Ice templating of ZrB2 porous architectures

For the first time, freeze casting of aqueous ZrB₂ based suspension was performed in order to produce porous architectures with main unidirectional anisotropic pores interconnected by diffuse globular-isotropic pores. The porosity characterizing the green bodies after the sublimation process is the replica of the ice crystals. The effects of solid content, suspension stabilization and cold transmission depending on mold type were studied since micro and macrostructure and, hence, the properties of the sintered body are determined by controlling the growth direction of the ice crystals during freezing. Improved mechanical performances are obtained by changing the above mentioned parameters, in virtue of the formation of thinner and more homogenously distributed ceramic lamellae. Possible applications of these materials include high temperature porous volumetric absorbers for concentrating solar power systems.     

Oxidation behaviour of a pressureless sintered HfB2–MoSi2 composite

The thermal stability of a 80-vol.% HfB₂ + 20 vol.% MoSi₂ composite is tested under oxidizing environment. Oxidation tests are carried out in flowing synthetic air in a TG equipment from 1000 to 1400 °C with exposure time of 30 h. At temperatures ≥1200 °C the silica resulting from oxidation of molybdenum disilicide seals the sample surface, preventing hafnium diboride from fast degradation. Analysis of the kinetics is carried out through fitting of the thermogravimetric curves. Between 1200 and 1400 °C, the kinetic curves deviate from a parabolic behaviour, being more close to a logarithmic–parabolic behaviour.     

Fair Π

In this paper, we define fair computations in the π-calculus [Milner, R., Parrow, J. & Walker, D., A Calculus of Mobile Processes, Part I and II, Information and Computation 100 (1992) 1–78]. We follow Costa and Stirling's approach for CCS-like languages [Costa, G. & Stirling, C., A Fair Calculus of Communicating Systems, Acta Informatica 21 (1984) 417–441, Costa, G. & Stirling, C., Weak and Strong Fairness in CCS, Information and Computation 73 (1987) 207–244] but exploit a more natural labeling method of process actions to filter out unfair process executions. The new labeling allows us to prove all the significant properties of the original one, such as unicity, persistence and disappearance of labels. It also turns out that the labeled π-calculus is a conservative extension of the standard one. We contrast the existing fair testing [Brinksma, E., Rensink, A. & Vogler, W., Fair Testing, Proc. of CONCUR'95, LNCS, 962 (1995) 313–327, Natarajan, V. & Cleaveland, R., Divergence and Fair Testing, Proc. of ICALP '95, LNCS, 944 (1995) 648–659] with those that naturally arise by imposing weak and strong fairness as defined by Costa and Stirling. This comparison provides the expressiveness of the various fair testing-based semantics and emphasizes the discriminating power of the one already proposed in the literature.     

Dry Sliding Wear Behavior of Al2O3–SiC Submicro- and Nano-Composites

The wear behavior of a pure alumina matrix and two Al₂O₃-based composites, one with 5 vol% SiC nanosized particles (mean size 52 nm) and the other with 5 vol% SiC sub-microsized particles (mean size 230 nm), was studied in two different experimental conditions corresponding to mild and severe wear regime, respectively. Whether considering the friction or the wear resistance, in the mild regime no difference was observed among the materials. In the severe regime, the composites performed much better than the matrix alone due to stronger grain boundaries. The SiC particle size had no influence on the mean wear resistance.     

Spark plasma sintering of ultra refractory compounds

Spark plasma sintering experiments were conducted on Zr- and Hf-based borides and carbides with the addition of 1, 3, and 9 vol% MoSi₂ as sintering aid. For comparison, as-received ZrC, HfC, ZrB₂, HfB₂ powders were also sintered. The microstructural features were investigated by means of scanning electron microscop–energy dispersive spectroscopy technique. Silicon carbide was detected in all the doped compositions along with significant amounts of oxide species (Hf/ZrO₂, and SiO₂). The effect of the MoSi₂ content on densification, microstructure, and mechanical properties is analyzed.