Firm relocation patterns incorporating spatial interactions

This paper developed a relocation pattern for analyzing decisions regarding the relocation process of individual firms by using discrete choice models. Within this framework, three decision points in the relocation process are maintained in the micro-simulation modeling. The first decision that is move or non-move is modeled by using a binary logit form with the outcome of the probability of moving. The second decision, choosing the destination region, is modeled as a multinomial logit model with the outcome of the conditional probability of choosing a region. The final decision, choosing the new zone, is estimated by considering the spatial interactions. For example, the correlation among firms in the deterministic term and the spatial correlation among zones in the error term are considered by mixed logit models. The results of the study indicated that large firms and older firms have a lower probability of relocation. Moreover, this research found out that migrating firms are more attracted in regions with high accessibility. Finally, spatial factors and land prices in a given zone strongly affect the zone choice decision-making process of all firms.     

Correlations, partitioning and bioaccumulation of heavy metals between different compartments of Lake Balaton

Correlations between trace metals in dissolved and particulate phases, zooplankton, mussels and sediments in Lake Balaton were investigated. The degree of correlation between the various metals was different in each of the investigated compartments. Particulate metal concentrations (microg g(-1)) were anti-correlated with suspended particulate matter (SPM) (mg l(-1)), indicating a dilution effect, while total metal concentrations in the water column (microg l(-1)) were highly correlated with SPM, implying a major influence of the turbidity on the total metal concentrations. Between compartments, not many significant correlations were recognized. Only Ba, Ca, Sr and Mg are correlated in the sediments and in the particulate phase, suggesting common sources for both compartments. Partitioning coefficients (Kd) of trace metals between dissolved and particulate phases are generally low, typical for natural water and fairly stable over the lake. Most of the trace metals (Zn, Co, Cd and Pb) exist in the particulate phase (for about 70% of the total metal load). Cu and Ni are exceptions, showing a more equal distribution. Bioconcentration factors (BCF) of zooplankton and mussels were comparable to those of other natural waters. A negative biomagnification from suspended particulate matter to zooplankton and from sediment to mussel was recognized for all trace metals, except a small enrichment of Zn in zooplankton and Cd in mussel. Four factors were recognized in SPM and in sediments but they did not contain the same group of metals. Cluster analysis showed that metal accumulations in the sediments were different between northern and southern shores and in SPM between western and eastern areas.     

Micro-structuring of glass with features less than 100 μm by electrochemical discharge machining

Micro-electrochemical discharge machining (ECDM) was studied in order to improve the machining of 3D micro-structures of glass. To minimize structures and obtain good surface microstructures, the effects of the electrolyte, the pulse on/off-time ratio, the voltage, the feedrate, the rotational speed, and the electrolyte concentration in the drilling and milling processes were studied.In ECDM, voltage is applied to generate a gas film and sparks on a tool electrode; however, high voltage produces poor machining resolution. To obtain a stable gas film over the whole surface of the tool at a low voltage, a new mechanical contact detector, based on a loadcell, was used; the immersion depth of the tool electrode in the electrolyte was reduced as much as possible. In this study, various micro-structures less than 100 μm in size, such as Ø 60 μm micro-holes, a 10 μm-thin wall, and a 3D micro-structure were fabricated to demonstrate the potential for micro-machining of glass by ECDM.     

Microstructure and abrasive wear in silicon nitride ceramics

It is well known that abrasive wear resistance is not strictly a materials property, but also depends upon the specific conditions of the wear environment. Nonetheless, characteristics of the ceramic microstructure do influence its hardness and fracture toughness and must, therefore, play an active role in determining how a ceramic will respond to the specific stress states imposed upon it by the wear environment. In this study, the ways in which composition and microstructure influence the abrasive wear behavior of six commercially-produced silicon nitride based ceramics are examined. Results indicate that microstructural parameters, such as matrix grain size and orientation, porosity, and grain boundary microstructure, and thermal expansion mismatch stresses created as the result of second phase formation, influence the wear rate through their effect on wear sheet formation and subsurface fracture. It is also noted that the potential impact of these variables on the wear rate may not be reflected in conventional fracture toughness measurements.     

