Impact of traffic localization on communication rates in ad-hoc networks

The effect of traffic distribution on communication rates and receiver complexity in ad-hoc networks is addressed, considering a network with constant density of users and a certain traffic model. Information theoretic upper bounds on communication rates are derived under an assumption that transmitting nodes as well as receiving nodes cooperate. It is shown that for the case of large signal attenuation the bounds hold even when the cooperation among users is limited to a certain region of the network domain. Furthermore, achievability bounds on communication rates are derived. The bounds rely on two proposed local cooperation strategies. A comparison shows that the upper bounds are tight and closely follow the achievability results. Finally, the impact of traffic localization on the receiver complexity is addressed.     

APPLICATION OF EXTRACTION AND ION EXCHANGE CHROMATOGRAPHIC TECHNIQUES FOR THE SEPARATION OF METAL ION MIXTURES: PROBLEMS AND PERSPECTIVES

ABSTRACT

This paper describes new perspectives for the development and wider application of extraction and ion-exchange chromatography for separation of metal ion mixtures. The stabilization of extraction chromatographic materials by different techniques, the evaluation of changes in the behaviour of immobilized reagents (extractants or water-soluble ligands) as compared to those in their “free” state, and the combination of extraction and ion-exchange within one fractionation technique are considered and discussed along with some related problems.     

Development of novel metallic glass/polymer composite materials by microwave heating in a separated H-field

Using a single mode 915 MHz applicator, we fabricate novel Cu₅₀Zr₄₅Al₅ metallic glass/polyphenylene sulfide (PPS) composites with high relative densities by microwave processing the constituents in a separated H-field with an applied pressure of about 5 MPa. The heating behaviors and structural changes of the composites have been investigated. A good bonding state between metallic glassy and PPS particles is found. The gradient structure is also induced by microwave heating of the composites with a high fraction of PPS phase.     

Thermodynamic calculation of phase equilibria of the Bi-Sn-Zn system

A thermodynamic assessment of the Bi-Sn-Zn ternary system was carried out by considering the experimental data including the phase equilibria and thermodynamic properties on the basis of the CALPHAD method. A set of optimized thermodynamic parameters has been obtained, which leads to a very good fit between calculation and experiments. In particular, the thermodynamic calculations in the Sn-rich portion are presented in view of the recent progress in Pb-free solder alloys.     

Low-energy electron elastic scattering cross sections for excited Au and Pt atoms

Electron elastic total cross sections (TCSs) and differential cross sections (DCSs) in both impact energy and scattering angle for the excited Au and Pt atoms are calculated in the electron impact energy range 0 ? E ? 4.0 eV. The cross sections are found to be characterized by very sharp long-lived resonances whose positions are identified with the binding energies of the excited anions formed during the collisions. The recent novel Regge-pole methodology wherein is embedded through the Mulholland formula the electron-electron correlations is used together with a Thomas-Fermi type potential incorporating the crucial core-polarization interaction for the calculations of the TCSs. The DCSs are evaluated using a partial wave expansion. The Ramsauer-Townsend minima, the shape resonances and the binding energies of the excited Au⁻ and Pt⁻ anions are extracted from the cross sections, while the critical minima are determined from the DCSs.     

Oxidative dehydrogenation of propane over monoliths at short contact times

A specially designed tubular microreactor with independent control of feed preheat as well as catalyst temperature and allowing to rapidly quench reaction products was used to test performance of supported Pt-based monolithic catalysts in the reaction of propane oxidative dehydrogenation at short contact times. To minimize the impact of undesired homogeneous reactions capable of decreasing propylene selectivity, proprietary straight-channel thin-wall high cell density corundum micromonoliths were chosen as supports. Catalytic properties of supported platinum were modified by using promoters known as dehydrogenation catalysts (tin, zinc aluminate spinel, transition metal pyrophosphates) as well as by tuning reaction mixture composition (propane/oxygen ratio, water and hydrogen content). In the operation temperature range up to 900°C with contact times 0.03–0.1 s, ethylene/propylene selectivities were found to strongly depend upon the chemical composition of the active component and type of feed. The results thus obtained demonstrate that for Pt-based catalysts, propylene yield can be substantially improved by suppressing secondary reactions of deep oxidation and cracking.     

Clustered crystalline structures as glassy phase approximants

This paper presents some crystalline structures which can be taken as the approximants of the corresponding metallic glassy phases. Such phases have a clustered structure and preferably (but not strictly necessarily) a large unit cell. Peak intensities of their radial distribution functions (RDFs) must be integrated at a step of about 0.01 nm in order to obtain RDFs similar to those of the corresponding glassy alloys owing to a degree of disorder related to the corresponding glassy structures.     

The effect of Fe on magnetic moment of electrodeposited CoFe alloys—Experimental study and analytical model

The effect of Fe³⁺ concentration on saturation magnetic flux density (B_s) of electrodeposited Co_40-44Fe_60-56 films was investigated. The results show that if the conditions at the electrochemical interface for nucleation/precipitation of iron(III) hydroxide (Fe(OH)₃) are reached, the B_s of electrodeposited Co_40-44Fe_60-56 films quickly decreases as a result of the Fe(OH)₃ incorporation into deposit. These conditions are discussed as a function of the solution formulation (pH) and the parameters of electrodeposition process (current density, current efficiency, diffusion layer thickness) and a simple analytical model is developed qualitatively describing the hydroxide incorporation phenomenon and resulting decrease in B_s of Co_40-44Fe_60-56 films.