and the key controls are two types of counter-terror tactics, one (“water”) that does not and one (“fire”) that does provoke recruitment of new terrorists. The model is nonlinear and does not admit analytical solutions, but an efficient numerical implementation of Pontryagin's minimum principle allows for solution with base case parameters and considerable sensitivity analysis. Generally, this model yields two different steady states, one where the terror organization is nearly eradicated and one with a high number of terrorists. Whereas water strategies are used at almost any time, it can be optimal not to use fire strategies if the number of terrorists is below a certain threshold. 相似文献
39.
Haoqiang Jin Barbara Chapman Lei Huang Dieter an Mey Thomas Reichstein 《International journal of parallel programming》2008,36(3):312-325
We describe a performance study of a multi-zone application benchmark implemented in several OpenMP approaches that exploit
multi-level parallelism and deal with unbalanced workload. The multi-zone application was derived from the well-known NAS
Parallel Benchmarks (NPB) suite that involves flow solvers on collections of loosely coupled discretization meshes. Parallel
versions of this application have been developed using the Subteam concept and Workqueuing model as extensions to the current
OpenMP. We examine the performance impact of these extensions to OpenMP and compare with hybrid and nested OpenMP approaches
on several large parallel systems. 相似文献
40.
Dieter Eckhartt 《Journal of Fusion Energy》1995,14(4):329-341
In searching to attain optimum conditions for the controlled release of nuclear energy by fusion processes, the stationary confinement of low-pressure ring-shaped plasmas by strong magnetic fields is now regarded as the most promising approach. We consider a number of fuel combinations that could be operated in such low-beta reactor systems and look upon the relevant fuel reserves. The classical D-T-Li cycle will be used as a standard and is extensively discussed therefore. It could supply most of mankind's future long-term power needs—but only on condition that the required lithium fuel can be extracted from seawater at reasonable expenses. The estimated landbound lithium reserves are too small to that end, they will last for about 500 years at most, depending on forecasts of future energy consumption and on assumptions about exploitable resources. Recovery of lithium from seawater would extend the possible range by a factor of 300 or so, provided that extraction technologies which are at present available in the laboratory, could be extended to a very large and industrial scale. Deuterium is abundant on earth but D-D fusion is difficult, if not impossible, to be achieved in the low-beta systems presently investigated for D-T fusion. The same arguments apply to so-called advanced concepts, such as the D-3He and the D-6Li cycles. 相似文献