Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

试论科技发展中的伦理向度

对于科技发展带来的一些消极影响,有人认为伦理的干预是无济于事的,甚至最终会影响科技本身的发展。但是,现实中科技与社会发展之间的密切关系表明,对科技的发展给予伦理导向是社会发展的必然走向。把科学发展观作为科技发展的伦理向度,能够实现科技发展和社会进步两者的双赢。     

鲍曼的知识分子角色危机论浅析

介绍了齐格蒙特·鲍曼时知识分子的立法者角色危机的论述.知识分子曾经的立法者角色为国家统治提供了合法化的依据,而其立法者地位的丧失是因为国家不再需要他们为统治提供合法化的依据.     

女性博客：公共领域的性别再塑或重塑

传播学的受众分类为女性博客提供了一个存在的界定,然而,这一明显为女性定制的公共领域空间中,女性的自主性别形象塑造是否具有网络的充分自主与自由？是对传统媒体女性刻板印象的再塑,还是对其的重复与巩固？笔者拟就此进行调研基础上的分析。     

多途信道中声屏蔽及声聚焦

针对传统阵处理无法分辨同一方向上2个点源的缺陷,提出了多途信道中声屏蔽技术.将声屏蔽技术应用于抗拖船干扰,把拖曳线列阵接收的拖船干扰和同方向的目标信号在频域通过一个屏蔽、聚焦权滤波器,在对干扰屏蔽的同时,对目标聚焦.仿真结果表明,干扰源的辐射噪声被显著抑制,而所期望的目标信号清晰可见,其输出相干信噪比大幅度提高,该技术在抑制拖船干扰的同时可以有效消除在该方向的探测盲区.     

风机冷风保安控制系统优化

介绍菜钢型钢AV80风机冷风保安控制系统的优化改造,以增加其控制安全性及可靠性.     

不同线密度粘胶原丝及其碳纤维的结构性能对比

用Weibull分析处理 10mm长的 4种不同线密度粘胶原丝和相应碳纤维的单丝断裂强度 ,得到原丝线密度、强度分布和碳纤维强度的对应关系。采用透射电镜 (TEM )和小角X散射 (SAXS)分析粗旦原丝 ,发现孔洞较多 ,并存在大于 70nm的大孔洞。截面和表面照片也揭示出细旦原丝截面相对规整 ,表面较光滑 ,粗旦原丝则反之。结果表明 ,原丝线密度小 ,截面形状圆整 ,缺陷少 ,所制得的碳纤维强度高。     

An SVD-based adaptive robust speech steganography using MDCT coefficient

Multimedia Tools and Applications - Speech is one of the essential ways of communication. The study of speech steganography provides great value in information security. To improve imperceptibility...