Determination of thermal parameters of non-spherical particles in a packed bed from svstem response analysis in the time domain

The thermal conductivity and the particle-to-fluid heat-transfer coefficient for peanut-shaped polyester particles in a packed bed were determined simultaneously using the pseudo-random binary noise sequence (PRBNS) response technique. The modified Dispersion-Concentric (D-C) model was applied to beds packed with the non-spherical particles. A time domain method, using the convolution integral, was developed for removing the effects of the bed ends and the transducer time lag on the experimental responses. Parameter estimation was performed in the time domain, using a simplex method to fit the thermal response calculated from the parametric D-C model to the experimental response curve. The particle-to-fluid heat transfer coefficient in the bed was determined to be 106 W/m². K at an interstitial fluid velocity of 2.0 m/s. The thermal conductivity of polyester was 0.22 W/m. K at 313 K.     

Screening of marine microalgae for biodiesel feedstock

Biodiesel production from microalgae lipids is increasingly regarded as a more sustainable and feasible alternative to conventional biodiesel feedstocks derived from terrestrial bioenergy crops. A total of ninety-six strains of marine microalgae, with an elevated biomass productivity and intracellular lipid content, were isolated from the coastal waters of Singapore using an automated flow cytometric cell-sorting technique. Cell sorting was based on the two-dimensional distribution of algal cells for red fluorescence (representing chlorophyll auto-fluorescence) against forward-light scatter (representing cell size) and red vs. green fluorescence. Twenty-one of the strains were further characterized with respect to cell growth rate, biomass concentration, lipid content (total and neutral lipid) and fatty acid profile. The growth rates of Skeletonema costatum, Chaetoceros and Thalassiosira species were greatest among the entire strains, but in terms of absolute lipid yield Nannochloropsis strains predominated. Nannochloropsis strains had a lipid content ranging from 39.4% to 44.9% of dry weight biomass. Transesterification of the lipids yielded 25-51% of fatty acid methyl ester (FAME) i.e. biodiesel, where total FAME content ranged between 11 and 21% of dry weight biomass. This study describes the microalgae screening process and demonstrates that Nannochloropsis is a promising species for biodiesel feedstock.     

Pseudo-Hydrodynamic Flow of Quasiparticles in Semimetal WTe2 at Room Temperature

Recently, much interest has emerged in fluid-like electric charge transport in various solid-state systems. The hydrodynamic behavior of the electronic fluid reveals itself as a decrease of the electrical resistance with increasing temperature (the Gurzhi effect) in narrow channels, polynomial scaling of the resistance as a function of the channel width, violation of the Wiedemann–Franz law supported by the emergence of the Poiseuille flow. Similar to whirlpools in flowing water, the viscous electronic flow generates vortices, resulting in abnormal sign-changing electrical response driven by backflow. However, the question of whether the long-ranged sign-changing electrical response can be produced by a mechanism other than hydrodynamics has not been addressed so far. Here polarization-sensitive laser microscopy is used to demonstrate the emergence of visually similar abnormal sign-alternating patterns in semi-metallic tungsten ditelluride at room temperature where this material does not exhibit true hydrodynamics. It is found that the neutral quasiparticle current consisting of electrons and holes obeys an equation remarkably similar to the Navier–Stokes equation. In particular, the momentum relaxation is replaced by the much slower process of quasiparticle recombination. This pseudo-hydrodynamic flow of quasiparticles leads to a sign-changing charge accumulation pattern via different diffusivities of electrons and holes.     

Jute fibre/epoxy composites: Surface properties and interfacial adhesion

Jute fibres were surface treated in order to enhance the interfacial interaction between jute natural fibres and an epoxy matrix. The fibres are exposed to alkali treatment in combination with organosilane coupling agents and aqueous epoxy dispersions. The surface topography and surface energy influenced by the treatments were characterized. Single fibre pull-out tests combined with SEM and AFM characterization of the fracture surfaces were used to identify the interfacial strengths and to reveal the mechanisms of failure.