Synthesis of crystalline metal nitride and metal carbide nanostructures by sol–gel chemistry

Attention toward nanosized metal nitrides and carbides is rapidly increasing thanks to their chemical characteristics that make them as valid and sustainable alternatives to noble metals in catalysis and to air-sensitive metals or oxides for applications under harsh conditions. They are mostly used as bulk phase or micron sized powders, due to an intrinsic difficulty to synthesize them as nanoparticles in a systematic and scalable fashion. However, nanosized metal nitrides and carbides could exhibit improved performances, e.g. in catalysis due to a higher surface area, and can be shaped more easily than corresponding larger grains for further specific applications. Recently, sol–gel chemistry has closed this gap and now enables the simple, cheap, and sustainable production of metal nitride and carbide nanoparticles.In the present review we give an overview on recent sol–gel based pathways for the synthesis of metal nitride and carbide nanoparticles, believing that a better knowledge of the potentialities of these still hardly touched materials stimulates research interest and applications.     

Comparison of different failure criteria for fiber-reinforced plastics in terms of fracture curves for arbitrary stress combinations

For fiber-reinforced plastics exists a big number of different criteria for the failure prediction. The intention of this paper is to compare the TSAI-HIL-, the LaRC04- and PUCK’s criterion in terms of their fracture curves for a unidirectional glass-fiber reinforced composite layer. Therefore after the implementation of these three criteria, the two-dimensional fracture curves for all possible stress combinations, which can be derived from a general spatial stress tensor, are computed. In this way, the characteristics of the criteria, similarities and differences and possible weak points become obvious.     

Multiscale Nanoparticle Assembly: From Particulate Precise Manufacturing to Colloidal Processing

Nanoparticle assembly and colloidal processing are two techniques with the goal to fabricate materials and devices from preformed particles. While colloidal processing has become an integral part of ceramic processing, nanoparticle assembly is still mainly limited to academic interests. It typically starts with the precise synthesis of building blocks, which are generally not only considerably smaller than those used for colloidal processing, but also better defined in terms of size, shape, and size distribution. Their arrangement into 1D, 2D, and 3D architectures is performed with great accuracy well beyond what is achieved by colloidal processing. At the same time, the final assembly is not sintered such that the intrinsic, nanospecific properties of the initial building blocks are preserved or even lead to collective behavior. However, in contrast to colloidal processing the structures accessible by nanoparticle assembly are often limited to a small length scale. The review presents selected examples of nanoparticle assembly and colloidal processing with the goal to reveal the capabilities of these two techniques to fabricate novel materials from preformed building blocks, and also to demonstrate the immense opportunities that would arise if the two methods could be combined with each other.     

50 Jahre Kybernetik in Österreich

The term “cybernetics” is very old, but in the middle of the last century it gained new importance as steering brought new aspects to the area of information technology. This paper deals with the general history of cybernetics and then describes the beginning of this field at Vienna University of Technology. In this context it was an important step, when the book “Cybernetics” by Norbert Wiener first came to Vienna; thus the interest in cybernetic models evolved. Originating from the interest in cybernetic models, three models were recreated (and refined):

1. the model of the conditioned reflex (artificial tortoise),
2. the model of orientation in a maze (mouse), and
3. the model of homeostasis (homeostat).

The third and final part of this paper illustrates the gradual transition to artificial intelligence (AI). Hopes that were tied up with this term are discussed. Apart from that the question of how much has been left of cybernetics and artificial intelligence today is raised. The mouse in the maze is very closely connected to our Emeritus: He built the Viennese version of it as part of his diploma thesis.     

Cryptanalysis of the Tillich�CZ��mor Hash Function

At CRYPTO ’94, Tillich and Zémor proposed a family of hash functions, based on computing a suitable matrix product in groups of the form SL₂(\mathbbF_2ⁿ)SL_{2}(\mathbb{F}_{2^{n}}). We show how to construct collisions between palindromic bit strings of length 2n+2 for Tillich and Zémor’s construction. The approach also yields collisions for related proposals by Petit et al. from ICECS ’08 and CT-RSA ’09.     

Switched beams versus beam pointing for boosting the downlink capacity of UMTS FDD

In this paper the switched beam method is compared with beam pointing. Using extensive system simulations it is shown that both methods achieve a capacity gain over a 3-sectored reference system of more than 170%. As the capacity achieved with the two systems is nearly the same but the complexity of beam pointing is significantly higher, I conclude that switched beams are the appropriate method for boosting the downlink capacity of UMTS FDD.     

Characterization and Modeling of Broad Spectrum InAs–GaAs Quantum-Dot Superluminescent Diodes Emitting at 1.2–1.3 μm

High-power broadband superluminescent diodes (SLDs) emitting in the 1.2-1.3-mum region are demonstrated using InAs-GaAs quantum dots (QDs). The highest output powers of ~30-50 mW are achieved using 18 QD layers with p-doped GaAs spacers. At these high powers the device operates in a regime of broad bandwidth (~100 nm) with a spectral dip of ~5 dB between two separate peaks originated by the QD ground and excited states. Spectral calculations performed with a traveling-wave rate equation model show excellent agreement with the experimental data and provide design rules for optimizing the output spectrum. SLD characteristics are presented for two different device structures consisting of tilted and bent waveguides. The latter allows the achievement of higher output powers at lower currents. The coherence properties and the temperature characteristics are also discussed in detail.