The stability of fixed bed catalytic reactors

A proper control design for safe and economic operation of industrial catalytic reactors requires a detailed study of transient and steady state behaviour. The present paper discusses contributions in this area with an emphasis on the stability problem. In addition, an attempt has been made to relate the stability of a fixed bed catalytic reactor to that of individual catalyst particles. Sufficient conditions for local stability of a two-dimensional and a one dimensional model for the reactor are obtained using the extension of Lyapunov stability theory to distributed parameter systems. For the two-dimensional model, the sufficient conditions are in the form of inequalities which require steady-state information. For the one dimensional model, the reactor is locally stable if and only if the slope of the heat removal line is greater than the slope of the heat generation curve at the steady state for small perturbations in temperature and concentration.     

A kinetic model for the hydrochloric acid leaching of kaolinite clay in the presence of fluoride ions

The dissolution of kaolinite clay in hydrochloric acid solutions has been carried out in the presence of fluoride ions. Leaching in the presence of fluoride ions activates the clay for leaching, making higher extractions possible at lower roasting and leaching temperatures. The activation energy for the leaching of clay calcined at 540°C is decreased from 71 kJ/mol to 23 kJ/mol in the presence of fluoride ions. Dissolution in the presence of fluoride appears to fit a second-order reaction mechanism.     

Evaluation of malonanilides as new stabilizers for double-base propellants

Five malonanilide derivatives (M1-M5) were prepared by the reaction of ethyl malonate with aniline derivatives. These compounds were investigated as new stabilizers for double-base propellants (DBPs). The evaluation process has been performed through thermal stability tests, thermal analyses measurements (TGA and DSC) and kinetic parameters calculations (E(a)). The results of the new stabilizers were compared with the results of the classical stabilizer N, N-diethyldiphenyl urea. It has been found that o- and p-dinitromalonanilides, in particular, showed better stability effect for DBPs than the classical one.     

Accuracy and convergence of a finite element algorithm for laminar boundary layer flow

The Galerkin-weighted residuals formulation is employed to derive an implicit finite element solution algorithm for a generally non-linear initial-boundary value problem. Solution accuracy and convergence with discretization refinement are quantized in several error norms, for the non-linear parabolic partial differential equation system governing laminar boundary layer flow, using linear, quadratic and cubic functions. Richardson extrapolation is used to isolate integration truncation error in all norms, and Newton iteration is employed for all equation solutions performed in double-precision. The mathematical theory supporting accuracy and convergence concepts for linear elliptic equation appears extensible to the non-linear equations characteristic of laminar boundary layer flow.     

Synthesis and structure study of copolymers from thiadiazole fused indolocarbazole and dithienosilole

We report synthesis and characterization of two D-A polymers (PSDT-C12 and PSDT-EH) with different side chains. Both polymers are based on alternate 12,13-dioctyl-indolo[2,3-a][1,2,5]thiadiazolo[3,4-c]carbazole (TDZIC) and dithienosilole derivative units in polymer main chain. We used TDZIC to enlarge the 2D conjugated plane of acceptor monomers by fusing benzothiadiazole (BT) unit with an indole unit having alkyl groups. PSDT-C12 exhibited 10 nm redshift compared to PSDT-EH in solid films, while their absorption spectra were almost identical in solutions. Since the backbone and side chains on the indolocarbazole group are the same, the redshift on PSDT-C12 could be resulted from the dodecyl (C12) side chain on the dithienosilole unit and different molecular weight between these two polymers. PSDT-C12 has a larger molecular weight than PSDT-EH. Therefore possibly both side chains and molecular weight contributed to the difference in the absorption spectra in solid films. The straight C-12 side chain has less steric hindrance than the branched EH side chain in solid films. PSDT-C12 has a longer main chain (larger molecule weight) than PSDT-EH, which can favour a more extended main chain interaction. The vibronic peak at 519 nm and shoulder at 563 nm in the PSDT-C12 film further confirmed stronger main chain interaction. Geometry optimization showed that head–tail (HT)-PSDT had a more twisting conjugated backbone with larger dihedral angle between dithienosilole unit and thiadiazole-fused ring compared to head–head/tail–tail (HH/TT)-PSDT.     

Stress analysis of multi-layer electronic and mechanical systems (MEMS) under fatigue and impact loading conditions

Detailed micro electronic and mechanical systems (MEMS) for a mobile microprocessor complex shape were modeled using Finite Element (FE) processing. Fatigue and impact conditions were performed on the Ball Grid Array (BGA) Integrated Circuit (IC) using AbaqusCAE finite element analysis software. The main objective of this research is to make sure that BGA products can endure the roughness of the daily usage, where a portable electronic product is habitually coupled with potential damage of functional failure when the device falls.     

Fractional‐order mutual inductance: analysis and design

This paper introduces for the first time the generalized concept of the mutual inductance in the fractional‐order domain where the symmetrical and unsymmetrical behaviors of the fractional‐order mutual inductance are studied. To use the fractional mutual inductance in circuit design and simulation, an equivalent circuit is presented with its different conditions of operation. Also, simulations for the impedance matrix parameters of the fractional mutual inductance equivalent circuit using Advanced Design System and MATLAB are illustrated. The Advanced Design System and MATLAB simulations of the double‐tuned filter based on the fractional mutual inductance are discussed. A great matching between the numerical analysis and the circuit simulation appears, which confirms the reliability of the concept of the fractional mutual inductance. Also, the analysis of the impedance matching using the fractional‐order mutual inductance is introduced. Copyright © 2015 John Wiley & Sons, Ltd.     

Digitally programmable second generation current conveyor‐based FPAA

A novel fully differential digitally programmable current conveyor (DPCCII) is presented in this paper. The programmability of the proposed DPCCII is achieved using three‐bit MOS R‐2R ladder current division network. The DPCCII is used to realize a field programmable analog array (FPAA). The FPAA consists of seven configurable analog blocks arranged in a hexagonal form. The FPAA power consumption is 72.3 mW from 1 V voltage supply. A second‐order programmable universal filter is realized using the proposed FPAA as an application. All the circuits are realized and simulated using 90 nm IBM CMOS technology model under balanced supply voltage of ±0.5 V. Copyright © 2012 John Wiley & Sons, Ltd.     

Dynamic Tracking of The Steady State Power System Magnitude and Frequency Using Linear Kalman Filter a Variable Frequency Model

ABSTRACT

This paper presents the application of Kalman Filtering algorithm for tracking the power system voltage magnitude, the rate of change of the frequency, the frequency deviation as well as the voltage phase angle, when the the frequency of the voltage signal varies linearly with the time during the data window size. The proposed algorithm uses the digitized samples of the voltage signal at the relay location. Effects of sampling rate, data window size and the harmonics contaminating the voltage signal on the performance of the algorithm are studied. Furthermore, effects of the noise level are also investigated. A sample of the results obtained is reported in this paper.     

Realizations of fully differential voltage second generation current conveyor with an application

Three novel CMOS realizations for the fully differential voltage second‐generation inverting current conveyor (FDVCCII‐) are proposed in this paper. The first realization has a limited input range, and the other two realizations have a rail to rail input range and show excellent features in linearity and bandwidth. As an application to the FDVCCII‐, a floating gyrator is proposed. A floating inductor is realized using the floating gyrator and it is used in realizing a second‐order low‐pass filter, which is simulated and compared with the ideal result. All circuits are simulated with SPICE using CMOS 0.35µm technology and supply voltages ±1.5V to verify the theoretical results. Copyright © 2008 John Wiley & Sons, Ltd.