Influence of organic carbon decomposition on calcite dissolution in surficial sediments of a freshwater lake

A multi-sensor approach was used to determine high-resolution porewater gradients of Ca(2+), CO(3)(2-), H(+) and O(2) in sediment cores along a depth transect from eutrophic Lake Sempach (Switzerland). We quantified the reproducibility of measurements and analyzed concentration profiles with a one-dimensional diffusion-reaction model to quantify benthic fluxes. Calculation of oxic respiration in the sediment showed that almost all settled organic carbon was degraded with O(2) at shallow depths while only 28% was decomposed aerobically at the deepest location. Fluxes were highest at 8 m depth (24.4 mM m(-2) d(-1)) and lowest at the deepest site of 85 m (7.1 mM m(-2) d(-1)). Dissolution of calcite from the sediment was also depth dependent. A total of 1.1 mM m(-2) d(-1) was found for the shallowest site, and values decreased with depth to 0.6 mM m(-2) d(-1) at the deepest site.     

Hydration of Portland cement with high replacement by siliceous fly ash

The effects of two different low calcium fly ashes on the hydration of ordinary Portland cement (OPC) pastes containing 50 wt.% of fly ash were investigated over a hydration time of 550 days. The results were compared with a reference blend of OPC containing 50 wt.% of inert quartz powder allowing the distinction between "filler effect" and pozzolanic reaction.Until 2 days, no evidence of fly ash reaction was measured and its influence on the hydration is mainly related to the “filler effect”. From 7 days on, the effects of the pozzolanic reaction were observed by the consumption of portlandite, the change of the pore solution chemistry, the formation of a presumably water-rich inner hydration product and the change of the C–S–H composition towards higher Al/Si ratio compared to the C–S–H of neat OPC. Additional strength due to the pozzolanic reaction developed after 28 days of hydration.     

Mucoadhesive plasticized system of branched poly(lactic-co-glycolic acid) with aciclovir

Commercially available antibacterial semisolid preparations intended for topical application provide only short-term drug release. A sustained kinetics is possible by exploitation of a biodegradable polymer carrier. The purpose of this work is to formulate a mucoadhesive system with aciclovir (ACV) based on a solid molecular dispersion of this drug in poly(lactic-co-glycolic acid) branched on tripenterythritol (PLGA/T). The ACV incorporation into PLGA/T was carried out either by solvent method, or melting method, or plasticization method using various plasticizers. The drug–polymer miscibility, plasticizer efficiency and content of residual solvent were found out employing DSC. Viscosity was measured at the shear rate range from 0.10 to 10.00?s^?1 at three temperatures and data were analyzed by Newtonian model. The mucoadhesive properties were ascertained in the tensile test on a mucin substrate. The amount of ACV released was carried out in a wash-off dissolution test. The DSC results indicate a transformation of crystalline form of ACV into an amorphous dissolved in branched polyester carrier, and absence of methyl formate residuals in formulation. All the tested plasticizers are efficient at T_g depression and viscosity decrease. The non-conventional ethyl pyruvate possessing supportive anti-inflammatory activity was evaluated as the most suitable plasticizer. The ACV release was strongly dependent on the ethyl pyruvate concentration and lasted from 1 to 10 days. The formulated PLGA/T system with ACV exhibits increased adhesion to mucosal hydrophilic surfaces and prolonged ACV release controllable by degradation process and viscosity parameters.     

Autonomous Vision-Based Helicopter Flights Through Obstacle Gates

The challenge for unmanned aerial vehicles to sense and avoid obstacles becomes even harder if narrow passages have to be crossed. An approach to solve a mission scenario that tackles the problem of such narrow passages is presented here. The task is to fly an unmanned helicopter autonomously through a course with gates that are only slightly larger than the vehicle itself. A camera is installed on the vehicle to detect the gates. Using vehicle localization data from a navigation solution, camera alignment and global gate positions are estimated simultaneously. The presented algorithm calculates the desired target waypoints to fly through the gates. Furthermore, the paper presents a mission execution plan that instructs the vehicle to search for a gate, to fly through it after successful detection, and to search for a proceeding one. All algorithms are designed to run onboard the vehicle so that no interaction with the ground control station is necessary, making the vehicle completely autonomous. To develop and optimize algorithms, and to prove the correctness and accuracy of vision-based gate detection under real operational conditions, gate positions are searched in images taken from manual helicopter flights. Afterwards, the integration of visual sensing and mission control is proven. The paper presents results from full autonomous flight where the helicopter searches and flies through a gate without operator actions.